File name: Pandora199s1_Fukuoka_20231204_L2Fit_fout2c70d20230726p1-8.txt File generation date: 20231204T151812.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c70p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v70d20230726.txt Level 1 file used: Pandora199s1_Fukuoka_20231204_L1_smca1c70d20230726p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20231204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal after fiber replacement based on Session 7 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1265 305.2675 305.4085 305.5495 305.6905 305.8315 305.9725 306.1135 306.2544 306.3954 306.5363 306.6772 306.8181 306.9591 307.0999 307.2408 307.3817 307.5226 307.6634 307.8042 307.9451 308.0859 308.2267 308.3675 308.5083 308.6490 308.7898 308.9306 309.0713 309.2120 309.3528 309.4935 309.6342 309.7748 309.9155 310.0562 310.1968 310.3375 310.4781 310.6187 310.7593 310.8999 311.0405 311.1811 311.3217 311.4622 311.6028 311.7433 311.8838 312.0243 312.1648 312.3053 312.4458 312.5863 312.7267 312.8672 313.0076 313.1480 313.2884 313.4288 313.5692 313.7096 313.8500 313.9903 314.1307 314.2710 314.4113 314.5517 314.6920 314.8323 314.9725 315.1128 315.2531 315.3933 315.5335 315.6738 315.8140 315.9542 316.0944 316.2346 316.3747 316.5149 316.6550 316.7952 316.9353 317.0754 317.2155 317.3556 317.4957 317.6358 317.7758 317.9159 318.0559 318.1959 318.3359 318.4759 318.6159 318.7559 318.8959 319.0358 319.1758 319.3157 319.4556 319.5956 319.7355 319.8754 320.0152 320.1551 320.2950 320.4348 320.5746 320.7145 320.8543 320.9941 321.1339 321.2736 321.4134 321.5532 321.6929 321.8327 321.9724 322.1121 322.2518 322.3915 322.5312 322.6708 322.8105 322.9501 323.0898 323.2294 323.3690 323.5086 323.6482 323.7878 323.9273 324.0669 324.2064 324.3459 324.4855 324.6250 324.7645 324.9040 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231203T224028.0Z 8737.944769 260 1 48.66 2 84.65 121.11 33.85 246.81 0.00 1 0.00 1 0 25 7.886e-01 8.630e-02 4.869e-01 6.612e-02 9.070960e-01 3.829203e-02 9.464795e-03 -6.000000e+00 4.694797e-01 224.23 -2.00 3.34 -2.00 321.64 0.00e+00 -3.261753e-02 1.224819e-02 7.587802e-03 -6.000000e+00 2.332287e-02 284.12 -2.00 20.00 -2.00 320.91 0.00e+00 9.335 0.012 302.00 328.00 3 1.0661e+00 1.1857e-01 1.2306e-01 -6.0000e+00 1.1609e+00 1.9975e+00 1.4265e-01 1.1679e-01 -6.0000e+00 1.2672e+00 -1.9347e+00 9.0239e-02 2.5858e-02 -6.0000e+00 7.5204e-01 6.0248e-01 4.7495e-02 2.5906e-02 -6.0000e+00 3.2282e-01 6.0396e-06 4.6418e-03 1.8872e-03 3.5488e-04 -6.0000e+00 2.4115e-02 1.6839e-02 0.0000e+00 12 8 8 10 0 0 49.29 18.43 1.41 0.01684 0.05172 18 5 1 5 0 2702.680 21.79 14.99 18.43 999.00 -9.0 -9.00 900000 11712 298631 49635 900000 -22942 79527 66019 900000 -44832 900000 -15388 900000 -8828 900000 -15509 900000 323494 87262 241645 42751 -6125 -13885 92145 126345 35070 -51029 304218 -58910 900000 -44779 900000 -29721 -9050 55086 -21901 315950 226605 900000 107993 205844 -1630 75310 1280 111961 15490 -11967 -36255 70407 -33715 11256 -38589 89261 102989 43106 135795 142472 34236 -11100 46278 -8013 160610 -10513 83529 39535 100744 -25781 39593 -16174 66277 38342 43327 31881 -2845 9111 -42343 35472 822 23963 -44247 14111 -28753 30957 3076 50884 40391 8612 15555 38292 -12995 -6461 18054 -11131 7992 -11754 13486 -9942 11311 -2254 1173 -11957 2156 -16724 9776 -1341 -2278 13964 -6660 5187 8637 16879 -6298 8061 -6206 1637 -7864 4663 -5122 11360 -4437 -940 -6384 2369 10208 -368 571 -6958 7392 -6126 714 -2690 4080 -4485 1025 370 3424 1414 13 -301 -192 -4561 2979 900000 1217 19214 3193 900000 -2583 5117 4248 900000 -9855 900000 -2558 900000 -1420 900000 -2661 900000 20814 5614 15547 3209 -788 -2233 5929 8129 3949 -11491 19573 -10739 900000 -7683 900000 -4621 -1165 3544 -3203 20328 14580 900000 8212 13244 -362 7048 225 7204 1993 -1960 -7634 5354 -7888 1843 -11286 7831 8433 6808 8737 9167 5407 -2467 5414 -1640 10334 -2583 8306 6012 8250 -7841 6947 -5582 10854 8522 8870 6713 -749 1865 -13374 5187 187 5046 -21481 4374 -15136 9597 1332 14286 12994 3828 6278 12811 -6157 -2721 6505 -5729 3856 -8016 8243 -7909 8660 -1987 936 -9771 1401 -13020 6164 -1001 -1817 10242 -6728 5340 9724 19005 -9239 10165 -8745 2075 -11031 6001 -7612 14618 -6537 -1276 -8790 2911 11296 -441 673 -9491 10083 -11076 1355 -5764 8820 -11457 2670 1024 9428 4013 36 -820 -486 -11240 6651 SS 20231203T225126.9Z 8737.952395 263 1 48.09 2 82.71 122.76 35.96 249.44 0.00 1 0.00 1 0 25 3.148e-01 2.113e-02 2.874e-01 1.304e-02 7.968721e-01 7.449031e-03 8.844820e-03 -6.000000e+00 1.844933e-01 224.23 -2.00 3.34 -2.00 322.11 0.00e+00 -3.940411e-03 4.287229e-03 1.101027e-02 -6.000000e+00 8.351900e-03 284.11 -2.00 20.00 -2.00 321.61 0.00e+00 7.275 0.006 302.00 328.00 3 1.2015e+00 2.9682e-02 1.0600e-01 -6.0000e+00 4.5410e-01 8.3422e-01 3.8081e-02 9.6752e-02 -6.0000e+00 4.9316e-01 -1.2180e+00 3.0454e-02 3.1810e-02 -6.0000e+00 2.9486e-01 4.8777e-01 1.4402e-02 9.0081e-03 -6.0000e+00 1.2605e-01 5.6689e-05 -5.3217e-04 3.9215e-04 1.3581e-04 -6.0000e+00 9.4244e-03 1.6089e-02 0.0000e+00 12 8 8 10 0 0 16.88 18.43 0.59 0.01609 0.01209 82 21 1 5 0 586.340 21.79 15.00 18.43 999.00 -9.0 -9.00 -68245 -44777 -29701 -139725 -25743 -96794 -49660 -78056 20529 -56980 -22903 -43473 -26001 -51329 -71921 -19276 13493 -27218 36332 -10257 1118 -15435 -38571 168185 -60516 47698 -46937 12981 -78189 -16867 -27481 13742 23198 31624 -8541 -3493 8544 18054 13917 25830 61181 14189 57536 7713 21622 3245 16157 30922 25030 1271 28742 22167 15075 40162 14690 44277 19599 19686 -12524 47074 6756 24755 18705 24463 23153 19797 12298 17188 13711 12354 12151 2348 6719 2116 5037 -1178 12550 -8875 -3368 -833 5382 1932 4426 -4240 638 1960 -17 3316 823 -3525 -308 -4308 -7366 -6421 -4645 -2057 -1823 424 -2105 -2230 -5372 -2802 -4310 -1850 -2116 -3409 -1670 -2088 2140 148 1134 -91 -197 -2016 64 -1623 -79 1097 1788 902 3243 1999 2230 2932 189 -373 -1480 2299 -168 -40 -823 249 -104 437 -204 142 788 -12 261 -687 330 -2253 -1807 -949 -503 -6216 -327 -2461 -842 -1902 261 -1207 -397 -1055 -631 -1898 -3740 -646 343 -1069 756 -332 31 -499 -1649 2138 -3566 937 -2224 315 -4698 -604 -1270 476 777 950 -365 -145 355 814 772 1433 2545 967 2526 544 1299 232 1027 1751 1591 112 2126 2113 1667 3676 1811 4165 2342 2252 -1878 3829 867 2958 2663 3545 3443 3020 2079 3015 2823 2858 2965 630 1631 489 1012 -232 2153 -2076 -878 -251 1765 734 1772 -1972 300 957 -9 1648 407 -1721 -137 -1944 -3548 -3428 -2846 -1441 -1471 372 -1962 -1998 -4521 -2091 -3178 -1397 -1711 -2969 -1541 -2144 2399 192 1589 -134 -289 -2908 88 -2256 -112 1629 2746 1394 4728 2833 3061 3884 249 -485 -2024 3413 -295 -79 -1775 567 -255 1144 -570 406 2273 -35 731 -1817 805 -5406 SS 20231203T230214.5Z 8737.959890 266 1 47.83 2 80.84 124.43 38.07 251.82 0.00 1 0.00 1 0 17 4.024e-01 1.527e-02 1.339e-01 4.954e-03 6.996219e-01 2.781862e-03 8.825579e-03 -6.000000e+00 2.358049e-01 224.23 -2.00 3.34 -2.00 321.76 0.00e+00 4.886657e-03 1.538368e-03 1.013534e-02 -6.000000e+00 1.067401e-02 284.11 -2.00 20.00 -2.00 321.23 0.00e+00 5.961 0.003 302.00 328.00 3 1.2340e+00 1.0497e-02 8.5806e-02 -6.0000e+00 5.8040e-01 3.9225e-01 1.4219e-02 7.5876e-02 -6.0000e+00 6.3031e-01 -6.1272e-01 1.2981e-02 3.3761e-02 -6.0000e+00 3.7686e-01 2.5088e-01 6.0392e-03 6.8413e-03 -6.0000e+00 1.6111e-01 2.1055e-04 -2.8028e-04 1.5301e-04 2.1092e-04 -6.0000e+00 1.2045e-02 1.5747e-02 0.0000e+00 12 8 8 10 0 0 91.12 18.42 0.63 0.01575 0.01364 157 40 1 5 0 304.580 21.79 15.00 18.42 999.00 -9.0 -9.00 -126795 -50269 -115837 -70670 -107600 -88798 -151808 -129867 -140532 -120614 -160987 -106084 -82412 -61980 -76567 -36847 -25635 -49278 -27061 -43040 -34642 -52174 -30932 -30629 -30219 -59727 -38586 -59601 -30316 -50504 -25777 -18046 -7572 -15952 -16865 -5138 -5719 18395 3024 28309 9086 28979 13738 23273 8760 16458 5398 11940 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