File name: Pandora38s1_BayonneNJ_20230804_L2Fit_fout2c5d20230101p1-8.txt File generation date: 20230805T173018.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v5d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20230804_L1_smca1c5d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20230804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2447 305.3854 305.5261 305.6667 305.8074 305.9480 306.0886 306.2292 306.3698 306.5104 306.6510 306.7916 306.9321 307.0727 307.2132 307.3537 307.4942 307.6347 307.7752 307.9157 308.0561 308.1966 308.3370 308.4775 308.6179 308.7583 308.8987 309.0391 309.1794 309.3198 309.4601 309.6005 309.7408 309.8811 310.0214 310.1617 310.3020 310.4423 310.5825 310.7228 310.8630 311.0032 311.1434 311.2836 311.4238 311.5640 311.7042 311.8443 311.9844 312.1246 312.2647 312.4048 312.5449 312.6850 312.8250 312.9651 313.1052 313.2452 313.3852 313.5252 313.6652 313.8052 313.9452 314.0852 314.2251 314.3651 314.5050 314.6449 314.7848 314.9247 315.0646 315.2045 315.3443 315.4842 315.6240 315.7639 315.9037 316.0435 316.1833 316.3231 316.4628 316.6026 316.7423 316.8821 317.0218 317.1615 317.3012 317.4409 317.5806 317.7202 317.8599 317.9995 318.1391 318.2788 318.4184 318.5580 318.6975 318.8371 318.9767 319.1162 319.2558 319.3953 319.5348 319.6743 319.8138 319.9533 320.0927 320.2322 320.3716 320.5110 320.6505 320.7899 320.9293 321.0686 321.2080 321.3474 321.4867 321.6261 321.7654 321.9047 322.0440 322.1833 322.3226 322.4618 322.6011 322.7403 322.8795 323.0188 323.1580 323.2972 323.4363 323.5755 323.7147 323.8538 323.9930 324.1321 324.2712 324.4103 324.5494 324.6884 324.8275 324.9666 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230804T122719.3Z 8616.518973 278 1 38.91 2 62.97 90.01 82.36 253.70 0.00 1 0.00 1 0 17 4.160e-02 7.812e-03 3.819e-02 6.266e-03 3.164613e-01 3.273883e-03 3.685993e-03 -6.000000e+00 2.483613e-02 232.20 -2.00 3.51 -2.00 318.62 0.00e+00 6.127763e-04 6.875757e-04 1.020735e-04 -6.000000e+00 1.117835e-03 290.20 -2.00 20.00 -2.00 317.72 0.00e+00 2.188 0.000 302.00 328.00 3 5.8320e+00 9.0515e-03 2.7636e-02 -6.0000e+00 6.2160e-02 4.7341e-02 1.0374e-02 1.6635e-02 -6.0000e+00 6.7181e-02 5.7424e-03 6.7349e-03 8.0511e-03 -6.0000e+00 4.0070e-02 -8.8101e-03 3.4268e-03 2.2785e-03 -6.0000e+00 1.6783e-02 1.1374e-04 7.7837e-05 1.9685e-04 2.5551e-05 -6.0000e+00 1.2289e-03 -2.3300e-05 4.6120e-05 12 9 1 12 1 1 99.99 21.77 0.52 -0.00002 0.00056 16 5 1 5 0 2278.770 26.83 19.99 21.77 30.53 34.3 987.05 12065 -7727 -4492 2840 -25699 -5374 -2491 11271 -11024 13067 -6901 4585 4869 -14570 3124 1325 233 -8091 6798 4186 5281 13569 892 4141 -4327 4424 -6287 5384 248 4147 3316 950 1078 -950 3987 -6735 -4746 696 -1232 -1060 -3085 827 -1073 1044 -1928 -958 -185 -3204 1162 -2639 2056 582 2287 1143 -225 1013 1110 1266 -505 2005 -946 2281 1776 861 829 -690 1137 -1170 582 -488 48 86 -611 1288 -498 -60 -2379 -1221 -435 72 -1725 -1881 -238 -1112 -327 -279 484 236 -319 870 -689 749 586 717 -173 929 823 232 654 -435 -297 -1107 828 -544 -351 -1215 -568 480 133 733 -176 681 -536 9 514 -432 834 -1091 229 -1152 359 57 -205 713 -88 312 -168 769 -90 52 -7 -443 83 -38 312 -281 591 -83 212 12 -771 157 -129 541 -456 -259 142 -1570 -265 -129 574 -769 745 -489 311 377 -1595 328 155 29 -1158 876 573 726 1727 134 637 -765 737 -1146 828 39 629 549 177 215 -195 747 -1423 -1093 179 -386 -380 -1227 332 -450 433 -825 -405 -76 -1346 466 -1129 894 276 1133 602 -124 566 627 709 -283 1101 -557 1405 1193 614 584 -463 709 -748 397 -377 40 73 -522 1030 -374 -41 -1511 -751 -284 53 -1443 -1733 -231 -1147 -357 -300 542 272 -366 1023 -762 748 547 664 -173 1019 1007 289 850 -559 -357 -1344 947 -653 -450 -1534 -747 656 194 1131 -288 1113 -855 13 762 -614 1176 -1513 334 -1793 557 88 -306 1095 -129 435 -227 1049 -132 82 -11 -703 135 -65 558 -529 1135 -164 414 23 -1427 277 -225 SS 20230804T123148.5Z 8616.522089 281 1 48.74 2 62.12 90.75 83.14 254.45 0.00 1 0.00 1 0 25 1.354e-02 5.265e-03 9.589e-03 1.629e-03 3.064499e-01 8.495271e-04 3.580992e-03 -6.000000e+00 8.080156e-03 232.20 -2.00 3.51 -2.00 318.61 0.00e+00 4.304934e-04 1.786615e-04 1.049173e-04 -6.000000e+00 3.637518e-04 290.20 -2.00 20.00 -2.00 317.73 0.00e+00 2.127 0.000 302.00 328.00 3 3.7368e+00 2.3469e-03 2.6827e-02 -6.0000e+00 2.0223e-02 1.0363e-02 2.6875e-03 1.6105e-02 -6.0000e+00 2.1858e-02 8.3886e-03 1.7370e-03 7.7881e-03 -6.0000e+00 1.3037e-02 -8.5915e-03 8.8482e-04 2.1480e-03 -6.0000e+00 5.4594e-03 1.0158e-03 -6.0220e-05 5.1244e-05 2.4657e-05 -6.0000e+00 3.9989e-04 2.1591e-04 1.2523e-05 10 0 0 10 0 0 99.99 21.77 0.18 0.00022 -0.00024 186 43 1 5 0 262.020 26.83 20.00 21.77 30.68 34.2 987.72 -2881 -2529 -3549 984 -7589 -115 -3496 -146 93 -3192 1513 -3682 2250 -3240 2904 -2477 -1050 482 -910 2403 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420 -802 -618 -659 -208 -155 -843 -918 -1022 -399 -103 431 137 -137 -1 -320 663 250 1081 175 250 -672 -461 -287 -440 883 91 797 1029 852 549 300 492 -358 13 -297 140 -292 179 -230 -708 277 -408 30 -371 SS 20230804T123601.1Z 8616.525013 284 1 2.17 2 61.32 91.44 83.87 255.16 0.00 1 0.00 1 0 25 1.064e-02 5.922e-03 5.659e-03 1.856e-03 2.961178e-01 9.715283e-04 3.501759e-03 -6.000000e+00 6.350161e-03 232.20 -2.00 3.51 -2.00 317.19 0.00e+00 3.390907e-04 1.397799e-04 9.551543e-05 -6.000000e+00 2.858834e-04 290.20 -2.00 20.00 -2.00 316.32 0.00e+00 2.074 0.000 302.00 328.00 3 1.8476e+00 2.5858e-03 2.6032e-02 -6.0000e+00 1.5893e-02 -1.3687e-03 2.9050e-03 1.5474e-02 -6.0000e+00 1.7178e-02 2.7288e-04 1.7117e-03 7.4657e-03 -6.0000e+00 1.0246e-02 -2.1761e-03 8.2377e-04 2.0260e-03 -6.0000e+00 4.2905e-03 7.2594e-03 -2.1417e-05 5.6466e-05 2.4901e-05 -6.0000e+00 3.1428e-04 -5.7358e-05 -3.2453e-06 12 1 1 12 1 1 95.51 21.76 0.20 -0.00006 -0.00022 23 133 1 5 0 83.120 26.83 20.00 21.76 30.84 34.3 988.93 545 -2571 508 -5183 172 -3584 266 96 -265 1837 -3945 110 -1944 1086 -983 187 799 -1247 1537 -733 1791 -189 1245 467 -220 69 -1192 331 -1151 1448 -613 2016 259 -779 -1825 -3164 -618 -1442 -109 -794 -830 -1007 -621 32 -1061 144 -793 -351 -506 287 548 923 1302 677 829 340 995 693 670 1482 1153 2302 1224 1208 186 -169 110 68 714 198 301 -453 -57 -184 -248 10 -408 85 -695 -256 -994 -1305 -1592 -1468 -997 -963 -79 -355 70 -67 220 279 610 1038 924 887 912 272 -116 -530 -573 -560 39 -375 -465 -915 -843 -415 2 254 -121 180 -224 175 363 420 698 336 323 -351 57 -463 17 526 436 472 1092 861 282 269 58 -79 -100 -226 21 -125 168 -189 -62 -171 -257 -151 -451 60 -312 60 -601 17 -372 29 12 -35 250 -575 16 -338 194 -204 42 187 -312 390 -197 475 -51 346 139 -64 21 -353 99 -334 413 -192 620 87 -265 -602 -1072 -227 -631 -52 -408 -463 -589 -371 19 -643 86 -470 -204 -292 168 341 575 859 472 596 252 741 514 490 1079 878 1760 1024 1002 154 -138 85 53 596 176 288 -429 -53 -173 -216 9 -313 67 -557 -230 -953 -1305 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