File name: Pandora106s1_Innsbruck_20230904_L2Fit_fout2c9d20221125p1-8.txt File generation date: 20230905T121851.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20230904_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20230904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0714 305.2123 305.3533 305.4943 305.6352 305.7761 305.9171 306.0580 306.1989 306.3398 306.4807 306.6215 306.7624 306.9032 307.0441 307.1849 307.3257 307.4666 307.6074 307.7481 307.8889 308.0297 308.1705 308.3112 308.4519 308.5927 308.7334 308.8741 309.0148 309.1555 309.2962 309.4368 309.5775 309.7181 309.8588 309.9994 310.1400 310.2806 310.4212 310.5618 310.7024 310.8430 310.9835 311.1241 311.2646 311.4051 311.5456 311.6861 311.8266 311.9671 312.1076 312.2481 312.3885 312.5290 312.6694 312.8098 312.9502 313.0906 313.2310 313.3714 313.5118 313.6521 313.7925 313.9328 314.0732 314.2135 314.3538 314.4941 314.6344 314.7747 314.9149 315.0552 315.1955 315.3357 315.4759 315.6161 315.7564 315.8966 316.0367 316.1769 316.3171 316.4573 316.5974 316.7375 316.8777 317.0178 317.1579 317.2980 317.4381 317.5782 317.7182 317.8583 317.9983 318.1384 318.2784 318.4184 318.5584 318.6984 318.8384 318.9784 319.1184 319.2583 319.3983 319.5382 319.6781 319.8180 319.9579 320.0978 320.2377 320.3776 320.5174 320.6573 320.7971 320.9370 321.0768 321.2166 321.3564 321.4962 321.6360 321.7758 321.9155 322.0553 322.1950 322.3347 322.4745 322.6142 322.7539 322.8936 323.0332 323.1729 323.3126 323.4522 323.5918 323.7315 323.8711 324.0107 324.1503 324.2899 324.4294 324.5690 324.7086 324.8481 324.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230904T060521.8Z 8647.253724 254 1 34.97 2 75.92 94.56 52.63 249.53 0.00 1 0.00 1 0 30 8.392e-02 7.964e-03 1.106e-02 1.056e-03 4.577423e-01 6.365059e-04 5.649736e-03 -6.000000e+00 5.870483e-02 229.84 -2.00 3.66 -2.00 319.19 0.00e+00 1.739677e-03 1.631111e-04 6.575389e-04 -6.000000e+00 2.561690e-03 281.19 -2.00 20.00 -2.00 318.52 0.00e+00 4.020 0.001 302.00 328.00 3 1.7847e+00 1.7769e-03 4.5156e-02 -6.0000e+00 1.4624e-01 6.2036e-02 2.0419e-03 2.5868e-02 -6.0000e+00 1.5749e-01 -5.8320e-02 1.4309e-03 1.2317e-02 -6.0000e+00 9.3657e-02 1.8661e-02 7.1257e-04 3.8539e-03 -6.0000e+00 3.7905e-02 1.2517e-03 -1.3569e-03 4.3227e-05 6.5489e-05 -6.0000e+00 3.5757e-03 4.1756e-02 0.0000e+00 12 9 1 12 1 1 86.67 18.17 0.17 0.04176 0.03156 168 49 1 5 0 206.900 22.19 15.00 18.17 23.46 54.40 52.90 38.7 933.77 -20827 -64492 -24532 -16633 -33778 -23764 -29077 -13164 -14090 -16887 -13755 -16716 -1988 -9841 -3219 -4969 -2669 -1753 1925 150 -5814 -1511 -3862 -2460 -3208 -2778 -2606 -2381 41 -2000 992 -1990 -252 3044 2403 1015 1908 792 -2707 -724 -47 -159 -659 0 449 1098 612 695 1763 2023 1152 2087 1086 1242 571 1244 553 305 1661 1068 1624 1066 51 87 706 1198 1798 1584 655 49 -1325 -1142 -903 -879 -364 430 1687 1162 602 -1196 -765 -957 -1218 -697 -1160 -1327 -1095 -1100 -1127 -461 375 1494 1674 1637 1284 702 -781 -920 -1048 -396 179 901 523 -12 -371 -42 -67 101 -38 -709 -621 -483 6 639 1120 1265 757 -96 -642 -592 -698 -398 -371 -148 580 1253 1038 877 226 242 313 635 216 190 -23 -321 -647 -400 -650 -348 106 266 900000 -515 -2689 -707 -438 -1040 -673 -922 -388 -456 -607 -524 -744 -89 -563 -200 -354 -204 -143 160 13 -560 -144 -393 -260 -357 -315 -297 -270 5 -244 128 -264 -35 428 351 160 332 161 -660 -196 -14 -50 -198 0 138 340 193 223 579 700 432 836 470 568 274 610 277 154 830 550 806 570 29 53 430 723 1087 999 447 34 -982 -863 -672 -624 -241 285 1072 762 430 -901 -640 -825 -1139 -695 -1159 -1397 -1191 -1210 -1221 -477 390 1469 1620 1641 1311 797 -932 -1179 -1385 -514 221 1059 607 -14 -462 -55 -88 142 -55 -1082 -987 -776 10 960 1704 1889 1149 -143 -1000 -942 -1114 -621 -563 -227 857 1799 1504 1326 347 399 520 1106 396 350 -44 -615 -1269 -785 -1264 -690 203 499 900000 SS 20230904T061445.5Z 8647.260248 257 1 49.91 2 74.33 96.33 54.06 251.62 0.00 1 0.00 1 0 25 4.341e-02 7.171e-03 4.304e-03 5.280e-04 4.190955e-01 3.181686e-04 5.213995e-03 -6.000000e+00 3.036819e-02 229.84 -2.00 3.66 -2.00 318.84 0.00e+00 4.643460e-04 7.331532e-05 6.096770e-04 -6.000000e+00 1.325118e-03 281.19 -2.00 20.00 -2.00 318.16 0.00e+00 3.638 0.001 302.00 328.00 3 1.1619e+00 8.7480e-04 4.0965e-02 -6.0000e+00 7.5649e-02 3.9230e-02 9.9206e-04 2.3400e-02 -6.0000e+00 8.1469e-02 -4.0376e-02 6.6293e-04 1.1244e-02 -6.0000e+00 4.8448e-02 1.1887e-02 3.2836e-04 3.1389e-03 -6.0000e+00 1.9609e-02 3.4717e-03 -1.2000e-03 2.1846e-05 5.7510e-05 -6.0000e+00 1.8496e-03 4.1372e-02 0.0000e+00 11 8 0 10 0 0 85.43 18.18 0.16 0.04137 0.03235 657 133 1 5 0 75.950 22.19 15.00 18.18 23.78 54.40 51.10 38.8 935.45 -16124 -25671 -15334 -12454 -18028 -13683 -13601 -8143 -9949 -11369 -6103 -8544 -2927 -5011 -2456 -1624 -1317 -48 -200 1152 -814 318 -1075 -1920 -989 -2249 -711 -1342 555 -160 -91 -1334 -1232 319 284 1093 1045 301 -937 -761 -508 -729 -469 -383 -221 -281 140 628 975 1276 924 1298 1047 1086 465 538 584 675 1426 1501 1575 758 -292 -175 235 1261 1509 1437 533 -254 -918 -1157 -997 -750 -305 578 1548 1095 465 -613 -828 -933 -979 -682 -821 -986 -922 -1142 -942 -407 408 1327 1653 1590 1253 592 -527 -929 -990 -431 252 818 531 -71 -231 -56 -29 67 -106 -586 -646 -499 -70 592 1229 1223 795 11 -585 -775 -797 -528 -476 -150 540 1239 1098 789 323 265 248 632 248 83 -12 -267 -507 -552 -614 -237 72 283 900000 -552 -1045 -577 -449 -675 -499 -527 -326 -441 -551 -305 -490 -183 -371 -203 -149 -131 -5 -22 131 -97 39 -139 -239 -128 -301 -94 -177 80 -22 -14 -217 -213 56 52 209 223 75 -273 -229 -167 -254 -169 -141 -82 -105 52 237 376 516 400 602 520 525 236 280 308 357 753 809 889 460 -190 -110 149 842 1008 925 371 -192 -740 -957 -812 -583 -221 389 1073 778 332 -492 -690 -855 -971 -677 -867 -1098 -1000 -1256 -1019 -447 421 1293 1682 1563 1331 655 -647 -1156 -1267 -541 320 990 634 -87 -297 -71 -39 97 -155 -911 -991 -769 -110 893 1773 1732 1142 17 -913 -1240 -1280 -831 -728 -220 803 1788 1592 1190 492 432 406 1082 425 149 -23 -499 -971 -1064 -1171 -440 136 523 900000 SS 20230904T062118.8Z 8647.264800 261 1 49.92 2 73.23 97.58 55.08 253.04 0.00 1 0.00 1 0 25 2.928e-02 7.038e-03 2.630e-03 3.903e-04 3.932895e-01 2.350510e-04 4.901330e-03 -6.000000e+00 2.048304e-02 229.84 -2.00 3.66 -2.00 318.56 0.00e+00 4.867523e-04 4.931073e-05 4.784711e-04 -6.000000e+00 8.937734e-04 281.19 -2.00 20.00 -2.00 317.88 0.00e+00 3.413 0.001 302.00 328.00 3 8.1807e-01 6.4027e-04 3.8389e-02 -6.0000e+00 5.1024e-02 2.8400e-02 7.2289e-04 2.1832e-02 -6.0000e+00 5.4950e-02 -3.3822e-02 4.6745e-04 1.0532e-02 -6.0000e+00 3.2678e-02 9.4837e-03 2.2973e-04 2.9596e-03 -6.0000e+00 1.3226e-02 6.2100e-03 -1.1293e-03 1.6238e-05 5.2821e-05 -6.0000e+00 1.2475e-03 4.1314e-02 0.0000e+00 11 8 0 10 0 0 93.71 18.18 0.21 0.04131 0.03283 1066 215 1 5 0 46.820 22.19 15.00 18.18 24.19 53.60 52.60 38.7 937.65 -11816 -15238 -10772 -9856 -10476 -9567 -8963 -7123 -6460 -6696 -5591 -4897 -3384 -2582 -2294 -1385 -979 -350 313 397 253 91 182 -864 -764 -1211 -1166 -324 138 971 129 -765 -348 -25 624 774 1222 194 -504 -891 -749 -673 -690 -474 -388 -243 -38 437 782 848 914 1092 1074 716 679 403 364 863 1349 1582 1537 636 -170 -151 80 942 1481 1152 495 -285 -1009 -1231 -1118 -674 -445 700 1429 1171 594 -432 -799 -999 -861 -725 -813 -998 -979 -1046 -948 -353 293 1357 1594 1660 1279 677 -462 -996 -949 -438 318 818 529 -43 -226 -104 -33 74 -146 -607 -605 -526 -126 547 1173 1195 790 -38 -581 -724 -740 -491 -437 -129 446 1222 1132 733 369 274 321 547 315 68 8 -281 -555 -567 -567 -216 72 359 900000 -504 -724 -500 -446 -467 -429 -424 -360 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