File name: Pandora206s1_BuffaloNY_20240609_L2Fit_fwvt1c1d20220512p1-8.txt File generation date: 20240610T052159.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v1d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20240609_L1_smca1c1d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20240609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0358 492.1569 492.2779 492.3989 492.5200 492.6409 492.7619 492.8829 493.0038 493.1247 493.2456 493.3665 493.4874 493.6082 493.7291 493.8499 493.9707 494.0915 494.2123 494.3330 494.4537 494.5745 494.6952 494.8159 494.9365 495.0572 495.1778 495.2984 495.4190 495.5396 495.6602 495.7807 495.9013 496.0218 496.1423 496.2628 496.3832 496.5037 496.6241 496.7445 496.8649 496.9853 497.1057 497.2260 497.3463 497.4666 497.5869 497.7072 497.8275 497.9477 498.0679 498.1882 498.3083 498.4285 498.5487 498.6688 498.7889 498.9091 499.0291 499.1492 499.2693 499.3893 499.5093 499.6293 499.7493 499.8693 499.9893 500.1092 500.2291 500.3490 500.4689 500.5888 500.7086 500.8285 500.9483 501.0681 501.1879 501.3076 501.4274 501.5471 501.6668 501.7865 501.9062 502.0258 502.1455 502.2651 502.3847 502.5043 502.6239 502.7435 502.8630 502.9825 503.1020 503.2215 503.3410 503.4605 503.5799 503.6993 503.8187 503.9381 504.0575 504.1768 504.2962 504.4155 504.5348 504.6541 504.7733 504.8926 505.0118 505.1310 505.2502 505.3694 505.4886 505.6077 505.7268 505.8460 505.9650 506.0841 506.2032 506.3222 506.4412 506.5602 506.6792 506.7982 506.9172 507.0361 507.1550 507.2739 507.3928 507.5117 507.6305 507.7494 507.8682 507.9870 508.1058 508.2245 508.3433 508.4620 508.5807 508.6994 508.8181 508.9367 509.0554 509.1740 509.2926 509.4112 509.5298 509.6483 509.7668 509.8854 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240609T112625.3Z 8926.476681 92 1 4.96 2 72.47 74.61 96.91 45.82 0.00 1 0.00 1 0 15 3.132e-03 3.124e-03 8.802e-05 8.784e-05 2.740538e+03 5.485643e+00 1.956934e+02 -6.000000e+00 1.794379e+02 283.99 -2.00 20.00 -2.00 505.24 0.00e+00 7.484928e-04 2.449992e-06 4.411215e-05 -6.000000e+00 8.905949e-05 283.99 -2.00 20.00 -2.00 500.34 0.00e+00 4.162428e-01 1.777615e-03 2.050844e-02 -6.000000e+00 6.345102e-02 232.55 -2.00 3.55 -2.00 501.94 0.00e+00 3.272 0.001 489.00 513.00 1 1.9099e-01 1.3642e-04 5.0103e-03 -6.0000e+00 4.8668e-03 -3.9741e-03 3.5150e-05 5.3383e-04 -6.0000e+00 1.2613e-03 9.8051e-01 1.0255e-03 9.3570e-06 2.7233e-05 -6.0000e+00 3.4459e-04 7.1059e-03 -6.1462e-05 10 0 0 10 0 0 -34.19 18.53 2.27 0.00711 0.01422 1389 1389 2 2 0 3.530 15.00 18.53 20.01 21.98 21.88 22.5 991.29 -672 -561 -396 -22 224 476 589 571 580 446 156 -51 -139 -194 -361 -392 -272 -119 127 221 217 283 219 188 321 295 100 -6 -7 -315 -420 -400 -309 13 208 196 166 165 34 -102 -113 -97 35 164 267 382 360 194 -65 -278 -522 -652 -797 -747 -469 -164 80 207 304 381 417 429 408 328 295 190 -13 -216 -187 -250 -295 -278 -221 -127 10 -10 -221 -362 -418 -433 -455 -324 -299 -218 -59 -120 -75 -77 -108 -119 -44 48 291 414 338 242 124 -89 -184 -437 -605 -558 -450 -246 -83 -165 -182 -208 -250 -184 13 142 302 459 541 532 488 511 369 193 170 113 35 189 194 103 249 280 79 155 234 -61 -259 -226 -309 -228 10 35 34 228 280 214 223 183 68 6 -19 -235 -497 -632 -665 -560 -398 -22 232 494 622 598 607 463 163 -53 -142 -200 -370 -403 -277 -124 133 233 230 301 233 197 337 310 104 -6 -7 -324 -424 -404 -318 13 216 206 174 171 35 -106 -117 -100 37 171 280 402 378 201 -66 -284 -520 -647 -782 -737 -462 -166 80 212 312 390 427 440 413 332 302 192 -13 -213 -185 -246 -288 -271 -218 -127 10 -10 -218 -352 -403 -415 -437 -313 -291 -210 -58 -118 -73 -76 -107 -118 -43 47 290 414 336 237 121 -85 -176 -411 -568 -530 -431 -239 -82 -161 -177 -204 -243 -180 13 139 300 460 536 529 488 512 368 190 168 110 34 183 190 101 244 273 77 151 225 -58 -244 -214 -294 -215 9 33 33 223 277 209 219 181 67 6 -19 -227 -472 -598 SQ 20240609T112630.5Z 8926.476741 92 2 5.11 2 72.45 74.62 96.90 45.84 0.00 1 0.00 1 0 15 3.126e-03 3.118e-03 8.795e-05 8.777e-05 2.745671e+03 5.481247e+00 1.962041e+02 -6.000000e+00 1.790847e+02 283.99 -2.00 20.00 -2.00 505.24 0.00e+00 7.502112e-04 2.448042e-06 4.416985e-05 -6.000000e+00 8.888402e-05 283.99 -2.00 20.00 -2.00 500.34 0.00e+00 4.145435e-01 1.776482e-03 2.050526e-02 -6.000000e+00 6.332535e-02 232.55 -2.00 3.55 -2.00 501.94 0.00e+00 3.270 0.001 489.00 513.00 1 1.9054e-01 1.3632e-04 5.0072e-03 -6.0000e+00 4.8572e-03 -4.0044e-03 3.5139e-05 5.3385e-04 -6.0000e+00 1.2588e-03 9.8141e-01 9.7854e-04 9.3498e-06 2.7252e-05 -6.0000e+00 3.4392e-04 7.5421e-03 -6.2783e-05 10 0 0 10 0 0 -22.17 18.53 2.27 0.00754 0.01433 1389 1389 2 2 0 3.530 15.00 18.53 20.01 21.98 21.88 22.5 991.29 -688 -559 -387 -14 219 486 608 583 575 436 154 -64 -141 -208 -359 -388 -269 -132 126 226 210 281 249 188 307 289 84 -18 -10 -294 -400 -398 -296 9 216 193 149 155 39 -97 -99 -73 26 158 263 352 354 182 -67 -281 -525 -639 -780 -758 -493 -158 63 213 326 385 419 434 422 320 285 185 1 -216 -181 -234 -287 -283 -218 -133 13 -15 -244 -373 -413 -428 -467 -312 -294 -227 -77 -107 -63 -85 -100 -95 -15 36 275 423 329 242 118 -80 -181 -445 -605 -554 -469 -245 -65 -162 -178 -208 -253 -184 25 120 279 460 537 517 499 521 369 189 152 124 16 192 206 109 228 273 78 163 243 -55 -205 -219 -329 -239 6 29 31 235 281 210 231 168 80 17 -30 -245 -493 -631 -682 -559 -388 -14 227 504 643 610 602 453 162 -67 -144 -215 -368 -399 -274 -137 131 238 223 298 265 197 323 304 88 -19 -11 -303 -404 -402 -304 10 224 203 156 161 40 -101 -102 -75 27 165 276 370 371 188 -68 -286 -522 -634 -766 -747 -486 -160 64 218 334 394 429 446 426 324 292 187 1 -213 -179 -230 -280 -277 -215 -132 13 -15 -241 -363 -398 -411 -449 -302 -287 -219 -75 -105 -62 -84 -98 -94 -15 36 275 423 327 237 115 -77 -172 -419 -568 -526 -449 -238 -65 -159 -173 -205 -247 -179 25 117 278 461 532 514 499 521 368 186 150 121 15 187 201 107 223 267 76 159 234 -53 -193 -208 -313 -225 5 28 30 231 278 205 226 166 79 17 -29 -237 -469 -597 SQ 20240609T112635.6Z 8926.476801 92 3 5.05 2 72.44 74.63 96.89 45.85 0.00 1 0.00 1 0 15 3.123e-03 3.114e-03 8.840e-05 8.822e-05 2.746742e+03 5.514284e+00 1.969292e+02 -6.000000e+00 1.789531e+02 283.99 -2.00 20.00 -2.00 505.24 0.00e+00 7.495284e-04 2.458275e-06 4.409304e-05 -6.000000e+00 8.881857e-05 283.99 -2.00 20.00 -2.00 500.34 0.00e+00 4.134468e-01 1.784655e-03 2.037784e-02 -6.000000e+00 6.327819e-02 232.55 -2.00 3.55 -2.00 501.94 0.00e+00 3.267 0.001 489.00 513.00 1 1.9854e-01 1.3692e-04 5.0004e-03 -6.0000e+00 4.8536e-03 -4.1756e-03 3.5295e-05 5.3274e-04 -6.0000e+00 1.2578e-03 9.7404e-01 9.6108e-04 9.3984e-06 2.7151e-05 -6.0000e+00 3.4367e-04 6.8577e-03 -5.7641e-05 10 0 0 10 0 0 -30.51 18.53 2.27 0.00686 0.01352 1389 1389 2 2 0 3.530 15.00 18.53 20.01 21.98 21.88 22.5 991.29 -695 -567 -394 -16 225 490 601 585 574 446 158 -59 -152 -188 -366 -383 -261 -123 110 217 221 295 221 190 299 289 96 -19 -31 -317 -415 -395 -308 14 210 209 143 170 36 -103 -95 -84 37 150 271 374 356 170 -68 -271 -518 -633 -794 -755 -494 -183 61 206 313 372 406 439 415 330 294 203 -11 -225 -175 -216 -298 -277 -206 -125 26 -11 -229 -372 -412 -418 -465 -313 -306 -215 -53 -114 -63 -76 -99 -93 -31 29 291 435 321 257 130 -79 -184 -440 -618 -551 -449 -233 -47 -149 -177 -229 -265 -178 6 134 276 440 540 497 472 491 372 196 152 128 35 198 217 92 225 273 51 154 235 -56 -242 -237 -325 -234 43 53 34 213 283 216 218 187 77 37 -15 -231 -501 -633 -687 -565 -394 -16 233 508 634 611 600 472 166 -61 -155 -193 -374 -392 -266 -128 114 228 234 312 234 202 313 303 100 -20 -32 -325 -419 -399 -316 14 218 219 150 176 37 -107 -98 -87 38 156 284 393 372 176 -69 -276 -514 -627 -778 -743 -495 -185 62 210 320 380 415 450 426 340 300 205 -11 -226 -174 -212 -291 -270 -202 -124 25 -11 -226 -362 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