File name: Pandora106s1_Innsbruck_20230716_L2Fit_fwvt1c6d20220727p1-8.txt File generation date: 20230717T005756.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v6d20220727.txt Level 1 file used: Pandora106s1_Innsbruck_20230716_L1_smca1c6d20220727p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20230716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1798 Nominal wavelengths inside fitting window [nm]: 492.1061 492.2279 492.3496 492.4714 492.5931 492.7149 492.8366 492.9582 493.0799 493.2016 493.3232 493.4448 493.5665 493.6880 493.8096 493.9312 494.0527 494.1742 494.2958 494.4172 494.5387 494.6602 494.7816 494.9031 495.0245 495.1459 495.2672 495.3886 495.5099 495.6313 495.7526 495.8739 495.9952 496.1164 496.2377 496.3589 496.4801 496.6013 496.7225 496.8437 496.9648 497.0859 497.2071 497.3281 497.4492 497.5703 497.6913 497.8124 497.9334 498.0544 498.1754 498.2963 498.4173 498.5382 498.6591 498.7800 498.9009 499.0218 499.1426 499.2635 499.3843 499.5051 499.6259 499.7466 499.8674 499.9881 500.1089 500.2296 500.3502 500.4709 500.5916 500.7122 500.8328 500.9534 501.0740 501.1946 501.3151 501.4357 501.5562 501.6767 501.7972 501.9176 502.0381 502.1585 502.2789 502.3993 502.5197 502.6401 502.7605 502.8808 503.0011 503.1214 503.2417 503.3620 503.4822 503.6025 503.7227 503.8429 503.9631 504.0832 504.2034 504.3235 504.4436 504.5637 504.6838 504.8039 504.9240 505.0440 505.1640 505.2840 505.4040 505.5240 505.6439 505.7639 505.8838 506.0037 506.1236 506.2434 506.3633 506.4831 506.6029 506.7227 506.8425 506.9623 507.0820 507.2018 507.3215 507.4412 507.5609 507.6805 507.8002 507.9198 508.0394 508.1590 508.2786 508.3982 508.5177 508.6372 508.7568 508.8763 508.9957 509.1152 509.2347 509.3541 509.4735 509.5929 509.7123 509.8316 509.9510 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Zenith motor temperature [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230716T040234.2Z 8597.168451 116 1 49.95 2 86.72 61.53 71.08 69.97 0.00 1 0.00 1 0 22 4.048e-03 4.015e-03 1.806e-04 1.801e-04 2.007244e+04 1.475208e+01 1.266307e+03 -6.000000e+00 2.542490e+02 282.71 -2.00 20.00 -2.00 505.41 0.00e+00 2.562578e-03 5.339155e-06 1.706610e-04 -6.000000e+00 1.202032e-04 282.71 -2.00 20.00 -2.00 501.00 0.00e+00 7.188895e-01 3.721626e-03 1.408264e-01 -6.000000e+00 8.624402e-02 233.13 -2.00 3.66 -2.00 502.51 0.00e+00 12.897 0.044 489.00 513.00 1 3.4129e+00 2.8676e-04 2.2026e-02 -6.0000e+00 6.6687e-03 -7.0473e-02 6.8827e-05 3.5316e-03 -6.0000e+00 1.6609e-03 1.0353e-02 1.5738e-03 2.2631e-05 1.0543e-04 -6.0000e+00 6.1885e-04 7.7903e-03 -1.3289e-04 11 8 0 10 0 0 -6.28 18.45 2.30 0.00779 0.01871 403 81 1 4 0 123.940 22.40 15.00 18.45 28.53 59.10 58.60 37.1 962.51 170 195 337 681 712 856 864 858 735 533 375 267 187 142 194 142 60 42 118 239 366 333 372 253 46 -187 -247 -243 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15 -40 -5 134 548 875 1076 980 682 475 345 426 470 514 550 467 465 442 379 190 114 146 160 171 206 101 35 82 195 251 358 258 282 233 183 96 -49 -79 -118 -189 -292 -405 SQ 20230716T041148.9Z 8597.174872 119 1 27.20 2 85.33 63.18 69.64 71.43 0.00 1 0.00 1 0 22 3.147e-03 3.134e-03 1.513e-04 1.510e-04 1.670182e+04 1.211420e+01 1.068575e+03 -6.000000e+00 1.976734e+02 282.71 -2.00 20.00 -2.00 505.40 0.00e+00 2.032556e-03 4.468120e-06 1.386750e-04 -6.000000e+00 9.344988e-05 282.71 -2.00 20.00 -2.00 500.91 0.00e+00 6.454687e-01 3.135678e-03 1.182902e-01 -6.000000e+00 6.704268e-02 233.13 -2.00 3.66 -2.00 502.44 0.00e+00 10.314 0.022 489.00 513.00 1 2.8234e+00 2.4170e-04 1.7523e-02 -6.0000e+00 5.1841e-03 -6.0857e-02 5.8242e-05 2.9426e-03 -6.0000e+00 1.2908e-03 2.6756e-02 1.2291e-03 1.9620e-05 8.8351e-05 -6.0000e+00 4.8113e-04 1.0073e-03 -7.8671e-05 10 0 0 10 0 0 -2.60 18.46 1.39 0.00101 0.00953 513 104 1 4 0 53.020 22.40 14.99 18.46 28.98 59.60 55.90 36.8 963.76 291 249 318 481 578 594 609 622 541 387 287 238 211 237 261 190 31 7 99 155 262 271 270 149 -67 -273 -304 -166 -42 54 54 -217 -419 -519 -405 -280 -137 -54 61 38 44 -23 -33 -119 -128 -198 -321 -406 -415 -369 -250 -235 -266 -376 -440 -268 -49 214 366 371 327 197 161 132 61 -45 -50 -90 -112 -158 -247 -388 -549 -569 -507 -408 -336 -329 -323 -345 -319 -308 -384 -447 -402 -253 -100 84 140 6 -198 -258 -159 -1 21 -125 -197 -242 -224 -217 -401 -678 -821 -754 -460 -114 58 55 -13 0 114 386 662 796 669 404 249 219 302 457 454 390 324 278 256 229 72 41 110 101 178 194 219 138 153 165 162 299 226 204 168 102 -27 -137 -106 -71 -28 -84 -190 267 233 295 457 546 572 595 611 531 378 278 228 201 224 247 182 30 7 97 154 261 272 272 151 -66 -269 -306 -164 -41 52 52 -211 -416 -511 -405 -280 -138 -54 60 38 43 -23 -34 -123 -129 -199 -330 -411 -413 -360 -247 -230 -262 -365 -436 -271 -50 215 368 375 332 201 164 133 62 -45 -51 -90 -112 -156 -245 -387 -552 -573 -509 -406 -332 -322 -314 -335 -311 -303 -381 -448 -405 -249 -98 85 137 6 -197 -256 -156 -1 21 -121 -186 -223 -211 -200 -379 -646 -812 -747 -464 -116 59 57 -13 0 116 394 679 822 697 415 257 226 309 475 467 398 331 284 263 236 75 42 113 103 180 196 222 141 158 169 170 317 238 217 180 110 -29 -147 -113 -75 -29 -88 -200 SQ 20230716T041216.2Z 8597.175187 119 2 27.20 2 85.26 63.26 69.57 71.50 0.00 1 0.00 1 0 22 3.121e-03 3.105e-03 1.469e-04 1.466e-04 1.657409e+04 1.171071e+01 1.062143e+03 -6.000000e+00 1.960435e+02 282.71 -2.00 20.00 -2.00 505.39 0.00e+00 2.005755e-03 4.336637e-06 1.369282e-04 -6.000000e+00 9.267771e-05 282.71 -2.00 20.00 -2.00 500.91 0.00e+00 6.423067e-01 3.042277e-03 1.168444e-01 -6.000000e+00 6.648662e-02 233.13 -2.00 3.66 -2.00 502.43 0.00e+00 10.207 0.022 489.00 513.00 1 2.7805e+00 2.3448e-04 1.7320e-02 -6.0000e+00 5.1412e-03 -6.0175e-02 5.6581e-05 2.9118e-03 -6.0000e+00 1.2800e-03 2.8348e-02 1.1742e-03 1.9121e-05 8.7083e-05 -6.0000e+00 4.7716e-04 5.9981e-04 -7.2058e-05 10 0 0 10 0 0 -6.99 18.46 1.34 0.00060 0.00874 513 104 1 4 0 53.020 22.40 15.00 18.46 28.98 59.60 55.90 36.8 963.76 306 245 302 453 556 606 576 619 551 381 311 242 197 204 273 183 32 3 74 176 260 257 262 152 -56 -294 -281 -198 5 69 65 -177 -415 -506 -392 -256 -140 -32 40 42 30 2 -42 -130 -135 -206 -334 -420 -433 -361 -235 -184 -240 -333 -417 -291 -31 195 348 405 332 186 149 119 67 -51 -85 -125 -117 -120 -264 -347 -531 -562 -498 -372 -322 -342 -360 -331 -309 -264 -418 -479 -433 -256 -85 72 117 -16 -195 -277 -130 5 8 -124 -165 -252 -228 -220 -374 -678 -847 -768 -446 -93 92 80 26 5 116 365 651 779 660 397 249 215 307 397 450 431 310 267 266 232 77 66 91 117 204 258 215 171 127 170 164 282 203 219 190 78 -54 -112 -107 -105 -61 -75 -204 280 227 279 429 524 582 561 607 540 371 301 232 187 192 258 175 31 3 72 174 258 257 263 154 -56 -298 -281 -196 5 67 62 -172 -411 -497 -390 -256 -140 -32 39 42 30 2 -42 -133 -139 -207 -342 -424 -430 -361 -231 -180 -235 -331 -413 -293 -32 195 350 408 336 189 152 121 67 -52 -86 -124 -116 -118 -261 -345 -531 -565 -498 -370 -317 -333 -349 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