File name: Pandora38s1_BayonneNJ_20240815_L2Fit_fout2c5d20230101p1-8.txt File generation date: 20240816T051230.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v5d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20240815_L1_smca1c5d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20240815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2447 305.3854 305.5261 305.6667 305.8074 305.9480 306.0886 306.2292 306.3698 306.5104 306.6510 306.7916 306.9321 307.0727 307.2132 307.3537 307.4942 307.6347 307.7752 307.9157 308.0561 308.1966 308.3370 308.4775 308.6179 308.7583 308.8987 309.0391 309.1794 309.3198 309.4601 309.6005 309.7408 309.8811 310.0214 310.1617 310.3020 310.4423 310.5825 310.7228 310.8630 311.0032 311.1434 311.2836 311.4238 311.5640 311.7042 311.8443 311.9844 312.1246 312.2647 312.4048 312.5449 312.6850 312.8250 312.9651 313.1052 313.2452 313.3852 313.5252 313.6652 313.8052 313.9452 314.0852 314.2251 314.3651 314.5050 314.6449 314.7848 314.9247 315.0646 315.2045 315.3443 315.4842 315.6240 315.7639 315.9037 316.0435 316.1833 316.3231 316.4628 316.6026 316.7423 316.8821 317.0218 317.1615 317.3012 317.4409 317.5806 317.7202 317.8599 317.9995 318.1391 318.2788 318.4184 318.5580 318.6975 318.8371 318.9767 319.1162 319.2558 319.3953 319.5348 319.6743 319.8138 319.9533 320.0927 320.2322 320.3716 320.5110 320.6505 320.7899 320.9293 321.0686 321.2080 321.3474 321.4867 321.6261 321.7654 321.9047 322.0440 322.1833 322.3226 322.4618 322.6011 322.7403 322.8795 323.0188 323.1580 323.2972 323.4363 323.5755 323.7147 323.8538 323.9930 324.1321 324.2712 324.4103 324.5494 324.6884 324.8275 324.9666 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240815T111252.6Z 8993.467275 71 1 49.37 2 78.82 81.32 154.92 290.05 0.00 1 0.00 1 0 17 5.055e-01 1.917e-02 3.027e-01 1.158e-02 7.197764e-01 6.544029e-03 8.000371e-03 -6.000000e+00 3.023949e-01 231.76 -2.00 3.51 -2.00 321.45 0.00e+00 -2.209302e-03 3.514303e-03 3.185520e-03 -6.000000e+00 1.494498e-02 290.42 -2.00 20.00 -2.00 320.81 0.00e+00 4.975 0.002 302.00 328.00 3 3.5495e+00 2.4508e-02 6.5612e-02 -6.0000e+00 7.5710e-01 3.2695e-01 3.2771e-02 4.5965e-02 -6.0000e+00 8.1967e-01 -4.3141e-01 2.8347e-02 1.9820e-02 -6.0000e+00 4.8706e-01 1.7602e-01 1.3234e-02 6.3527e-03 -6.0000e+00 2.0502e-01 4.6819e-05 1.4981e-04 3.4499e-04 6.9601e-05 -6.0000e+00 1.5029e-02 -2.7433e-03 9.5918e-05 12 8 8 10 0 0 -13.16 21.55 0.40 -0.00274 -0.00162 24 5 1 5 0 2056.780 26.62 19.99 21.55 29.45 36.6 973.56 -200799 -222151 -200003 -181018 900000 116862 -143967 -209408 -97204 900000 -171043 900000 -18422 84438 -107365 -26466 -21907 -13717 3785 900000 65558 -17970 900000 -37698 -26334 869 4163 45087 -47125 39775 -10028 -11608 21044 70037 -19070 -2947 61290 -9124 34951 38397 37663 21411 11120 37233 13108 26113 32130 14086 -205 31269 10373 22174 21043 10272 19694 3657 18732 10433 -106 3451 13864 16045 12609 9536 7545 12025 6751 4436 10372 2264 8196 -6829 2578 -2545 3244 -4497 -8058 -1754 -5567 2546 -5172 2654 -5305 -1076 -1779 14 375 967 497 -241 190 -211 -421 -1771 -466 -2285 -11 -220 -781 -1035 -375 -1354 -794 -3323 -942 -2362 -343 -1064 158 -904 -637 -1474 66 218 -336 1123 1182 654 920 -884 548 583 701 1894 2811 758 577 995 428 939 165 451 -126 194 -234 205 -278 -27 -40 -440 -257 -1053 -272 -4533 -6896 -5079 -3901 900000 1319 -2216 -7091 -1197 900000 -5090 900000 -208 953 -3636 -462 -405 -253 62 900000 740 -387 900000 -1160 -784 21 94 648 -1692 653 -319 -441 648 1365 -881 -118 1446 -524 1578 1970 2164 1538 913 2369 1063 1876 2209 1200 -21 2567 1171 2480 2613 1539 2849 649 2922 1745 -19 588 2205 2749 2523 2172 1819 2739 1628 1156 2852 767 2843 -2838 952 -924 1008 -1366 -2414 -513 -1919 956 -2447 1318 -3119 -647 -1150 9 263 687 350 -164 120 -127 -249 -1121 -329 -1906 -9 -216 -824 -1087 -365 -1315 -714 -3107 -915 -2460 -371 -1251 186 -1206 -934 -2297 102 325 -479 1534 1780 949 1401 -1406 847 866 1091 2811 3975 1056 793 1442 702 1581 308 894 -266 434 -562 511 -713 -71 -103 -1078 -589 -2288 -573 SS 20240815T111835.8Z 8993.471247 74 1 48.55 2 77.75 82.22 155.88 291.74 0.00 1 0.00 1 0 25 3.837e-01 9.191e-03 2.954e-01 7.369e-03 6.746166e-01 4.177677e-03 7.771796e-03 -6.000000e+00 2.329741e-01 231.76 -2.00 3.51 -2.00 321.38 0.00e+00 2.954308e-03 2.139429e-03 3.377914e-03 -6.000000e+00 1.056378e-02 290.42 -2.00 20.00 -2.00 320.72 0.00e+00 4.572 0.002 302.00 328.00 3 3.3913e+00 1.5173e-02 6.0416e-02 -6.0000e+00 5.8357e-01 1.4485e-01 2.0736e-02 4.1747e-02 -6.0000e+00 6.3256e-01 -1.4466e-01 1.9432e-02 2.0843e-02 -6.0000e+00 3.7536e-01 5.1429e-02 9.1567e-03 5.6193e-03 -6.0000e+00 1.5552e-01 8.4462e-05 -6.1009e-05 2.2344e-04 9.8997e-05 -6.0000e+00 1.1529e-02 -1.6474e-03 9.3707e-05 11 8 0 10 0 0 28.15 21.55 0.24 -0.00165 -0.00211 35 8 1 5 0 1386.930 26.62 20.00 21.55 29.62 36.4 974.38 -125907 -89825 -185900 -144227 900000 -45590 900000 -171256 10279 -152549 -74919 -74740 -123409 -101880 -46122 900000 -53822 900000 -3702 16794 37323 -15829 76132 -18909 -48692 -48432 7549 -17234 7918 30569 -14201 1113 -47438 -4855 -24226 -891 -929 16032 2888 4570 8146 198 -6167 8079 9985 3476 2745 7511 -1051 -4135 1684 8718 637 4555 6746 6405 8530 -3671 6437 -4049 1769 3819 5166 4502 2735 728 -1055 3508 339 778 2947 2318 2153 -1132 3816 -3268 -1910 -511 -155 1108 -2044 42 -1185 -1696 -1843 -71 -882 -375 -449 734 -506 -2526 1584 97 606 -665 1098 1002 452 -330 -1920 -844 -1531 -542 -1226 -1323 -1148 -1058 -183 -393 712 50 403 135 750 1004 811 733 -580 277 -292 175 -21 300 602 915 1120 199 89 287 279 -122 2 -296 -388 -235 -181 -72 -410 238 -195 131 431 -904 -645 -2670 -1318 900000 -327 900000 -2460 74 -2191 -538 -634 -2175 -1862 -602 900000 -1019 900000 -51 197 365 -269 547 -383 -1430 -1486 133 -383 140 479 -417 33 -2632 -184 -1091 -33 -38 670 168 307 590 17 -580 675 834 318 260 706 -114 -502 216 1161 101 752 1154 1146 1526 -736 1139 -793 343 805 1217 1083 759 186 -300 1003 102 266 1072 877 799 -407 1298 -1082 -593 -162 -56 464 -942 21 -669 -1025 -1191 -48 -627 -271 -322 497 -325 -1555 914 60 417 -536 1004 1036 503 -366 -2022 -796 -1358 -482 -1168 -1334 -1224 -1212 -229 -550 1079 80 641 208 1089 1408 1151 1088 -919 448 -468 270 -31 428 821 1199 1438 272 137 493 522 -245 4 -665 -930 -587 -463 -186 -1053 582 -451 284 916 SS 20240815T112354.1Z 8993.474931 77 1 49.13 2 76.75 83.06 156.76 293.39 0.00 1 0.00 1 0 25 3.634e-01 7.860e-03 2.067e-01 5.050e-03 6.317039e-01 2.766397e-03 7.088356e-03 -6.000000e+00 2.166685e-01 231.76 -2.00 3.51 -2.00 321.13 0.00e+00 2.171831e-03 1.353479e-03 4.807260e-04 -6.000000e+00 9.772911e-03 290.42 -2.00 20.00 -2.00 320.46 0.00e+00 4.252 0.001 302.00 328.00 3 3.1871e+00 9.7046e-03 5.4607e-02 -6.0000e+00 5.4165e-01 1.0370e-01 1.3034e-02 3.4576e-02 -6.0000e+00 5.8551e-01 -1.0042e-01 1.1910e-02 1.6989e-02 -6.0000e+00 3.4941e-01 3.2253e-02 5.6622e-03 6.2199e-03 -6.0000e+00 1.4658e-01 1.4874e-04 -3.6679e-04 1.5123e-04 7.2931e-05 -6.0000e+00 1.0732e-02 -2.1383e-03 6.5825e-05 11 8 0 10 0 0 17.43 21.55 0.36 -0.00214 -0.00489 52 12 1 5 0 944.650 26.62 20.00 21.55 29.80 36.4 975.67 167043 -108595 -78550 -170847 -112919 -162689 -76762 -93945 -97268 -117285 -109592 -5683 -28576 -43347 -32328 -44006 34717 -36065 3791 -31619 20634 -27198 567 -23734 -10683 7919 -29981 19955 -29435 -10650 -27711 -7539 4862 8 9444 -16653 662 -7175 4060 -8103 9808 -2758 5905 5431 -827 9745 -2182 8339 -1102 3994 3887 2593 5289 1510 3987 850 4146 -232 337 1356 5097 2952 1310 5460 -838 4577 1819 -1158 2389 2211 836 -512 1146 -993 451 -1107 637 -256 -3074 797 -496 -1260 -1878 -3100 -1382 -2365 -32 -100 1037 24 -298 697 1263 665 -322 772 664 848 -251 -217 -339 -331 485 169 -570 -1247 -844 -583 120 400 -108 169 -291 395 183 354 734 -150 91 -1132 319 -246 -71 98 700 112 741 945 208 646 -323 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