File name: Pandora243s1_Toronto-CNTower_20240219_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T101938.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240219_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240219T130229.0Z 8815.543391 215 1 29.72 2 82.02 114.09 108.23 350.36 0.00 1 0.00 1 0 25 5.999e-01 4.405e-02 1.976e-01 1.248e-02 1.154079e+00 7.160225e-03 1.346912e-02 -6.000000e+00 3.440060e-01 224.75 -2.00 3.56 -2.00 322.00 0.00e+00 -1.632780e-02 2.845406e-03 1.942417e-03 -6.000000e+00 1.641990e-02 271.38 -2.00 20.00 -2.00 321.54 0.00e+00 6.741 0.006 302.00 328.00 3 2.1396e+00 2.3435e-02 8.8692e-02 -6.0000e+00 8.5676e-01 1.9800e+00 2.7886e-02 6.3498e-02 -6.0000e+00 9.4036e-01 -2.3600e+00 1.9906e-02 3.2038e-02 -6.0000e+00 5.4894e-01 8.9852e-01 1.0794e-02 1.8422e-02 -6.0000e+00 2.3237e-01 2.2110e-05 -2.5277e-03 2.9251e-04 2.9005e-04 -6.0000e+00 1.7314e-02 3.7644e-03 0.0000e+00 12 9 8 11 32 0 99.37 27.48 0.59 0.00376 -0.01523 17 17 1 5 0 1747.900 35.75 19.99 27.48 -0.26 3.9 766.94 726 102839 900000 900000 389081 900000 900000 18815 900000 900000 59 -51894 117944 30856 29298 900000 36993 69655 -37720 6611 -13225 37422 72967 900000 -15166 51518 -158 -4285 -48036 -65730 -31693 900000 25200 140008 102561 -61898 26409 900000 44528 111185 178701 41121 -26645 34450 42587 10946 37629 147932 71405 900000 59702 52266 50538 -5149 278021 11474 65431 57182 47673 61511 -40276 17824 12391 5546 40991 57228 -17370 83466 19869 78615 12654 22011 18816 34480 -9057 -21155 -48720 5363 2498 9410 -2255 -8909 -1597 10492 12303 15857 3300 -4997 10879 -9668 10156 804 25149 -9080 -2686 7451 -10146 -2289 -1609 1669 -3848 -1817 10859 -3622 -12248 -6258 5611 -3177 156 -243 -5946 -468 1708 6373 1135 -5640 -2506 2313 -91 1673 2904 -2599 1423 -723 4591 2565 925 3943 -438 2840 -1932 2177 2874 -1209 -483 -469 756 -1181 1038 -783 -4382 1942 949 75 3634 900000 900000 4727 900000 900000 914 900000 900000 4 -5846 2735 1908 2038 900000 2533 3385 -5041 518 -1125 1777 2579 900000 -1507 2560 -12 -274 -4244 -7404 -2975 900000 1642 2783 2866 -7725 1604 900000 3192 4727 4125 3747 -4120 2888 3001 997 2560 3415 3730 900000 4279 4445 4727 -907 3377 1868 6200 5488 4459 4484 -7878 2100 1761 957 5179 6118 -4073 7706 3910 9741 3228 5107 4206 5822 -2025 -4652 -13613 945 537 2298 -737 -3626 -665 4079 4932 6357 1527 -2501 4494 -4592 3664 308 7791 -4445 -1472 4427 -8529 -1889 -1438 1429 -3204 -1420 6570 -2508 -9835 -4957 4206 -2875 158 -266 -8064 -663 2473 8819 1610 -8358 -3659 3357 -140 2541 4106 -3596 1801 -905 5283 2932 1061 4847 -677 5038 -4106 4496 6383 -3028 -1291 -1306 2091 -3328 2784 -1977 -10355 4254 1989 SS 20240219T131213.9Z 8815.550161 218 1 29.96 2 80.42 115.88 108.48 352.51 0.00 1 0.00 1 0 25 7.693e-01 1.651e-02 5.075e-02 1.452e-03 1.002916e+00 7.677980e-04 1.113684e-02 -6.000000e+00 4.302228e-01 224.75 -2.00 3.56 -2.00 321.26 0.00e+00 5.751723e-03 3.459124e-04 1.587936e-03 -6.000000e+00 1.842777e-02 271.38 -2.00 20.00 -2.00 320.84 0.00e+00 5.733 0.004 302.00 328.00 3 1.3460e-01 2.4143e-03 7.6418e-02 -6.0000e+00 1.0656e+00 5.1919e-01 3.5103e-03 5.4025e-02 -6.0000e+00 1.1637e+00 -6.7738e-01 3.9401e-03 3.0982e-02 -6.0000e+00 6.9012e-01 2.7229e-01 1.8828e-03 1.2786e-02 -6.0000e+00 2.9178e-01 6.3393e-04 -8.2142e-04 3.2235e-05 1.4272e-04 -6.0000e+00 2.0573e-02 1.0570e-03 0.0000e+00 12 8 8 10 0 0 97.91 27.48 0.55 0.00106 -0.00512 255 255 1 5 0 117.480 35.75 20.00 27.48 -0.35 3.9 767.04 -268798 -250238 -187541 -157394 -233073 -257953 -215263 -262198 -212352 -226838 -259061 -210018 -152780 -152466 -119149 -98432 -71417 -63722 -93383 -88007 -81513 -99371 -87086 -34099 -94731 -15258 -69730 -78812 -83982 -68434 -70310 22626 -12008 -4149 -28701 -32677 -23961 20128 1476 7168 23081 11322 176 10313 13130 6205 7849 16573 11831 28179 8216 16425 17250 13367 16420 9970 11576 9529 8207 5928 4660 8466 7165 8289 11230 8078 3651 7075 6165 7784 5863 5365 3793 2029 -98 -3814 -5123 -3092 -2207 -393 563 -1092 -937 -1733 -309 107 508 87 818 76 177 -792 -1415 -2363 -2092 -1560 -1040 -112 -647 -833 -1514 -1038 -1429 -1623 -2117 -1629 -1234 -895 -560 -276 -152 143 181 69 83 -206 355 457 54 257 905 846 905 1149 1322 1256 801 916 708 866 366 352 139 -163 -190 -200 -51 -152 -2 17 -726 -423 -958 -3910 -3446 -1424 -810 -2340 -3353 -2164 -4219 -2495 -3276 -5722 -3687 -2120 -2893 -2126 -1742 -1112 -1029 -2155 -1969 -1673 -2420 -2010 -502 -2696 -203 -1590 -1919 -2283 -1977 -2718 429 -377 -124 -1032 -1245 -943 613 66 360 1098 648 12 631 794 417 549 1154 950 2166 892 1863 2157 1908 2406 1619 1873 1522 1258 907 760 1519 1404 1863 2603 1957 970 1970 1985 2836 2153 2009 1373 740 -32 -1169 -1570 -1023 -878 -174 294 -621 -583 -1152 -215 78 381 66 608 54 117 -508 -930 -1742 -1699 -1416 -1119 -130 -775 -985 -1762 -1121 -1382 -1581 -2213 -1776 -1340 -1067 -717 -389 -232 236 289 109 133 -322 565 760 90 427 1496 1309 1339 1728 1919 1771 1121 1412 1170 1585 724 728 296 -373 -448 -471 -122 -364 -4 39 -1581 -881 -1929 SS 20240219T132021.2Z 8815.555801 223 1 30.00 2 79.10 117.40 108.64 354.30 0.00 1 0.00 1 0 17 7.051e-01 1.375e-02 2.693e-02 9.507e-04 9.056346e-01 4.953292e-04 1.018829e-02 -6.000000e+00 3.943615e-01 224.75 -2.00 3.56 -2.00 320.89 0.00e+00 4.463209e-03 2.035557e-04 1.231640e-03 -6.000000e+00 1.689085e-02 271.38 -2.00 20.00 -2.00 320.45 0.00e+00 5.100 0.002 302.00 328.00 3 5.5515e-02 1.4951e-03 6.8163e-02 -6.0000e+00 9.7676e-01 2.9987e-01 2.0480e-03 4.7890e-02 -6.0000e+00 1.0666e+00 -3.9246e-01 2.2414e-03 2.6654e-02 -6.0000e+00 6.3258e-01 1.5773e-01 1.1008e-03 1.0454e-02 -6.0000e+00 2.6748e-01 1.3822e-03 -6.0452e-04 2.1980e-05 1.1126e-04 -6.0000e+00 1.8856e-02 3.0271e-04 0.0000e+00 12 8 8 10 0 0 56.58 27.47 0.52 0.00030 -0.00424 433 433 1 5 0 69.270 35.75 20.00 27.47 0.22 4.0 773.36 -258228 -232323 -204879 -205973 -246596 -237074 -218091 -213919 -192253 -190125 -200049 -198220 -148538 -117447 -100513 -67791 -79513 -60310 -73988 -54539 -79634 -71513 -66866 -43122 -66726 -16937 -61233 -51207 -59619 -50361 -44190 -2400 -9914 -10711 -16972 -22464 -7467 2747 2067 5419 7464 4723 4790 5822 8561 4935 1103 8877 8194 11889 5115 9543 10846 9311 10304 6906 6133 4960 3961 4635 2811 6127 5355 6412 5539 4447 2569 3007 3299 3717 3412 2803 1512 952 -861 -2050 -3527 -2859 -1767 -737 -908 -966 -1823 -2295 -992 -602 -254 26 658 301 92 -626 -1076 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