File name: Pandora199s1_Fukuoka_20231022_L2Fit_fout2c4d20230503p1-8.txt File generation date: 20231026T022238.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v4d20230503.txt Level 1 file used: Pandora199s1_Fukuoka_20231022_L1_smca1c4d20230503p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20231022 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session after fiber replacement based on session 3 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1223 305.2633 305.4044 305.5454 305.6865 305.8275 305.9685 306.1095 306.2505 306.3915 306.5325 306.6735 306.8144 306.9554 307.0963 307.2372 307.3781 307.5190 307.6599 307.8008 307.9417 308.0825 308.2234 308.3642 308.5050 308.6458 308.7866 308.9274 309.0682 309.2090 309.3497 309.4905 309.6312 309.7719 309.9126 310.0533 310.1940 310.3347 310.4754 310.6160 310.7567 310.8973 311.0379 311.1785 311.3191 311.4597 311.6003 311.7409 311.8814 312.0220 312.1625 312.3030 312.4435 312.5840 312.7245 312.8650 313.0055 313.1459 313.2864 313.4268 313.5672 313.7077 313.8481 313.9884 314.1288 314.2692 314.4095 314.5499 314.6902 314.8305 314.9709 315.1112 315.2514 315.3917 315.5320 315.6722 315.8125 315.9527 316.0930 316.2332 316.3734 316.5136 316.6537 316.7939 316.9340 317.0742 317.2143 317.3544 317.4946 317.6347 317.7747 317.9148 318.0549 318.1949 318.3350 318.4750 318.6150 318.7550 318.8950 319.0350 319.1750 319.3150 319.4549 319.5949 319.7348 319.8747 320.0146 320.1545 320.2944 320.4343 320.5741 320.7140 320.8538 320.9937 321.1335 321.2733 321.4131 321.5529 321.6926 321.8324 321.9721 322.1119 322.2516 322.3913 322.5310 322.6707 322.8104 322.9501 323.0897 323.2294 323.3690 323.5086 323.6482 323.7878 323.9274 324.0670 324.2066 324.3461 324.4857 324.6252 324.7647 324.9043 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231021T215913.6Z 8694.916130 48 1 47.24 2 84.60 106.84 167.55 57.98 0.00 1 0.00 1 0 25 5.940e-01 5.306e-02 5.170e-01 4.865e-02 8.988135e-01 2.881803e-02 1.004884e-02 -6.000000e+00 3.621520e-01 226.40 -2.00 3.34 -2.00 321.96 0.00e+00 -3.070172e-02 1.179684e-02 4.680746e-03 -6.000000e+00 1.651951e-02 288.37 -2.00 20.00 -2.00 321.34 0.00e+00 9.253 0.011 302.00 328.00 3 5.7785e-01 1.0083e-01 1.1547e-01 -6.0000e+00 8.9539e-01 1.6271e+00 1.2350e-01 9.7783e-02 -6.0000e+00 9.7003e-01 -1.7666e+00 7.5348e-02 2.2126e-02 -6.0000e+00 5.7922e-01 6.2369e-01 3.8667e-02 2.7869e-02 -6.0000e+00 2.4660e-01 1.2119e-05 -1.0349e-03 1.4368e-03 4.1680e-04 -6.0000e+00 1.9198e-02 -6.7293e-03 3.1062e-05 12 8 8 10 0 0 33.44 17.55 1.21 -0.00673 -0.01451 27 7 1 5 0 1749.220 20.96 15.00 17.55 16.59 5.8 896.08 85210 9111 -17071 -60549 -38949 94386 -30302 -13967 -42666 87140 -3804 39637 -13115 294834 49603 91268 34245 226441 72130 -46192 19009 13049 -5937 88464 23689 29087 -50403 84611 -98361 167439 121796 49938 53371 -49512 900000 -53299 68359 97906 900000 42021 28433 86935 121692 900000 -24267 -6141 34033 103203 257298 63142 113304 89014 72266 98190 38988 22264 -1632 46620 23946 41758 21405 -33067 95245 26320 14145 3766 1953 27069 80845 30355 12952 22302 42732 -17565 9473 -9024 -1416 -28902 -5580 13809 -13816 12378 -9388 7807 20444 29766 8618 20867 -4093 18535 -15782 2896 -422 -12207 12884 -7819 -7230 -4103 -5045 -9343 2660 -4920 459 2665 -2016 -10195 165 807 -2534 -623 6965 -573 -2685 -2047 -1961 1718 437 -3081 5685 -790 2959 6295 570 6639 -605 -1644 780 -2266 -41 -1261 1728 834 927 -160 59 -2401 2753 707 1400 -3034 1324 -2695 4040 504 -1079 -5024 -2308 4475 -1916 -883 -4046 4131 -271 1879 -1088 13978 2352 4327 1894 10736 3420 -5110 1147 844 -512 4194 1940 2257 -7821 4012 -18654 7939 5775 2368 2530 -6402 900000 -6892 3241 4642 900000 3985 3309 5620 5770 900000 -3765 -741 2640 4893 12199 4082 5372 5371 5607 6348 4873 3455 -324 5425 3199 4320 2676 -7554 6568 3857 2378 698 379 4433 9582 6018 3238 5095 8306 -5148 2066 -2139 -302 -8633 -1508 3601 -5502 4284 -4406 3294 8045 11149 4086 8706 -2115 7206 -8156 1208 -188 -6771 6414 -5560 -5862 -3579 -4641 -8726 2031 -3685 311 1819 -1529 -8894 140 746 -2751 -756 8684 -815 -3947 -2932 -2724 2281 603 -4601 8059 -1194 4167 8208 763 8121 -774 -2089 999 -3342 -69 -2415 3547 1871 2242 -421 166 -7150 7910 2067 3935 -8371 3252 -6554 SS 20231021T220944.1Z 8694.923427 51 1 47.83 2 82.51 108.37 165.74 63.56 0.00 1 0.00 1 0 17 2.766e-01 1.820e-02 1.467e-01 8.875e-03 7.289889e-01 5.158762e-03 8.349713e-03 -6.000000e+00 1.675845e-01 226.40 -2.00 3.34 -2.00 321.91 0.00e+00 8.258505e-03 2.822945e-03 4.567670e-03 -6.000000e+00 7.678861e-03 288.37 -2.00 20.00 -2.00 321.36 0.00e+00 7.105 0.005 302.00 328.00 3 6.2018e-01 1.9975e-02 8.1287e-02 -6.0000e+00 4.1376e-01 7.7696e-01 2.5240e-02 4.1714e-02 -6.0000e+00 4.4756e-01 -1.0869e+00 1.8775e-02 2.2654e-02 -6.0000e+00 2.6790e-01 4.3979e-01 8.9665e-03 8.3455e-03 -6.0000e+00 1.1411e-01 1.2120e-04 -1.4142e-03 2.8008e-04 2.0250e-04 -6.0000e+00 8.7915e-03 -6.2508e-03 -1.0550e-05 12 8 8 10 0 0 15.17 17.55 0.50 -0.00625 -0.01688 116 30 1 5 0 412.230 20.96 15.00 17.55 17.20 5.8 901.41 -58261 -52602 -86674 -86180 -104980 -70991 -74985 -66418 -96561 -61658 -105493 -28758 -81202 -20632 -6244 -4850 -25308 33018 -19012 -25805 -16193 -22056 -5690 -25997 -1942 -19670 -27774 -58656 18864 -24327 14618 -16714 31514 10943 10600 1526 -17455 4990 8362 24719 20215 21894 10521 35699 18872 30445 17130 17122 13022 16529 14372 38063 22237 22954 23853 30256 22855 7333 8617 7281 12209 9139 18287 11436 14382 6766 11933 8215 8830 8549 8306 9698 3249 4553 -1092 -3119 -13054 -4626 -6782 474 -1459 -769 -2851 2163 1607 858 2325 2262 908 -1848 -1880 -5947 -3589 -5155 -4180 -2166 -806 -2018 -776 -1299 -1832 -2993 -1342 -3484 -2867 -2145 -1462 -118 167 930 75 -639 372 205 -1893 -929 -858 -146 -358 1225 1843 2362 2723 2108 809 1384 655 40 66 181 302 -34 -61 111 274 255 922 294 -238 -423 -928 -1779 -1650 -1490 -3341 -2983 -3882 -1731 -1888 -1568 -3115 -1407 -3901 -566 -3322 -568 -177 -153 -1055 805 -793 -1137 -624 -868 -188 -1064 -63 -743 -1092 -3046 460 -1014 483 -868 1091 465 477 75 -1133 298 557 1562 1434 1592 874 2317 1453 2108 1379 1422 1183 1559 1517 3459 2540 2741 2910 3508 2828 1028 1156 989 1669 1431 2928 2128 2663 1341 2272 1727 2055 2212 2286 2652 908 1158 -266 -710 -3219 -1129 -1960 151 -547 -321 -1315 1011 803 455 1261 1241 495 -987 -945 -2985 -1780 -2833 -2623 -1560 -663 -1878 -748 -1228 -1610 -2432 -1029 -2819 -2454 -1940 -1412 -123 196 1216 109 -964 553 296 -2690 -1298 -1238 -220 -567 1933 2827 3473 3862 2911 1097 1822 887 59 112 345 629 -77 -145 283 735 708 2593 833 -662 -1117 -2310 -4271 SS 20231021T222035.0Z 8694.930961 54 1 47.78 2 80.38 109.98 163.78 68.14 0.00 1 0.00 1 0 17 3.935e-01 1.423e-02 5.923e-02 3.051e-03 6.323186e-01 1.726092e-03 7.481684e-03 -6.000000e+00 2.384152e-01 226.40 -2.00 3.34 -2.00 321.47 0.00e+00 4.409720e-03 8.947236e-04 5.590648e-03 -6.000000e+00 1.092403e-02 288.37 -2.00 20.00 -2.00 320.86 0.00e+00 5.702 0.003 302.00 328.00 3 5.5407e-01 6.3190e-03 7.0082e-02 -6.0000e+00 5.8864e-01 3.1519e-01 8.2639e-03 4.7143e-02 -6.0000e+00 6.3671e-01 -4.8084e-01 6.9091e-03 2.2094e-02 -6.0000e+00 3.8112e-01 1.9472e-01 3.2639e-03 5.3897e-03 -6.0000e+00 1.6235e-01 5.6846e-04 -5.8144e-04 9.8498e-05 1.4111e-04 -6.0000e+00 1.2506e-02 -6.8445e-03 -1.7354e-05 12 8 8 10 0 0 16.45 17.56 0.46 -0.00684 -0.01121 283 72 1 5 0 168.790 20.96 15.00 17.56 18.16 5.8 908.36 -127330 -129807 -112485 -130399 -132443 -146556 -124638 -131581 -113862 -135639 -81455 -104896 -73381 -65623 -39792 -36322 -20345 -19733 -29651 -16037 -23749 -19716 -36722 -17858 -23981 -29055 -35968 -22827 -27891 -9749 -18681 -1825 -4160 -10853 -6167 -14132 -4923 4156 4078 9848 16700 10670 14473 13992 15884 10557 10721 12462 10712 8580 9148 12799 13810 10265 10807 11501 9185 6422 3468 6786 5197 7744 8191 9725 6821 6964 2721 5260 5491 5955 5052 3529 2882 482 -840 -4339 -5138 -6733 -3942 -3014 -1523 -2218 -770 -1473 -404 1009 1410 1013 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