File name: Pandora243s1_Toronto-CNTower_20240222_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T102122.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240222_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T141513.9Z 8818.593910 354 1 7.31 2 69.83 127.74 110.19 330.65 0.00 1 0.00 1 0 17 3.191e-01 2.498e-02 2.263e-01 1.462e-02 5.097259e-01 7.393481e-03 5.965523e-03 -6.000000e+00 1.792869e-01 224.87 -2.00 3.56 -2.00 319.81 0.00e+00 5.957294e-04 2.122452e-03 3.706054e-04 -6.000000e+00 7.961236e-03 271.60 -2.00 20.00 -2.00 319.31 0.00e+00 2.870 0.000 302.00 328.00 3 5.4117e+00 2.0782e-02 3.8144e-02 -6.0000e+00 4.4356e-01 8.3739e-02 2.4659e-02 2.6261e-02 -6.0000e+00 4.8444e-01 -2.1261e-01 2.0459e-02 1.3442e-02 -6.0000e+00 2.8675e-01 1.0669e-01 1.0693e-02 4.0932e-03 -6.0000e+00 1.2156e-01 8.0566e-05 2.1961e-04 4.1026e-04 4.6251e-05 -6.0000e+00 8.7236e-03 -2.0569e-03 0.0000e+00 12 9 9 12 33 1 999.00 27.71 0.58 -0.00206 -0.00041 1 8 1 5 0 3652.290 36.00 19.99 27.71 13.32 3.8 869.52 -104256 -73261 -13186 900000 900000 142341 -9074 -66342 75297 125773 -57424 -124243 12279 -25967 7605 138197 -5257 -7238 -672 -13105 -18812 17406 33520 131236 -28082 19686 -5624 -38511 -33461 -13061 -20800 64747 20734 41601 42313 -1927 1111 15640 -2629 1067 22420 15154 15469 -4667 -161 18496 9701 5567 -6553 19443 4445 14053 -827 211 16352 -985 6036 6617 -3584 7530 -5195 4539 1910 2377 -5079 5563 -8811 5495 -806 2406 265 -103 3554 652 -2250 -5079 2429 -2291 109 -697 -5408 -4802 -1828 -58 -1121 544 751 -1734 -93 -61 -756 -2348 3017 1511 -609 120 -3998 1310 388 998 -1561 -85 1315 -1121 -3080 -1312 3242 -1647 940 71 -1749 -274 -1582 -761 3437 -807 1580 1168 -718 803 422 10 762 1336 2900 387 -1262 2126 1161 1939 -131 889 2219 -1222 82 -742 -78 -1048 80 -1191 -1732 1347 -489 -5267 -2942 -290 900000 900000 2028 -194 -2836 1073 1792 -2618 -11426 385 -1443 358 1969 -337 -505 -46 -1046 -1581 1017 1767 2805 -3121 1402 -505 -4499 -3623 -1247 -2460 3690 2038 3319 3135 -228 144 2095 -513 233 4281 3260 3416 -1263 -42 4006 2294 1388 -1886 4571 1336 4185 -307 83 5685 -381 2434 2602 -1374 2822 -2106 1840 888 1194 -2743 2558 -4577 2541 -443 1458 177 -71 2297 407 -1311 -2730 1136 -1140 59 -447 -4161 -4112 -1491 -49 -1028 521 749 -1812 -94 -59 -678 -2172 2524 1323 -556 124 -4903 1715 499 1241 -1999 -97 1387 -1262 -3821 -1678 4177 -2189 1320 111 -3002 -442 -2721 -1227 4954 -1162 2252 1754 -1169 1340 701 16 1181 1973 4024 528 -1826 2873 1760 3204 -220 1549 3949 -2371 167 -1487 -158 -2180 163 -2518 -3482 2489 -898 SS 20240222T142015.0Z 8818.597396 357 1 30.27 2 69.11 128.82 110.62 331.75 0.00 1 0.00 1 0 17 1.458e-01 8.796e-03 3.621e-02 2.098e-03 5.118548e-01 1.043994e-03 6.052057e-03 -6.000000e+00 8.160685e-02 224.87 -2.00 3.56 -2.00 319.26 0.00e+00 4.349088e-04 2.629741e-04 3.472074e-04 -6.000000e+00 3.496408e-03 271.60 -2.00 20.00 -2.00 318.75 0.00e+00 2.778 0.000 302.00 328.00 3 4.1321e+00 2.8774e-03 3.7619e-02 -6.0000e+00 2.0216e-01 2.2267e-02 3.3476e-03 2.6323e-02 -6.0000e+00 2.2072e-01 -4.8107e-02 2.6969e-03 1.3315e-02 -6.0000e+00 1.3091e-01 1.7292e-02 1.4402e-03 3.9095e-03 -6.0000e+00 5.5361e-02 3.1052e-04 -3.4667e-04 5.7177e-05 4.1572e-05 -6.0000e+00 3.8994e-03 -1.1312e-03 0.0000e+00 11 9 0 11 32 0 97.65 27.70 0.35 -0.00113 -0.00374 32 32 1 5 0 945.770 36.00 19.99 27.70 13.40 3.8 870.22 -76809 -56106 -15578 85986 -9892 -29696 -49301 -48964 5297 -3000 -20343 -60634 -10268 -5635 -14993 -257 -5798 -3084 -9143 -993 -6510 -7658 -264 6375 -9991 22739 -5294 -4192 -12792 -14796 -13085 12968 -909 -1848 3116 -6578 -2630 5869 -2422 695 2807 2763 -2282 846 386 2448 2519 3582 1176 6545 2196 1591 260 -844 3252 -346 1229 -118 521 1547 -1414 3402 1767 891 1331 1032 -1702 474 815 1822 4 236 245 -147 -606 -1798 -2936 -470 -657 -507 -1574 -1620 -1392 -1574 -700 -164 -455 180 509 -94 551 416 891 -127 -9 256 -263 317 -194 -9 -853 -682 10 -616 -952 -914 39 -518 -27 316 -205 500 50 522 644 25 886 41 -567 -88 740 -212 18 321 688 441 103 938 590 601 -202 279 -172 -290 -30 96 18 -362 -48 -357 -723 -5 125 -2625 -1722 -325 598 -166 -626 -1412 -1603 113 -73 -612 -3139 -395 -254 -890 -15 -387 -216 -722 -75 -526 -632 -22 534 -1053 1805 -550 -408 -1330 -1708 -1716 1499 -135 -281 425 -1018 -444 1095 -546 178 767 797 -717 260 120 753 778 1113 384 2155 834 611 109 -385 1486 -169 604 -58 247 720 -712 1800 983 545 812 599 -994 278 531 1344 3 183 185 -104 -424 -1142 -1767 -279 -439 -366 -1317 -1419 -1304 -1557 -690 -171 -497 200 556 -98 563 396 803 -119 -9 283 -313 423 -260 -12 -1097 -841 12 -736 -1161 -1168 52 -698 -39 476 -335 794 82 807 977 36 1296 60 -889 -143 1181 -331 28 487 992 612 146 1301 912 968 -335 483 -310 -524 -57 183 35 -722 -95 -677 -1363 -10 228 SS 20240222T142522.6Z 8818.600956 360 1 29.57 2 68.40 129.93 111.05 332.89 0.00 1 0.00 1 0 17 2.275e-01 2.040e-02 9.636e-02 4.915e-03 4.913995e-01 2.474854e-03 5.873287e-03 -6.000000e+00 1.273195e-01 224.87 -2.00 3.56 -2.00 319.57 0.00e+00 -7.007745e-04 6.729042e-04 1.165843e-03 -6.000000e+00 5.660660e-03 271.60 -2.00 20.00 -2.00 319.07 0.00e+00 2.692 0.000 302.00 328.00 3 5.5098e+00 6.8951e-03 3.6633e-02 -6.0000e+00 3.1533e-01 8.0723e-02 8.0862e-03 2.6272e-02 -6.0000e+00 3.4432e-01 -1.3852e-01 6.5407e-03 1.2986e-02 -6.0000e+00 2.0442e-01 6.3776e-02 3.4507e-03 3.7591e-03 -6.0000e+00 8.7120e-02 8.6510e-05 -1.3205e-04 1.3827e-04 4.2361e-05 -6.0000e+00 6.2520e-03 2.5452e-04 0.0000e+00 12 9 8 11 32 0 99.40 27.70 0.36 0.00025 -0.00074 10 10 1 5 0 2956.540 36.00 20.00 27.70 13.51 3.8 871.80 -102468 -57964 900000 900000 91344 93856 -61550 -69862 27751 44947 -5198 -99350 2510 -22603 -16425 85871 -9943 -7967 -17619 14702 -7898 552 18035 40204 -19047 26743 7297 -4832 -27277 -33058 -19966 19934 10203 -1168 11446 -19362 -4910 13876 1720 997 9049 11765 -4870 4292 3624 13024 9944 571 7386 20097 6567 3446 -1041 4937 3066 -1658 2849 518 2932 3564 3414 6928 2586 -1600 2241 5264 -5886 1382 -770 3533 -1238 -56 -1080 -90 -1709 -2850 -8435 1206 -1931 -647 -3494 -3003 -2512 656 -336 1579 -8 -1343 -112 -1362 -681 -406 3967 -561 -2619 1535 -3669 1340 365 246 -1458 -584 -1022 130 -1613 -1281 1044 512 -83 200 -1484 161 -100 2402 546 -235 2238 1132 -196 706 385 -524 239 425 1199 1171 -2144 2871 1415 958 -628 670 927 -435 -145 -791 -782 -1652 -342 1394 -1881 181 806 -5132 -2222 900000 900000 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