File name: Pandora243s1_Toronto-CNTower_20240223_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T102114.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240223_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240223T123644.9Z 8819.525520 277 1 31.48 2 85.23 108.54 95.98 300.16 0.00 1 0.00 1 0 25 7.841e-01 2.626e-01 3.381e-01 7.913e-02 8.354335e-01 4.917107e-02 1.078267e-02 -6.000000e+00 4.773221e-01 224.91 -2.00 3.56 -2.00 318.47 0.00e+00 -3.686596e-02 5.571940e-03 3.872742e-03 -6.000000e+00 2.455693e-02 271.67 -2.00 20.00 -2.00 317.41 0.00e+00 10.196 0.020 302.00 328.00 3 8.3459e-01 1.2859e-01 1.1597e-01 -6.0000e+00 1.1713e+00 2.6893e+00 1.4582e-01 8.6760e-02 -6.0000e+00 1.2830e+00 -1.7045e+00 8.2446e-02 2.1803e-02 -6.0000e+00 7.6329e-01 3.1104e-01 3.9625e-02 2.8788e-02 -6.0000e+00 3.2746e-01 2.9148e-06 -8.5081e-03 2.0978e-03 3.4253e-04 -6.0000e+00 2.3326e-02 1.1279e-03 0.0000e+00 12 9 8 11 32 0 30.41 28.18 6.83 0.00113 -0.06281 10 10 1 5 0 3147.760 36.25 20.00 28.18 11.09 3.8 852.88 71293 -24122 900000 900000 900000 900000 46414 -44906 900000 900000 18163 121201 900000 64958 209349 900000 170187 17154 17953 76366 -9130 900000 67782 103165 -1760 900000 66884 -19454 -23249 900000 57738 900000 145296 145200 900000 -44782 101699 900000 16559 37877 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-6.0000e+00 1.1758e+00 -2.5424e+00 2.2217e-02 4.2043e-02 -6.0000e+00 6.9400e-01 9.6349e-01 1.1815e-02 1.8580e-02 -6.0000e+00 2.9528e-01 2.1559e-05 -6.8293e-04 3.1209e-04 1.6899e-04 -6.0000e+00 2.0572e-02 -1.6565e-03 0.0000e+00 12 9 8 11 32 0 95.05 28.17 1.56 -0.00166 -0.00679 28 28 1 5 0 1071.290 36.25 20.00 28.17 11.14 3.8 853.00 165224 20823 900000 315987 155903 14220 4264 -1166 900000 900000 -31133 -62699 900000 81490 78100 900000 148121 131100 25302 182673 16445 23504 74872 117083 9200 243397 -9071 -36999 -5244 -34049 -31553 900000 72596 73507 99280 -52869 20139 160517 2478 43135 395749 174655 14625 9246 12115 122248 900000 245357 85912 900000 149796 56325 29868 72237 900000 26651 25762 8826 20882 112999 58368 87818 10058 -1514 64246 23651 -15143 47885 44168 46656 -6060 26912 36549 3015 30657 -45402 -33785 30644 352 16390 -12078 -11347 20152 -1498 11305 14324 1417 -1501 16669 -13554 10159 2104 16058 5773 -8510 10745 -14412 -6742 -3709 3361 -3668 -6744 -6245 5234 -14900 729 6500 -1273 -861 -685 -6449 2629 -447 8443 6727 -4996 4378 856 -713 5118 2346 -2787 -170 -2481 5185 49 -4337 4580 -388 3766 -1181 -5 -821 -1421 1350 -866 285 -814 1124 -1524 -3298 2149 2102 4378 2135 900000 4005 2155 786 285 -91 900000 900000 -3515 -10185 900000 3568 3779 900000 3584 3625 1866 2525 1061 1327 2760 3237 795 3085 -794 -3453 -308 -2785 -2872 900000 2760 2625 2402 -5604 1114 2848 237 3499 5015 3984 1538 914 1044 3253 900000 3109 3375 900000 3797 3997 2990 5127 900000 3310 3232 1219 2249 4296 3699 4452 1262 -240 5455 2997 -2955 5401 5877 6859 -1605 5116 5883 600 3963 -10990 -7065 3650 67 3240 -3781 -4113 5874 -573 4012 5119 587 -637 5704 -5875 3232 707 4884 2202 -4475 5583 -11415 -5767 -3342 2786 -3003 -4974 -4076 3058 -11386 500 4514 -1061 -830 -715 -8337 3428 -629 10894 8611 -7056 5755 1220 -1075 7288 3243 -3776 -214 -3121 6472 57 -5251 5662 -609 6721 -2532 -11 -1934 -3659 3653 -2500 818 -2373 3128 -4030 -8034 4920 4607 SS 20240223T125711.8Z 8819.539719 283 1 29.91 2 81.76 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