File name: Pandora82s1_DeBilt_20240530_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20240530T234410.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_DeBilt_20240530_L1_smca1c2d20240415p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20240530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240530T071333.6Z 8916.301083 241 1 9.39 2 58.19 94.80 69.61 206.05 0.00 1 0.00 1 0 17 1.201e-02 6.063e-03 1.445e-03 5.752e-04 3.338893e-01 2.921809e-04 4.314912e-03 -6.000000e+00 6.879816e-03 232.34 -2.00 3.84 -2.00 316.82 0.00e+00 5.082420e-04 3.626100e-05 6.761082e-05 -6.000000e+00 2.950491e-04 278.66 -2.00 20.00 -2.00 316.16 0.00e+00 1.890 0.000 302.00 328.00 3 1.1133e+00 7.7143e-04 2.7109e-02 -6.0000e+00 1.7310e-02 1.5837e-02 8.6225e-04 1.8926e-02 -6.0000e+00 1.8769e-02 -8.0544e-03 5.0552e-04 9.1927e-03 -6.0000e+00 1.1110e-02 2.6275e-04 2.4130e-04 2.5488e-03 -6.0000e+00 4.6617e-03 1.6861e-02 1.3846e-04 1.5653e-05 2.7503e-05 -6.0000e+00 3.1594e-04 2.9752e-02 12 1 1 12 1 1 99.94 24.50 0.30 0.02975 0.03079 164 100 1 5 0 56.870 32.75 20.00 24.50 21.98 4.7 871.90 -3233 -2672 -2894 -4358 -4351 -4573 -3252 -1508 -1430 -2236 -2905 -1566 -1222 -80 675 580 289 550 1194 1549 517 1173 1153 732 806 731 -38 -854 -898 624 1010 1538 1353 -1076 -2625 -2724 -1866 -846 -26 -189 -513 -334 -471 -72 7 -77 -192 -272 -369 59 812 873 1352 988 927 991 923 455 416 463 946 1411 1783 1560 310 -102 -834 -700 414 440 416 150 95 -27 -175 -593 -785 -1220 -866 -1074 -1005 -1370 -1891 -1597 -1051 -605 -69 346 564 579 611 215 -38 53 189 146 566 762 183 -193 -219 -763 -767 -328 -737 -691 -651 -403 -52 297 574 357 358 57 -226 -50 -89 133 93 45 -12 241 306 418 632 361 370 635 517 434 277 128 -244 37 7 -60 152 173 -103 -162 -314 -589 -735 -442 -394 -434 -605 -592 -626 -480 -227 -239 -391 -507 -291 -244 -18 166 157 82 165 347 467 159 356 367 250 271 256 -13 -297 -296 209 370 575 525 -430 -1046 -1105 -794 -397 -14 -106 -313 -202 -294 -45 4 -48 -118 -166 -223 37 539 596 936 728 676 739 701 343 306 340 722 1121 1488 1345 266 -83 -680 -568 350 395 392 146 91 -25 -158 -499 -628 -993 -732 -967 -984 -1396 -1991 -1758 -1203 -715 -82 423 686 689 688 229 -39 55 201 168 686 972 240 -253 -275 -908 -885 -396 -918 -877 -866 -547 -72 433 844 532 525 80 -308 -66 -118 181 132 66 -18 349 443 591 867 475 476 832 716 613 405 188 -368 57 11 -98 254 290 -173 -268 -512 -924 -1154 SS 20240530T071708.7Z 8916.303573 244 1 1.94 2 57.64 95.54 69.84 206.92 0.00 1 0.00 1 0 17 1.473e-02 6.931e-03 8.026e-03 3.231e-03 3.275138e-01 1.640577e-03 4.213974e-03 -6.000000e+00 8.437889e-03 232.34 -2.00 3.84 -2.00 316.76 0.00e+00 1.963301e-04 2.007492e-04 6.735132e-05 -6.000000e+00 3.617297e-04 278.66 -2.00 20.00 -2.00 316.10 0.00e+00 1.862 0.000 302.00 328.00 3 2.7956e+00 4.3314e-03 2.6612e-02 -6.0000e+00 2.1231e-02 1.6101e-02 4.8423e-03 1.8506e-02 -6.0000e+00 2.3018e-02 -5.5570e-03 2.8338e-03 8.9848e-03 -6.0000e+00 1.3624e-02 1.8949e-03 1.3480e-03 2.4646e-03 -6.0000e+00 5.7192e-03 3.2501e-03 2.9363e-04 8.7902e-05 2.6806e-05 -6.0000e+00 3.8733e-04 2.7234e-02 12 9 1 12 1 1 -5.14 24.52 0.19 0.02723 0.02944 4 15 1 5 0 387.540 32.75 20.01 24.52 22.39 4.7 875.14 -2317 -4090 -7344 -5398 190 -6136 -89 -572 -1531 -1374 -5627 -3487 -1506 -321 393 551 -913 1642 1390 3753 -9 1257 809 148 1008 378 434 -698 -1623 1324 238 2823 1525 13 -2223 -651 -597 -1961 -96 -396 -1141 7 -959 58 74 -147 -92 92 -510 -1146 -140 849 724 1095 1637 979 1011 344 1153 282 1488 1341 1442 1193 -72 -317 -568 -615 934 657 391 -289 -4 -106 404 -626 -926 -685 -1038 -1255 -1525 -1577 -1636 -1701 -1352 -203 -455 320 1104 508 799 751 -105 121 326 181 200 1112 212 -261 -653 -440 -885 -7 -728 -1140 -350 -430 -280 340 332 228 -3 -48 -252 -37 30 258 75 268 -251 468 534 577 314 323 480 830 362 723 264 222 -437 21 237 -71 172 468 4 -362 -338 -675 -1045 -339 -606 -1138 -817 24 -842 -13 -92 -253 -236 -997 -650 -320 -72 102 145 -256 472 419 1149 -3 395 268 49 350 137 156 -235 -557 454 84 1065 601 5 -845 -264 -254 -941 -52 -224 -702 4 -602 36 46 -92 -56 58 -323 -713 -93 574 520 795 1218 750 789 267 867 214 1160 1089 1229 1047 -63 -265 -470 -507 795 593 370 -285 -3 -102 367 -534 -755 -542 -890 -1138 -1504 -1605 -1710 -1865 -1540 -237 -540 388 1323 600 892 822 -107 126 355 205 239 1427 280 -336 -834 -530 -1041 -8 -918 -1466 -455 -588 -394 497 501 339 -5 -67 -344 -49 41 350 107 391 -373 674 770 793 422 426 619 1089 487 1014 382 332 -654 33 372 -114 282 784 6 -590 -541 -1070 -1621 SS 20240530T072029.2Z 8916.305894 246 1 0.89 2 57.13 96.23 70.05 207.73 0.00 1 0.00 1 0 17 1.778e-02 7.675e-03 1.075e-02 4.534e-03 3.235031e-01 2.303143e-03 4.161732e-03 -6.000000e+00 1.018404e-02 232.34 -2.00 3.84 -2.00 316.68 0.00e+00 7.447386e-04 2.761852e-04 9.665183e-05 -6.000000e+00 4.366956e-04 278.66 -2.00 20.00 -2.00 316.02 0.00e+00 1.836 0.000 302.00 328.00 3 2.5448e+00 6.0637e-03 2.6256e-02 -6.0000e+00 2.5624e-02 2.4101e-02 6.7748e-03 1.8268e-02 -6.0000e+00 2.7783e-02 -1.0723e-02 3.9532e-03 8.8734e-03 -6.0000e+00 1.6445e-02 2.1565e-03 1.8702e-03 2.4757e-03 -6.0000e+00 6.9013e-03 4.2931e-03 3.0252e-05 1.2331e-04 2.6484e-05 -6.0000e+00 4.6761e-04 2.8914e-02 12 9 1 12 1 1 999.00 24.55 0.26 0.02891 0.02914 2 19 1 5 0 296.430 32.75 20.01 24.55 22.72 4.7 877.79 464 -6444 -3655 -6210 -514 -8502 -5736 1394 357 163 -5794 -2701 -3335 -3475 5086 -1108 256 2518 1748 1498 2144 2167 2554 3062 1335 1332 -1022 -2226 -577 -93 736 484 1707 -612 -3563 -3203 -2739 -163 -719 -138 14 -167 297 -473 -234 2 388 -810 -1195 -31 449 937 1083 729 800 884 269 762 586 7 1328 2294 1794 943 826 -135 71 -102 1148 375 492 243 68 135 -600 -672 -1017 -1338 -800 -1662 -415 -2106 -2274 -714 -1105 -516 9 1039 609 18 619 -340 -37 -935 -331 -154 901 865 -169 -34 77 -671 -859 36 -1452 -700 -331 -488 -74 430 670 -168 516 -189 91 62 -353 239 -112 368 946 369 498 680 480 570 637 213 586 296 -117 -286 -472 -65 156 342 62 639 -175 -437 -769 -483 -595 67 -1090 -609 -968 -74 -1216 -869 221 64 30 -1125 -546 -729 -887 1279 -326 78 735 537 479 688 689 846 1075 469 486 -377 -773 -198 -33 264 190 684 -252 -1485 -1348 -1212 -78 -377 -80 9 -103 189 -304 -150 2 243 -506 -744 -20 304 648 760 544 614 665 207 578 452 5 1017 1817 1505 822 732 -115 57 -82 995 347 477 235 67 127 -543 -585 -845 -1084 -669 -1543 -399 -2203 -2448 -768 -1247 -600 11 1245 731 21 688 -372 -38 -971 -358 -174 1094 1107 -223 -45 98 -803 -1000 44 -1832 -893 -440 -665 -104 610 982 -251 752 -266 123 81 -470 322 -159 537 1382 531 716 955 641 746 814 278 805 415 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