File name: Pandora199s1_Fukuoka_20231004_L2Fit_fout2c4d20230503p1-8.txt File generation date: 20231005T124606.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v4d20230503.txt Level 1 file used: Pandora199s1_Fukuoka_20231004_L1_smca1c4d20230503p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20231004 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session after fiber replacement based on session 3 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1223 305.2633 305.4044 305.5454 305.6865 305.8275 305.9685 306.1095 306.2505 306.3915 306.5325 306.6735 306.8144 306.9554 307.0963 307.2372 307.3781 307.5190 307.6599 307.8008 307.9417 308.0825 308.2234 308.3642 308.5050 308.6458 308.7866 308.9274 309.0682 309.2090 309.3497 309.4905 309.6312 309.7719 309.9126 310.0533 310.1940 310.3347 310.4754 310.6160 310.7567 310.8973 311.0379 311.1785 311.3191 311.4597 311.6003 311.7409 311.8814 312.0220 312.1625 312.3030 312.4435 312.5840 312.7245 312.8650 313.0055 313.1459 313.2864 313.4268 313.5672 313.7077 313.8481 313.9884 314.1288 314.2692 314.4095 314.5499 314.6902 314.8305 314.9709 315.1112 315.2514 315.3917 315.5320 315.6722 315.8125 315.9527 316.0930 316.2332 316.3734 316.5136 316.6537 316.7939 316.9340 317.0742 317.2143 317.3544 317.4946 317.6347 317.7747 317.9148 318.0549 318.1949 318.3350 318.4750 318.6150 318.7550 318.8950 319.0350 319.1750 319.3150 319.4549 319.5949 319.7348 319.8747 320.0146 320.1545 320.2944 320.4343 320.5741 320.7140 320.8538 320.9937 321.1335 321.2733 321.4131 321.5529 321.6926 321.8324 321.9721 322.1119 322.2516 322.3913 322.5310 322.6707 322.8104 322.9501 323.0897 323.2294 323.3690 323.5086 323.6482 323.7878 323.9274 324.0670 324.2066 324.3461 324.4857 324.6252 324.7647 324.9043 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231003T222315.6Z 8676.932819 259 1 38.19 2 76.72 104.22 45.49 273.85 0.00 1 0.00 1 0 17 2.006e-01 1.035e-02 1.370e-01 6.512e-03 4.827661e-01 3.594706e-03 5.463695e-03 -6.000000e+00 1.222230e-01 227.75 -2.00 3.34 -2.00 320.70 0.00e+00 7.418285e-04 1.468285e-03 2.304887e-03 -6.000000e+00 5.611249e-03 290.12 -2.00 20.00 -2.00 319.97 0.00e+00 4.242 0.001 302.00 328.00 3 3.4556e+00 1.1637e-02 4.9622e-02 -6.0000e+00 3.0254e-01 3.7660e-02 1.4605e-02 2.8505e-02 -6.0000e+00 3.2676e-01 -1.1419e-01 1.1821e-02 1.3133e-02 -6.0000e+00 1.9559e-01 4.6901e-02 5.8416e-03 3.4675e-03 -6.0000e+00 8.3299e-02 1.5141e-04 -4.6410e-05 2.1969e-04 5.5492e-05 -6.0000e+00 6.3766e-03 -1.0769e-02 1.0861e-06 12 9 9 12 1 1 99.99 17.10 0.60 -0.01077 -0.01112 39 13 1 5 0 954.480 20.56 15.00 17.10 27.74 5.3 969.89 -44316 -91147 -24940 -60343 10747 -98223 -33490 -93197 -47364 -85727 -7808 -56803 -34761 -28395 -26615 -4135 -26919 -15742 -2985 -6506 -4475 -7791 -29535 8544 -13006 5682 -26950 -12911 -11855 -5387 -20536 -9980 560 -3236 -279 -5630 10578 -1949 6898 2919 5709 -659 5833 3676 6138 -3820 652 2290 964 5896 5087 3838 3013 5958 4013 3944 3714 -886 1445 800 -506 7074 3288 5426 411 2177 -1252 -1293 2148 1847 1622 1853 1896 988 -508 -4602 -2228 -4186 -1885 -2882 -2159 -3040 -1377 -740 -1170 878 1493 1251 444 299 -413 -121 -2027 103 -1167 241 598 337 -267 -159 -1559 -768 -1282 -521 -1720 -1617 -84 -622 714 879 250 -4 0 -563 -23 -986 -92 128 16 631 1079 1288 823 736 80 191 409 1131 -871 -443 -466 -428 190 395 119 474 326 -10 157 -77 -849 -727 -614 -2025 -317 -1045 87 -2381 -464 -2636 -929 -2622 -117 -1574 -923 -852 -922 -129 -1150 -645 -114 -267 -183 -337 -1671 355 -713 266 -1727 -701 -636 -289 -1446 -714 39 -239 -20 -439 794 -198 764 386 804 -105 895 586 964 -668 110 386 170 1055 1001 835 713 1455 1045 1061 1014 -251 395 223 -151 2152 1140 1954 156 785 -462 -501 894 858 809 942 941 466 -223 -1926 -872 -1732 -853 -1516 -1280 -2011 -964 -549 -932 728 1282 1092 384 246 -319 -87 -1464 77 -976 225 630 389 -321 -185 -1707 -776 -1274 -537 -1913 -1901 -103 -822 1014 1355 410 -7 0 -863 -33 -1413 -135 196 27 1040 1758 2037 1265 1088 114 263 563 1648 -1423 -784 -876 -841 388 855 274 1127 794 -26 378 -180 -1894 -1570 SS 20231003T224840.4Z 8676.950467 272 1 46.74 2 71.63 108.16 50.60 276.86 0.00 1 0.00 1 0 17 1.303e-01 1.838e-02 1.548e-01 1.573e-02 3.616052e-01 8.373546e-03 4.228690e-03 -6.000000e+00 7.933323e-02 227.75 -2.00 3.34 -2.00 319.54 0.00e+00 4.031835e-03 2.339177e-03 1.429559e-03 -6.000000e+00 3.643971e-03 290.12 -2.00 20.00 -2.00 318.70 0.00e+00 3.132 0.000 302.00 328.00 3 5.8886e+00 2.3954e-02 3.6011e-02 -6.0000e+00 1.9637e-01 1.0439e-01 2.8189e-02 1.8490e-02 -6.0000e+00 2.1217e-01 -7.1548e-02 1.9955e-02 1.0128e-02 -6.0000e+00 1.2700e-01 2.9377e-02 1.0275e-02 3.9057e-03 -6.0000e+00 5.4028e-02 4.1252e-05 -2.4884e-04 5.2507e-04 5.4017e-05 -6.0000e+00 4.1448e-03 -7.7166e-03 -1.5966e-04 12 8 8 10 0 0 99.87 17.10 0.88 -0.00772 -0.00959 12 3 1 5 0 3894.470 20.56 14.99 17.10 29.66 5.2 984.24 -34148 3493 135 -45395 56873 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-1547 1407 1284 4221 785 1162 -273 -701 -1534 44 3710 198 2570 -1550 3360 -242 991 -2226 -1401 -3163 -396 -1674 -3285 -3523 -416 -2412 1118 438 1562 3343 -2255 932 -22 637 322 -474 344 726 1072 -142 -1201 -228 51 -3196 -656 -1245 -5045 -1975 1582 -1871 2683 1645 1952 -1319 1884 -2195 -1777 962 -853 -1057 1162 2204 1761 2966 -341 1091 -830 746 -1019 874 -478 1175 -504 1477 -2435 -1436 1812 333 1293 -644 4178 -2181 -375 -3841 SS 20231003T231431.6Z 8676.968421 284 1 26.81 2 66.59 112.45 55.77 279.78 0.00 1 0.00 1 0 17 3.254e-02 8.049e-03 8.373e-03 1.634e-03 3.037274e-01 8.657277e-04 3.461373e-03 -6.000000e+00 1.983059e-02 227.75 -2.00 3.34 -2.00 318.42 0.00e+00 1.641102e-03 1.754281e-04 3.174139e-04 -6.000000e+00 9.103983e-04 290.12 -2.00 20.00 -2.00 317.55 0.00e+00 2.497 0.000 302.00 328.00 3 3.2690e+00 2.3525e-03 2.8948e-02 -6.0000e+00 4.9087e-02 5.1855e-03 2.6831e-03 1.5050e-02 -6.0000e+00 5.3016e-02 -1.9158e-02 1.7106e-03 7.4738e-03 -6.0000e+00 3.1734e-02 2.4930e-03 8.7315e-04 2.4041e-03 -6.0000e+00 1.3516e-02 1.1841e-03 -2.0021e-05 5.3827e-05 2.9800e-05 -6.0000e+00 1.0346e-03 -1.1046e-02 -4.9540e-08 12 9 1 12 1 1 99.98 17.11 0.43 -0.01105 -0.01120 58 27 1 5 0 453.870 20.56 15.00 17.11 31.41 5.2 997.10 -4232 -9797 -8054 -11212 -10291 -14408 -10810 -9719 -9328 -11472 -7539 -7893 -5689 -1179 -3031 283 -1500 1977 600 3106 -532 2579 280 1050 -109 -1519 -2457 -2525 -2857 -1895 -348 -1696 -2227 -4219 -3640 -4860 -1541 -2078 265 -325 461 333 788 1140 1314 837 390 529 356 1023 1114 1551 1238 1809 1459 1510 100 297 551 955 1897 2708 1920 919 543 -197 239 536 1090 1057 577 370 713 19 -453 -2051 -2166 -2340 -2173 -2573 -2225 -2467 -2013 -945 -557 -6 578 851 559 776 90 -128 -380 5 -344 385 895 493 -149 -624 -795 -669 -502 -817 -1298 -1289 -575 -77 763 574 553 31 -56 -264 -360 -217 -46 44 104 -35 308 813 684 903 529 579 666 609 252 -283 -331 161 288 353 138 263 501 58 -275 -540 -630 -1024 -255 -668 -539 -730 -621 -897 -696 -684 -706 -919 -599 -681 -549 -126 -374 37 -211 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