File name: Pandora82s1_DeBilt_20240609_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20240609T234827.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_DeBilt_20240609_L1_smca1c2d20240415p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20240609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240609T045413.2Z 8926.204320 95 1 54.30 2 78.52 67.21 94.18 36.75 0.00 1 0.00 1 0 25 5.065e-01 1.050e-02 4.073e-02 1.233e-03 7.404357e-01 6.465161e-04 9.017652e-03 -6.000000e+00 2.906160e-01 233.12 -2.00 3.84 -2.00 320.53 0.00e+00 2.681505e-03 2.500976e-04 9.999356e-04 -6.000000e+00 1.250430e-02 279.85 -2.00 20.00 -2.00 319.95 0.00e+00 4.857 0.002 302.00 328.00 3 9.2986e-01 1.9712e-03 6.5379e-02 -6.0000e+00 7.3232e-01 1.3613e-01 2.5373e-03 4.3446e-02 -6.0000e+00 7.9369e-01 -1.6560e-01 2.4981e-03 2.2332e-02 -6.0000e+00 4.6981e-01 6.1309e-02 1.2425e-03 7.3933e-03 -6.0000e+00 1.9677e-01 7.3397e-04 -4.2430e-04 3.0507e-05 7.5336e-05 -6.0000e+00 1.3329e-02 3.7563e-02 12 8 8 10 0 0 97.51 24.31 0.35 0.03756 0.03437 215 23 1 5 0 252.540 32.50 20.00 24.31 17.43 4.7 839.37 -212030 -189268 -180871 -183471 -60680 -193052 -177838 -136509 -149081 -113950 -138338 -126772 -106426 -81716 -43111 -43146 -41203 -29128 -44146 -46555 -31083 -45660 -37218 -29341 -18296 -19353 -37043 -36227 -29413 -26753 -13930 -14601 -3937 -8603 -15187 -10934 -11181 -3554 -3770 3164 2465 3156 2279 4591 -185 2939 5002 1379 2213 4704 6355 3607 5653 5163 5704 3628 3973 3666 1238 1853 1866 3600 3797 3905 2704 1879 1049 33 1321 1365 1555 1180 516 749 -984 -947 -2988 -2864 -2427 -848 -846 -1123 -2241 -1598 -747 -581 117 384 915 857 790 249 -665 -716 -537 -623 277 517 168 -191 -829 -1025 -1126 -1084 -1311 -985 -782 -453 -200 316 503 368 120 -41 -248 -67 -29 148 -103 89 265 617 866 597 765 483 381 477 331 396 341 101 -234 -88 -88 -149 313 173 114 -222 -230 -560 -678 -3221 -2648 -2471 -2426 -241 -2994 -2651 -1543 -2169 -1260 -2096 -2088 -1894 -1484 -679 -814 -867 -609 -1162 -1327 -770 -1323 -1078 -868 -521 -591 -1363 -1276 -983 -1013 -576 -730 -207 -492 -878 -627 -737 -263 -347 325 284 386 296 594 -26 407 701 211 358 816 1125 736 1247 1255 1461 991 1112 1013 339 500 530 1130 1373 1462 1058 724 415 14 624 689 853 668 286 385 -503 -434 -1340 -1347 -1325 -506 -548 -837 -1711 -1284 -640 -528 103 345 812 772 659 197 -521 -597 -514 -654 317 640 212 -237 -1014 -1188 -1193 -1182 -1549 -1147 -965 -571 -279 471 793 584 191 -65 -378 -103 -43 233 -171 145 441 976 1322 920 1131 692 559 711 540 696 631 193 -471 -181 -186 -330 675 380 248 -476 -480 -1100 -1348 SS 20240609T050411.7Z 8926.211246 98 1 54.36 2 77.10 69.05 93.30 38.71 0.00 1 0.00 1 0 25 3.609e-01 8.987e-03 2.102e-02 9.264e-04 6.739987e-01 4.811752e-04 8.269461e-03 -6.000000e+00 2.070804e-01 233.12 -2.00 3.84 -2.00 320.12 0.00e+00 2.060170e-03 1.641744e-04 5.240200e-04 -6.000000e+00 8.909013e-03 279.85 -2.00 20.00 -2.00 319.52 0.00e+00 4.360 0.002 302.00 328.00 3 9.4618e-01 1.4180e-03 5.8958e-02 -6.0000e+00 5.2182e-01 8.6620e-02 1.7447e-03 3.9222e-02 -6.0000e+00 5.6553e-01 -1.0665e-01 1.6157e-03 1.9653e-02 -6.0000e+00 3.3475e-01 3.8027e-02 8.2487e-04 6.2683e-03 -6.0000e+00 1.4022e-01 1.2449e-03 -3.2684e-04 2.3514e-05 6.0524e-05 -6.0000e+00 9.4961e-03 3.6785e-02 11 8 0 10 0 0 98.80 24.34 0.29 0.03679 0.03433 308 32 1 5 0 176.460 32.75 20.01 24.34 18.13 4.7 845.90 -137090 -122018 -105568 -131201 -131812 -146938 -146008 -95545 -85521 -88195 -99179 -83046 -63606 -46593 -27378 -16868 -24066 -19803 -31152 -16881 -18733 -23211 -19619 -19534 -10099 -11066 -20063 -22236 -19879 -20952 -7061 -9192 672 -6938 -10537 -10176 -9213 -2449 -2493 1663 1083 3350 1671 2905 1813 2148 3755 505 1472 2258 3758 3653 4694 3464 3499 4432 1823 1291 718 1151 1310 2421 3384 2735 1288 959 99 -615 588 934 974 821 582 400 -549 -1174 -2183 -2564 -1882 -928 -1218 -1104 -2088 -1606 -1120 -529 73 416 1141 839 743 218 -378 -629 -257 -218 403 661 29 -193 -539 -900 -855 -794 -1074 -966 -789 -559 -46 374 494 350 250 56 -266 -29 -111 48 -188 59 156 446 492 539 605 364 511 603 390 386 360 97 -325 -147 -57 -60 270 158 41 -149 -185 -436 -726 -1944 -1709 -1326 -2003 -1881 -2535 -2796 -1269 -1167 -1331 -1774 -1515 -1241 -985 -601 -395 -681 -598 -1137 -564 -648 -849 -751 -824 -417 -489 -977 -1063 -932 -1134 -405 -639 49 -566 -841 -837 -860 -258 -326 226 164 530 282 494 317 384 678 98 300 496 921 999 1395 1043 1112 1455 631 443 240 381 455 931 1475 1242 608 439 46 -302 321 546 621 540 374 240 -301 -626 -1119 -1369 -1068 -622 -890 -861 -1781 -1441 -1013 -506 72 421 1138 798 654 193 -327 -573 -250 -232 469 834 38 -244 -667 -1055 -971 -883 -1297 -1158 -1000 -724 -66 566 789 562 397 89 -401 -43 -164 74 -297 96 249 708 757 830 891 518 736 882 622 661 648 179 -607 -292 -116 -125 566 338 87 -311 -376 -838 -1411 SS 20240609T053935.0Z 8926.235822 110 1 54.28 2 71.92 75.58 89.84 45.51 0.00 1 0.00 1 0 17 8.219e-02 6.661e-03 3.222e-03 3.714e-04 5.043136e-01 1.886680e-04 6.354248e-03 -6.000000e+00 4.716525e-02 233.12 -2.00 3.84 -2.00 318.73 0.00e+00 1.195523e-03 4.045005e-05 2.402538e-04 -6.000000e+00 2.029286e-03 279.85 -2.00 20.00 -2.00 318.05 0.00e+00 3.180 0.001 302.00 328.00 3 5.0711e-01 5.1952e-04 4.3389e-02 -6.0000e+00 1.1885e-01 3.4559e-02 5.9255e-04 2.8958e-02 -6.0000e+00 1.2881e-01 -4.3028e-02 4.2132e-04 1.4091e-02 -6.0000e+00 7.6246e-02 1.4608e-02 2.2215e-04 4.0787e-03 -6.0000e+00 3.1936e-02 7.1831e-03 -7.1563e-05 9.8796e-06 4.0079e-05 -6.0000e+00 2.1630e-03 3.7228e-02 11 8 0 10 0 0 67.45 24.31 0.27 0.03723 0.03669 840 88 1 5 0 64.610 32.50 20.00 24.31 18.38 4.7 846.43 -30923 -24709 -25515 -30219 -32221 -36710 -31616 -24909 -21616 -19713 -21252 -18360 -12929 -8676 -3172 -3616 -1536 -1544 -1256 -180 -1423 -743 -397 -1295 -716 -508 -2327 -3194 -4202 -2292 -345 806 1552 -1115 -2956 -3208 -2175 -465 77 486 74 397 543 614 592 501 356 -13 -87 743 1327 1375 1648 1674 1322 1446 850 618 374 533 1145 1538 2248 2095 704 368 -287 -462 543 518 748 435 371 118 -337 -701 -1441 -1723 -1047 -1168 -1143 -1450 -2047 -1764 -1066 -613 -181 295 667 645 644 288 -131 -70 44 -38 419 623 127 -267 -423 -849 -855 -373 -847 -754 -673 -461 25 280 520 337 307 37 -216 32 -20 91 34 56 108 281 487 455 668 308 407 675 478 429 246 134 -275 16 -9 -96 213 158 -79 -194 -264 -552 -717 -1004 -841 -906 -1041 -1039 -1271 -1155 -972 -917 -867 -976 -936 -769 -606 -253 -331 -150 -149 -128 -19 -155 -81 -46 -164 -96 -71 -332 -434 -564 -329 -56 148 319 -220 -606 -680 -476 -120 22 165 26 144 205 234 229 196 140 -5 -36 322 591 671 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