File name: Pandora82s1_DeBilt_20240801_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20240801T234758.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_DeBilt_20240801_L1_smca1c2d20240415p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20240801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240801T053940.2Z 8979.235882 214 1 55.09 2 76.88 77.66 44.95 101.86 0.00 1 0.00 1 0 25 4.557e-01 2.048e-02 1.800e-01 5.193e-03 5.750636e-01 2.779795e-03 7.378508e-03 -6.000000e+00 2.638660e-01 233.16 -2.00 3.84 -2.00 320.63 0.00e+00 1.121047e-02 1.103975e-03 1.703189e-03 -6.000000e+00 1.242321e-02 283.30 -2.00 20.00 -2.00 319.99 0.00e+00 4.293 0.002 302.00 328.00 3 4.1239e+00 8.6472e-03 5.4661e-02 -6.0000e+00 6.6572e-01 1.3805e-01 1.0811e-02 3.3874e-02 -6.0000e+00 7.2276e-01 -2.1376e-01 9.8191e-03 2.0372e-02 -6.0000e+00 4.2549e-01 8.6578e-02 4.8954e-03 1.2434e-02 -6.0000e+00 1.7814e-01 6.1138e-05 -4.4247e-04 1.4459e-04 1.2625e-04 -6.0000e+00 1.2260e-02 4.7735e-02 12 9 8 11 8 0 96.27 24.63 0.41 0.04774 0.04441 19 2 1 5 0 2899.110 32.75 20.01 24.63 22.67 4.6 874.90 -193831 -184808 -101269 42103 900000 -158266 -144879 900000 -70125 900000 11545 -93310 900000 76230 900000 101677 8299 -11025 272676 -49084 -4004 -91630 900000 900000 7650 72496 14031 -36000 -14309 7708 17666 21736 82576 18833 18371 -3900 11042 7337 6368 50980 7406 -1448 18310 8345 43362 17200 13607 215 13340 8785 13146 13101 18014 14330 5440 14934 1389 5015 1725 -4227 -2010 5716 520 3642 1462 -653 6320 -596 2578 1846 739 -2031 3025 -4017 -6425 3213 -5134 2907 -5028 -190 -4311 -1540 -2148 -2122 627 -507 904 -1650 3415 3473 927 -145 -3627 -3654 -2177 -2332 1737 789 135 -1058 -1749 -1489 -1108 -205 -1652 -1942 -1081 -479 -253 338 490 1298 -323 173 -484 -560 1504 437 -1019 60 921 1314 1540 838 -1374 1367 1662 -318 530 1842 1026 76 602 -652 -96 -501 -118 -151 -265 -254 476 -950 -926 -7842 -7732 -1909 213 900000 -4366 -3663 900000 -967 900000 74 -2059 900000 578 900000 874 201 -357 1379 -2582 -134 -7229 900000 900000 244 1247 433 -1784 -586 292 733 1011 2380 1038 948 -258 709 575 605 3584 873 -198 2167 1123 4232 2253 1892 35 1997 1475 2354 2571 3635 3211 1373 3497 376 1286 447 -1178 -586 1735 189 1418 586 -255 2285 -238 1121 843 368 -1064 1465 -1952 -3184 1302 -2150 1163 -2507 -97 -2650 -1037 -1558 -1623 502 -437 803 -1541 3016 2911 736 -109 -2706 -2849 -1897 -2354 1782 931 170 -1308 -2020 -1543 -1162 -204 -1810 -2238 -1310 -619 -357 487 769 2085 -517 262 -690 -773 2082 646 -1633 98 1479 2029 2303 1208 -1940 1958 2299 -477 822 3120 1899 139 1141 -1326 -208 -1062 -254 -332 -579 -566 995 -1911 -1821 SS 20240801T074531.8Z 8979.323284 257 1 55.14 2 57.72 102.77 28.68 138.78 0.00 1 0.00 1 0 17 2.369e-02 7.795e-03 5.057e-03 1.824e-03 2.721154e-01 9.227722e-04 3.532921e-03 -6.000000e+00 1.358689e-02 233.16 -2.00 3.84 -2.00 317.07 0.00e+00 1.055285e-03 1.233668e-04 6.871839e-05 -6.000000e+00 5.932784e-04 283.30 -2.00 20.00 -2.00 316.31 0.00e+00 1.866 0.000 302.00 328.00 3 5.1377e+00 2.4510e-03 2.4535e-02 -6.0000e+00 3.4201e-02 -7.9430e-03 2.7472e-03 1.5691e-02 -6.0000e+00 3.7054e-02 2.3136e-03 1.6236e-03 7.5537e-03 -6.0000e+00 2.1976e-02 -3.5883e-03 7.8084e-04 2.2130e-03 -6.0000e+00 9.2248e-03 3.4712e-04 3.2038e-04 5.0556e-05 2.2930e-05 -6.0000e+00 6.2362e-04 4.2714e-02 11 9 0 11 8 0 99.47 24.88 0.23 0.04271 0.04512 24 3 1 5 0 2297.110 33.00 20.00 24.88 24.43 4.6 886.94 -8324 -8963 -7647 -3941 8361 -13327 -6913 875 -1388 655 -4195 -2921 2244 2862 5184 3547 -643 -1021 1849 -588 1997 -2810 4386 4618 -1342 987 -572 -1760 -1169 422 1071 1633 2791 -466 -2302 -3167 -1941 -1403 111 973 -783 -821 -444 -602 525 -841 -455 -1153 -260 915 1347 1095 1363 1655 457 1771 597 217 -10 -665 1027 1556 1675 1328 846 -431 -549 -280 652 389 48 -212 359 -147 -800 57 -1146 -831 -1836 -700 -2009 -1391 -2210 -1562 -374 -254 348 322 853 1151 720 512 -902 -459 286 -107 761 704 299 -119 -916 -925 -829 -283 -853 -1087 -286 -374 483 418 678 567 505 87 -335 -309 196 -98 -321 -162 -60 135 434 123 63 430 862 750 564 682 265 -1 -273 -196 85 41 358 94 -48 -26 -273 -735 -795 -1146 -1328 -1115 -498 842 -1681 -891 117 -209 99 -652 -482 405 592 1087 817 -160 -267 490 -165 549 -805 1222 1357 -437 324 -187 -537 -335 123 335 549 1009 -172 -797 -1138 -777 -604 57 521 -456 -497 -275 -374 323 -523 -276 -689 -151 540 851 740 901 1149 328 1282 444 160 -7 -486 776 1270 1386 1162 718 -362 -436 -221 560 355 45 -203 336 -141 -708 48 -890 -627 -1518 -608 -1976 -1403 -2369 -1748 -420 -305 410 389 1022 1379 794 549 -904 -454 304 -120 940 910 403 -155 -1123 -1104 -945 -341 -1064 -1420 -389 -506 683 633 1020 853 763 121 -456 -401 256 -135 -454 -242 -90 200 624 179 87 562 1130 1011 777 1000 389 -2 -420 -298 138 67 591 159 -81 -42 -455 -1184 -1259 SS 20240801T080451.6Z 8979.336708 263 1 55.75 2 54.86 107.10 26.93 146.84 0.00 1 0.00 1 0 17 1.741e-02 7.351e-03 4.175e-03 1.755e-03 2.535064e-01 8.880556e-04 3.283867e-03 -6.000000e+00 9.985063e-03 233.16 -2.00 3.84 -2.00 316.69 0.00e+00 6.677214e-04 1.078030e-04 5.704834e-05 -6.000000e+00 4.359798e-04 283.30 -2.00 20.00 -2.00 315.94 0.00e+00 1.732 0.000 302.00 328.00 3 5.2566e+00 2.3488e-03 2.2772e-02 -6.0000e+00 2.5135e-02 -3.6924e-03 2.6267e-03 1.4520e-02 -6.0000e+00 2.7230e-02 4.4134e-03 1.5290e-03 7.0049e-03 -6.0000e+00 1.6150e-02 -5.9965e-03 7.2013e-04 1.9704e-03 -6.0000e+00 6.7798e-03 3.6165e-04 1.6144e-04 4.8528e-05 2.1114e-05 -6.0000e+00 4.5826e-04 4.2204e-02 11 9 0 11 8 0 97.92 24.94 0.30 0.04220 0.04342 17 2 1 5 0 3279.370 33.00 20.00 24.94 24.89 4.6 890.14 -8002 -5607 -2616 -4126 5351 -7544 -4800 -83 -1121 -1321 -2256 -3992 2596 414 3724 1878 1110 -109 2428 183 1812 -2397 2729 3828 -849 535 -228 -764 -1941 -81 590 2511 3175 -734 -1927 -3093 -1744 -1169 -667 851 -606 -1232 -369 -790 1342 -597 -505 -468 -876 95 438 713 1894 983 520 1580 888 163 440 -193 864 724 1968 1740 -125 -619 -674 -712 148 106 207 -178 831 71 -743 -346 -1542 -457 -1290 -763 -1555 -1782 -1674 -1207 -613 -168 465 289 1077 1121 945 306 -631 -608 30 -108 697 828 290 -415 -468 -884 -928 -236 -829 -815 -328 -398 98 395 841 414 24 91 -250 -4 344 34 -362 -227 132 306 309 247 -189 505 716 611 821 627 39 53 -293 -206 93 9 296 292 -72 -213 -129 -725 -708 -1352 -986 -444 -639 677 -1092 -737 -14 -205 -247 -417 -800 557 94 933 516 317 -33 742 59 578 -792 894 1311 -318 204 -86 -266 -642 -27 209 939 1278 -278 -742 -1236 -710 -557 -351 507 -390 -768 -234 -504 837 -378 -336 -303 -560 61 280 484 1340 739 401 1229 706 128 340 -151 700 594 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