File name: Pandora187s1_PittsburghPA_20211106_L2Fit_fwvt1c2d20210902p1-8.txt File generation date: 20231128T180802.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v2d20210902.txt Level 1 file used: Pandora187s1_PittsburghPA_20211106_L1_smca1c2d20210902p1-8.txt.bz2 Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20211106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.1177 492.2395 492.3614 492.4832 492.6050 492.7267 492.8485 492.9702 493.0920 493.2137 493.3354 493.4570 493.5787 493.7003 493.8219 493.9435 494.0651 494.1867 494.3083 494.4298 494.5513 494.6728 494.7943 494.9158 495.0372 495.1587 495.2801 495.4015 495.5229 495.6442 495.7656 495.8869 496.0083 496.1296 496.2508 496.3721 496.4934 496.6146 496.7358 496.8570 496.9782 497.0994 497.2205 497.3416 497.4628 497.5839 497.7049 497.8260 497.9470 498.0681 498.1891 498.3101 498.4311 498.5520 498.6730 498.7939 498.9148 499.0357 499.1566 499.2775 499.3983 499.5191 499.6399 499.7607 499.8815 500.0023 500.1230 500.2437 500.3644 500.4851 500.6058 500.7265 500.8471 500.9677 501.0883 501.2089 501.3295 501.4500 501.5706 501.6911 501.8116 501.9321 502.0525 502.1730 502.2934 502.4139 502.5343 502.6546 502.7750 502.8953 503.0157 503.1360 503.2563 503.3766 503.4968 503.6171 503.7373 503.8575 503.9777 504.0979 504.2181 504.3382 504.4583 504.5784 504.6985 504.8186 504.9387 505.0587 505.1787 505.2987 505.4187 505.5387 505.6586 505.7786 505.8985 506.0184 506.1383 506.2581 506.3780 506.4978 506.6176 506.7374 506.8572 506.9770 507.0967 507.2165 507.3362 507.4559 507.5756 507.6952 507.8149 507.9345 508.0541 508.1737 508.2933 508.4128 508.5324 508.6519 508.7714 508.8909 509.0103 509.1298 509.2492 509.3686 509.4880 509.6074 509.7268 509.8461 509.9655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211106T122713.7Z 7980.518909 62 1 45.83 2 85.37 115.82 106.88 105.58 0.00 1 0.00 1 0 15 2.744e-03 2.732e-03 5.377e-04 5.372e-04 2.601261e+03 3.718041e+01 1.713579e+02 -6.000000e+00 1.777805e+02 280.46 -2.00 20.00 -2.00 505.35 0.00e+00 2.237225e-03 1.597899e-05 1.226525e-04 -6.000000e+00 8.280882e-05 280.46 -2.00 20.00 -2.00 500.81 0.00e+00 8.726868e-01 1.133692e-02 3.107936e-02 -6.000000e+00 5.912514e-02 223.99 -2.00 3.49 -2.00 502.35 0.00e+00 10.393 0.020 489.00 513.00 1 4.0935e+00 8.7864e-04 1.5226e-02 -6.0000e+00 4.5896e-03 -8.1232e-03 2.1121e-04 9.8736e-04 -6.0000e+00 1.1204e-03 7.0497e-03 1.2252e-03 8.8201e-05 8.0367e-05 -6.0000e+00 4.6118e-04 2.4388e-03 -6.0072e-05 0 0 0 10 0 0 99.86 18.71 1.58 0.00244 0.01094 94 29 1 4 0 487.400 22.09 14.99 18.71 3.91 11.7 847.13 -534 -353 -87 -112 11 247 443 380 256 200 28 6 -101 -176 -169 -107 109 72 68 119 94 242 378 411 448 237 130 -78 -302 -465 -323 -191 138 115 1 -108 -97 -63 16 89 155 190 279 344 268 216 14 -3 -210 -510 -631 -567 -510 -263 -144 -171 -58 27 131 202 494 491 476 310 236 35 7 -46 -247 -350 -320 -107 -22 -75 -160 -329 -463 -338 -260 -254 -376 -384 -358 -191 -162 -190 -143 -129 2 198 370 386 258 157 45 -75 -198 -315 -347 -429 -405 -257 -225 -222 -346 -478 -350 -94 33 209 212 239 274 360 489 485 479 342 383 245 255 329 411 371 206 113 111 124 161 36 -113 -218 -127 -115 6 10 -16 -38 -5 123 132 198 170 85 -86 -206 -416 -481 -285 -499 -334 -84 -111 11 244 442 380 256 199 28 6 -98 -169 -163 -104 107 72 69 122 94 241 378 412 448 236 128 -76 -303 -463 -321 -191 135 114 1 -109 -98 -64 16 90 156 193 285 353 276 221 15 -3 -209 -499 -610 -544 -491 -256 -142 -172 -59 27 135 201 493 507 490 318 240 35 7 -45 -243 -342 -313 -105 -21 -74 -158 -322 -450 -327 -250 -245 -365 -374 -352 -189 -161 -190 -143 -130 2 195 366 383 257 155 44 -74 -195 -306 -334 -415 -396 -255 -219 -219 -344 -477 -349 -94 33 211 216 247 277 366 499 496 489 348 387 246 264 338 422 382 206 112 111 124 165 37 -114 -220 -128 -116 6 10 -16 -39 -5 128 139 208 179 89 -89 -213 -426 -490 -290 SQ 20211106T123857.8Z 7980.527058 65 1 9.23 2 83.38 117.83 104.86 107.27 0.00 1 0.00 1 0 15 2.397e-03 2.395e-03 7.016e-04 7.012e-04 2.031328e+03 4.784099e+01 1.339199e+02 -6.000000e+00 1.553434e+02 280.45 -2.00 20.00 -2.00 505.31 0.00e+00 1.762333e-03 2.079768e-05 9.627515e-05 -6.000000e+00 7.235793e-05 280.45 -2.00 20.00 -2.00 500.69 0.00e+00 6.714021e-01 1.484054e-02 2.428805e-02 -6.000000e+00 5.167039e-02 223.98 -2.00 3.49 -2.00 502.25 0.00e+00 7.893 0.009 489.00 513.00 1 3.4062e+00 1.1502e-03 1.1451e-02 -6.0000e+00 4.0107e-03 -3.0543e-03 2.7814e-04 7.5084e-04 -6.0000e+00 9.7932e-04 2.0245e-02 1.2914e-03 1.1486e-04 6.3008e-05 -6.0000e+00 4.0299e-04 -2.1748e-03 -4.7603e-05 2 1 1 12 1 1 54.18 18.66 1.24 -0.00217 0.00678 28 45 1 4 0 312.110 21.98 15.00 18.66 4.17 11.6 848.75 -419 -187 -59 -140 -12 120 357 251 228 168 41 12 -91 -256 -177 -73 27 74 144 166 107 265 352 315 355 218 145 -18 -320 -372 -320 -64 233 101 -50 -127 -113 -110 107 77 139 104 261 284 214 96 48 46 -180 -387 -592 -456 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-26 27 47 158 98 52 -70 -123 -360 -303 -233 SQ 20211106T124933.2Z 7980.534411 68 1 8.30 2 81.62 119.67 103.05 108.80 0.00 1 0.00 1 0 15 2.138e-03 2.134e-03 1.638e-04 1.637e-04 1.706120e+03 1.107743e+01 1.122478e+02 -6.000000e+00 1.385200e+02 280.45 -2.00 20.00 -2.00 505.30 0.00e+00 1.415727e-03 4.853016e-06 7.817735e-05 -6.000000e+00 6.452100e-05 280.45 -2.00 20.00 -2.00 500.66 0.00e+00 5.356940e-01 3.479210e-03 2.033910e-02 -6.000000e+00 4.606653e-02 223.98 -2.00 3.49 -2.00 502.22 0.00e+00 6.452 0.005 489.00 513.00 1 6.4202e-01 2.6986e-04 9.3345e-03 -6.0000e+00 3.5759e-03 -2.3005e-03 6.5308e-05 6.1927e-04 -6.0000e+00 8.7287e-04 3.9805e-01 7.8205e-04 2.6859e-05 5.1741e-05 -6.0000e+00 3.5934e-04 -1.0830e-03 -3.4699e-05 0 0 0 10 0 0 -53.75 18.61 1.11 -0.00108 0.00434 535 164 1 4 0 14.950 21.88 15.00 18.61 4.61 11.6 852.26 -323 -134 2 -37 -29 159 313 324 222 129 98 13 -80 -182 -136 -134 35 102 88 22 46 212 334 388 350 265 156 -47 -213 -267 -225 -68 133 147 -55 -201 -208 -106 10 62 114 124 168 203 182 140 37 -42 -165 -344 -513 -519 -412 -244 -149 -143 -139 -107 30 208 314 354 345 251 113 46 30 -12 -116 -209 -141 -58 -3 -6 -139 -274 -313 -245 -192 -168 -212 -287 -274 -192 -114 -178 -133 -74 -15 132 236 301 233 73 -28 -91 -157 -218 -322 -357 -281 -174 -104 -220 -358 -430 -330 -158 64 158 165 200 219 235 330 401 399 321 247 215 212 270 370 330 208 139 147 153 173 64 -56 -160 -147 -83 12 52 -12 -43 -1 18 78 103 138 66 -62 -208 -330 -299 -147 -312 -131 2 -37 -29 159 317 330 225 130 98 13 -80 -182 -136 -132 35 103 90 23 47 216 340 396 356 269 156 -48 -215 -266 -224 -68 135 147 -56 -205 -212 -108 10 63 115 126 172 209 187 143 38 -42 -163 -343 -505 -508 -405 -242 -146 -143 -140 -109 31 213 321 361 351 254 114 46 29 -12 -116 -207 -139 -58 -3 -6 -138 -271 -308 -239 -187 -164 -208 -284 -266 -187 -112 -175 -132 -73 -15 133 238 298 230 74 -28 -90 -152 -208 -314 -350 -270 -170 -103 -221 -353 -425 -325 -155 63 157 166 204 220 237 334 406 404 323 247 219 214 271 371 331 210 140 148 154 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