File name: Pandora243s1_Toronto-CNTower_20240222_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240223T053801.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240222_L1_smca1c2d20230307p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T141513.9Z 8818.593910 354 1 7.31 2 69.83 127.74 110.19 330.65 0.00 1 0.00 1 0 17 3.190e-01 2.496e-02 2.263e-01 1.462e-02 5.092599e-01 7.378744e-03 5.967985e-03 -6.000000e+00 1.787805e-01 224.87 -2.00 3.56 -2.00 319.81 0.00e+00 5.666037e-04 2.118106e-03 3.922090e-04 -6.000000e+00 7.934850e-03 271.60 -2.00 20.00 -2.00 319.31 0.00e+00 2.870 0.000 302.00 328.00 3 5.3816e+00 2.0736e-02 3.8137e-02 -6.0000e+00 4.4238e-01 8.2065e-02 2.4609e-02 2.6251e-02 -6.0000e+00 4.8321e-01 -2.1188e-01 2.0444e-02 1.3438e-02 -6.0000e+00 2.8602e-01 1.0655e-01 1.0690e-02 4.0768e-03 -6.0000e+00 1.2132e-01 8.3150e-05 1.0269e-04 4.0881e-04 4.5786e-05 -6.0000e+00 8.6526e-03 5.3591e-04 -1.1988e-05 12 9 9 12 33 1 999.00 27.71 0.58 0.00054 0.00131 1 8 1 5 0 3652.290 36.00 19.99 27.71 13.32 3.8 869.52 -104083 -73126 -13099 900000 900000 141961 -9184 -66110 75487 125823 -57513 -124422 12184 -25897 7675 138226 -5287 -7272 -711 -13066 -18782 17310 33327 131252 -27860 19798 -5650 -38492 -33496 -13337 -20899 64873 20866 41656 42253 -2234 857 15699 -2512 1109 22487 15220 15479 -4678 -168 18486 9682 5540 -6603 19390 4417 14125 -755 204 16327 -934 6073 6627 -3625 7445 -5296 4534 1955 2464 -4953 5547 -9044 5295 -782 2494 320 -65 3565 660 -2263 -5157 2291 -2422 53 -662 -5347 -4771 -1810 -64 -1158 541 833 -1694 -114 -50 -721 -2406 2878 1440 -610 160 -3988 1303 468 1115 -1609 -275 1247 -1148 -3057 -1253 3247 -1720 921 88 -1721 -234 -1542 -764 3410 -857 1524 1146 -708 832 481 19 720 1376 2982 405 -1316 2043 1129 2001 -103 837 2175 -1228 66 -737 -63 -1078 80 -1114 -1706 1299 -508 -5258 -2936 -288 900000 900000 2023 -196 -2826 1076 1793 -2622 -11442 382 -1439 361 1969 -339 -508 -49 -1043 -1579 1011 1757 2805 -3096 1410 -507 -4497 -3627 -1273 -2471 3697 2051 3324 3130 -264 111 2103 -490 242 4293 3275 3418 -1266 -44 4004 2290 1381 -1900 4558 1328 4206 -281 80 5676 -362 2449 2606 -1390 2790 -2147 1838 909 1239 -2675 2551 -4697 2449 -430 1512 214 -45 2304 412 -1319 -2772 1071 -1205 29 -425 -4114 -4085 -1476 -54 -1061 518 831 -1770 -116 -49 -647 -2225 2408 1261 -557 165 -4891 1704 602 1386 -2061 -314 1315 -1292 -3793 -1603 4182 -2287 1293 137 -2954 -378 -2652 -1232 4914 -1234 2172 1720 -1152 1388 798 31 1117 2032 4137 552 -1905 2761 1711 3308 -174 1459 3872 -2382 134 -1478 -127 -2241 164 -2354 -3429 2401 -932 SS 20240222T142015.0Z 8818.597396 357 1 30.27 2 69.11 128.82 110.62 331.75 0.00 1 0.00 1 0 25 1.460e-01 8.856e-03 3.621e-02 2.099e-03 5.113895e-01 1.043104e-03 6.042497e-03 -6.000000e+00 8.154026e-02 224.87 -2.00 3.56 -2.00 319.26 0.00e+00 4.230347e-04 2.624399e-04 3.691959e-04 -6.000000e+00 3.491336e-03 271.60 -2.00 20.00 -2.00 318.75 0.00e+00 2.778 0.000 302.00 328.00 3 4.1019e+00 2.8750e-03 3.7595e-02 -6.0000e+00 2.0203e-01 2.0731e-02 3.3449e-03 2.6287e-02 -6.0000e+00 2.2058e-01 -4.7354e-02 2.6971e-03 1.3306e-02 -6.0000e+00 1.3083e-01 1.7112e-02 1.4407e-03 3.9153e-03 -6.0000e+00 5.5370e-02 3.2048e-04 -2.2542e-04 5.6877e-05 4.1153e-05 -6.0000e+00 3.8746e-03 5.8732e-04 1.9872e-05 11 9 0 11 32 0 97.65 27.70 0.35 0.00059 -0.00111 32 32 1 5 0 945.770 36.00 19.99 27.70 13.40 3.8 870.22 -76709 -56010 -15492 86042 -10049 -30124 -49500 -48822 5414 -3003 -20505 -60923 -10471 -5657 -14994 -274 -5866 -2858 -9207 -977 -6486 -7527 -507 6575 -9825 22809 -5344 -4194 -12855 -14945 -13246 13045 -807 -1788 3059 -6913 -2946 5853 -2292 756 2898 2793 -2240 815 357 2424 2546 3541 1165 6521 2133 1678 304 -838 3240 -289 1278 -125 499 1476 -1506 3358 1805 978 1475 1044 -1917 247 821 1899 53 293 262 -129 -601 -1856 -3062 -600 -727 -487 -1509 -1600 -1367 -1573 -735 -168 -371 227 495 -72 601 376 764 -196 -27 289 -259 300 -121 110 -892 -867 -57 -646 -934 -849 49 -595 -50 330 -175 542 93 518 617 -23 830 17 -560 -54 803 -206 -27 357 768 461 52 862 559 665 -165 233 -214 -292 -44 104 37 -388 -51 -285 -698 -49 107 -2622 -1720 -323 599 -169 -635 -1419 -1599 115 -73 -617 -3155 -403 -255 -890 -16 -391 -200 -727 -74 -524 -619 -42 549 -1036 1812 -556 -408 -1337 -1722 -1738 1509 -120 -272 417 -1070 -498 1093 -516 193 792 806 -704 250 111 746 786 1101 381 2147 811 644 128 -382 1481 -142 628 -62 236 688 -758 1777 1004 598 899 606 -1119 145 536 1400 40 227 198 -92 -421 -1179 -1843 -357 -485 -352 -1263 -1401 -1281 -1556 -725 -175 -406 252 542 -75 614 357 689 -183 -28 320 -309 400 -161 143 -1148 -1069 -65 -772 -1139 -1085 65 -801 -72 497 -287 861 153 800 935 -34 1214 25 -878 -87 1281 -321 -40 542 1109 639 74 1195 865 1071 -273 403 -385 -527 -84 198 72 -774 -100 -540 -1318 -88 194 SS 20240222T142522.6Z 8818.600956 360 1 29.57 2 68.40 129.93 111.05 332.89 0.00 1 0.00 1 0 17 2.276e-01 2.043e-02 9.635e-02 4.913e-03 4.909610e-01 2.468649e-03 5.872965e-03 -6.000000e+00 1.270933e-01 224.87 -2.00 3.56 -2.00 319.57 0.00e+00 -7.024773e-04 6.712533e-04 1.209853e-03 -6.000000e+00 5.646719e-03 271.60 -2.00 20.00 -2.00 319.07 0.00e+00 2.692 0.000 302.00 328.00 3 5.4796e+00 6.8749e-03 3.6638e-02 -6.0000e+00 3.1482e-01 7.9247e-02 8.0637e-03 2.6308e-02 -6.0000e+00 3.4378e-01 -1.3833e-01 6.5329e-03 1.2991e-02 -6.0000e+00 2.0410e-01 6.3997e-02 3.4489e-03 3.7560e-03 -6.0000e+00 8.7059e-02 8.9285e-05 -1.1146e-04 1.3736e-04 4.2016e-05 -6.0000e+00 6.2058e-03 1.1071e-03 -3.0966e-05 12 9 8 11 32 0 99.40 27.70 0.36 0.00111 0.00027 10 10 1 5 0 2956.540 36.00 20.00 27.70 13.51 3.8 871.80 -102969 -57647 900000 900000 91341 93627 -61524 -69512 28042 45085 -5197 -99430 2520 -22419 -16239 86012 -9862 -7891 -17552 14842 -7773 544 17916 40278 -18776 26898 7306 -4781 -27264 -33272 -20000 20126 10399 -1056 11440 -19925 -5113 13979 1873 1071 9142 11852 -4839 4307 3648 13049 9960 413 7372 20080 6575 3551 -939 4956 3063 -1591 2902 541 2792 3494 3224 6944 2653 -1567 2392 5186 -6175 1204 -728 3572 -1163 1 -1050 -62 -1769 -2981 -8553 1092 -1971 -594 -3413 -2951 -2472 626 -352 1558 59 -1316 -143 -1319 -613 -479 3804 -659 -2645 1594 -3669 1327 448 372 -1495 -767 -1092 129 -1598 -1226 1046 437 -104 217 -1471 193 -65 2393 535 -274 2188 1112 -182 746 459 -499 213 454 1292 1203 -2188 2756 1353 1023 -614 609 873 -434 -154 -792 -771 -1685 -340 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