File name: Pandora82s1_DeBilt_20240617_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20240618T220631.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_DeBilt_20240617_L1_smca1c2d20240415p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20240617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240617T052100.2Z 8934.222920 146 1 1.49 2 74.59 71.57 132.00 311.15 0.00 1 0.00 1 0 17 3.262e-01 1.521e-02 2.075e-01 1.144e-02 5.839223e-01 5.930052e-03 7.411758e-03 -6.000000e+00 1.885013e-01 233.58 -2.00 3.84 -2.00 319.58 0.00e+00 -4.005092e-04 1.677588e-03 1.551976e-03 -6.000000e+00 8.157967e-03 280.73 -2.00 20.00 -2.00 318.92 0.00e+00 3.692 0.001 302.00 328.00 3 2.4284e+00 1.6918e-02 5.0960e-02 -6.0000e+00 4.7630e-01 5.0404e-02 2.0005e-02 3.5168e-02 -6.0000e+00 5.1644e-01 -7.2948e-02 1.6509e-02 1.6747e-02 -6.0000e+00 3.0438e-01 3.3114e-02 8.6271e-03 4.5592e-03 -6.0000e+00 1.2799e-01 5.8916e-04 -4.5457e-04 3.0182e-04 4.7815e-05 -6.0000e+00 8.7339e-03 3.5353e-02 12 9 9 12 1 1 999.00 24.41 0.29 0.03535 0.03194 1 8 1 5 0 741.700 32.75 20.00 24.41 20.94 4.6 863.49 900000 -142449 -81516 -40445 -75383 -65742 -94450 900000 -43517 258004 -1673 97589 -59423 -55697 7357 37382 -4056 12887 55003 -3230 -3617 -19189 15919 -7715 -21550 48435 -15738 -22541 -9671 -2965 -16062 7516 -5464 -2525 -15599 -6618 -5025 -9396 -5711 8464 -978 1627 -2363 1331 5312 9800 -3475 838 -4648 6621 2752 -568 3214 8109 -620 2393 1204 1998 1148 -1607 2531 3697 2887 3372 3652 5277 -1261 -3398 5352 717 -1686 3144 -373 -522 735 -3846 -1 -2144 -3523 -1548 -646 -1058 -1991 -2292 -624 1723 183 -48 1589 -788 -953 -924 -600 108 -1819 530 -1269 -677 -671 -547 197 -321 -981 -508 -3262 -220 532 -940 393 568 2366 931 -24 -434 1115 -329 -101 819 -951 1203 110 -595 1540 752 -774 754 -262 571 637 1329 675 -153 -1701 -832 739 -505 651 719 -1093 509 -48 -126 -1284 900000 -5344 -1909 -586 -1429 -1173 -2528 900000 -922 2877 -26 1088 -2386 -2671 230 1001 -181 532 1595 -177 -202 -1263 799 -542 -1875 2215 -1369 -1986 -733 -231 -1684 721 -683 -315 -1898 -834 -647 -1524 -1106 1691 -237 408 -589 352 1363 2444 -917 217 -1322 1803 872 -206 1222 3188 -258 1008 528 859 483 -688 1088 1738 1435 1846 2019 2741 -693 -1974 3189 482 -1186 2321 -262 -368 465 -2442 0 -1281 -2253 -1144 -512 -897 -1839 -2118 -611 1755 188 -50 1634 -789 -932 -843 -554 102 -1865 578 -1533 -881 -886 -704 246 -381 -1139 -579 -3949 -271 685 -1255 537 827 3694 1468 -37 -677 1671 -480 -149 1257 -1515 1951 178 -935 2296 1128 -1125 1085 -367 832 997 2192 1166 -270 -3056 -1567 1417 -990 1284 1443 -2222 1004 -90 -231 -2322 SS 20240617T053005.9Z 8934.229235 149 1 53.73 2 73.25 73.24 133.02 313.69 0.00 1 0.00 1 0 25 2.025e-01 1.051e-02 1.073e-01 3.249e-03 5.508254e-01 1.667220e-03 6.842740e-03 -6.000000e+00 1.164471e-01 233.58 -2.00 3.84 -2.00 319.84 0.00e+00 1.345261e-03 5.125105e-04 3.290845e-04 -6.000000e+00 5.018668e-03 280.73 -2.00 20.00 -2.00 319.20 0.00e+00 3.416 0.001 302.00 328.00 3 4.1723e+00 4.8211e-03 4.7228e-02 -6.0000e+00 2.9369e-01 9.2036e-02 5.7777e-03 3.2152e-02 -6.0000e+00 3.1811e-01 -6.0213e-02 4.9976e-03 1.5761e-02 -6.0000e+00 1.8832e-01 2.0567e-02 2.5986e-03 4.7701e-03 -6.0000e+00 7.8884e-02 1.3395e-04 -2.8623e-04 8.6753e-05 4.5197e-05 -6.0000e+00 5.3303e-03 3.5488e-02 12 9 8 11 32 0 99.93 24.41 0.28 0.03549 0.03334 28 3 1 5 0 1918.560 32.75 20.01 24.41 21.44 4.7 867.83 -4699 3603 95905 -78656 -32364 -93399 -118463 2765 -1517 4568 -46453 -40557 46995 -853 45317 42709 -9287 5038 -22250 -9550 -10042 -42503 1153 44232 14452 11242 -15236 -6451 -14233 -6659 -1831 -1706 13444 -3633 -16942 -13891 -6588 -3789 -2307 5812 -1844 -5970 -1224 3435 6884 -5369 3597 -3731 -436 6031 3682 534 5207 3581 4722 9173 13 1408 235 -3470 907 2985 2597 1149 432 927 743 -854 1511 -727 -103 -64 731 -581 -140 242 -1544 -3704 -1706 237 -1830 268 -2047 -2121 510 -770 356 163 1657 1127 872 -134 262 -268 -513 -741 1250 942 45 642 -1452 -1686 -955 -702 -360 -1125 -556 -519 -1041 559 579 -104 386 395 -11 -837 159 -112 -1202 135 185 522 656 880 -27 398 825 722 87 732 444 185 62 -412 54 63 149 56 174 -294 -65 -414 -863 -38 30 365 -1595 -379 -2071 -3753 30 -19 58 -1015 -964 581 -21 861 961 -385 198 -1227 -487 -522 -3070 58 1569 737 623 -1101 -405 -947 -451 -139 -149 1146 -376 -1879 -1536 -770 -516 -381 1044 -393 -1401 -286 775 1516 -1359 840 -957 -112 1544 1074 161 1623 1225 1671 3215 5 539 88 -1346 353 1259 1237 611 233 473 374 -449 866 -449 -69 -44 488 -369 -88 135 -823 -2046 -1041 153 -1383 224 -1734 -1894 477 -777 371 174 1734 1126 805 -126 234 -248 -490 -812 1426 1221 59 862 -1849 -1943 -1090 -830 -427 -1408 -729 -726 -1480 863 912 -170 616 637 -17 -1220 232 -172 -1870 216 292 846 1028 1316 -39 587 1163 1066 135 1244 767 336 118 -776 108 125 300 116 355 -609 -127 -770 -1666 SS 20240617T072712.8Z 8934.310565 195 1 3.87 2 55.47 95.70 141.31 352.67 0.00 1 0.00 1 0 17 1.044e-02 6.050e-03 1.177e-03 5.924e-04 2.902251e-01 3.022176e-04 3.758775e-03 -6.000000e+00 6.003736e-03 233.58 -2.00 3.84 -2.00 316.24 0.00e+00 4.004250e-04 3.265220e-05 4.784129e-05 -6.000000e+00 2.586534e-04 280.73 -2.00 20.00 -2.00 315.56 0.00e+00 1.759 0.000 302.00 328.00 3 4.8898e-01 7.9376e-04 2.4440e-02 -6.0000e+00 1.5142e-02 1.1692e-02 8.8473e-04 1.6530e-02 -6.0000e+00 1.6399e-02 -4.3810e-03 5.0894e-04 7.9882e-03 -6.0000e+00 9.7083e-03 -1.1205e-03 2.3383e-04 2.1852e-03 -6.0000e+00 4.0683e-03 3.8525e-02 8.2932e-05 1.6172e-05 2.4678e-05 -6.0000e+00 2.7470e-04 3.2995e-02 12 1 1 12 1 1 99.31 24.58 0.29 0.03300 0.03362 122 181 1 5 0 31.410 32.75 20.00 24.58 22.40 4.6 873.87 -1370 -836 -2042 -4018 -4240 -3271 -1856 -1096 -65 -1695 -3071 -1760 -1178 -349 904 528 848 1043 1072 1568 840 934 1162 1096 730 1303 374 -537 -397 626 1166 1210 1434 -1128 -2568 -2207 -1695 -713 -317 -95 -714 -512 -563 -451 -205 -210 -405 -457 -641 174 670 803 1063 983 866 1044 523 502 411 600 959 1265 1606 1481 283 -218 -615 -713 307 396 490 99 197 122 -185 -341 -1135 -1107 -844 -1068 -1086 -1375 -1846 -1509 -992 -591 -97 390 692 434 458 197 -52 122 153 162 659 769 252 -33 -291 -703 -728 -248 -693 -573 -653 -403 104 297 506 344 328 -13 -223 19 -91 60 131 51 -99 173 414 307 663 300 477 636 497 406 203 186 -267 5 -10 -92 140 139 -84 -225 -265 -529 -649 -274 -179 -445 -810 -767 -588 -359 -237 -14 -390 -705 -426 -305 -103 283 181 283 364 390 589 320 352 457 433 303 558 159 -213 -157 250 474 533 652 -526 -1118 -974 -795 -371 -181 -60 -468 -348 -379 -304 -138 -141 -277 -306 -425 117 462 592 796 750 680 834 412 406 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