File name: Pandora243s1_Toronto-CNTower_20240229_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T103242.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240229_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240229 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240229T122704.6Z 8825.518803 273 1 29.98 2 85.14 105.43 77.39 234.01 0.00 1 0.00 1 0 25 7.014e-01 1.435e-01 2.477e-01 3.697e-02 1.394512e+00 2.156613e-02 1.645452e-02 -6.000000e+00 3.942849e-01 225.15 -2.00 3.56 -2.00 320.14 0.00e+00 -3.098608e-02 3.612856e-03 6.303044e-03 -6.000000e+00 1.786482e-02 272.11 -2.00 20.00 -2.00 319.32 0.00e+00 10.051 0.020 302.00 328.00 3 -8.5078e-01 5.9025e-02 1.3498e-01 -6.0000e+00 9.8018e-01 4.0902e+00 6.9250e-02 1.1766e-01 -6.0000e+00 1.0722e+00 -2.9477e+00 3.7385e-02 3.4883e-02 -6.0000e+00 6.3311e-01 6.2305e-01 1.8788e-02 2.7283e-02 -6.0000e+00 2.6882e-01 7.5383e-06 1.3752e-03 7.3512e-04 2.3676e-04 -6.0000e+00 1.9304e-02 2.8670e-03 0.0000e+00 12 9 8 11 32 0 -9.74 27.28 2.58 0.00287 0.01320 23 23 1 5 0 1303.060 35.75 19.99 27.28 -1.49 4.0 758.87 11720 -1244 900000 900000 70828 16547 -14245 -21465 900000 111233 117058 3286 141007 87373 53926 189278 42503 198257 32112 78396 68822 -42417 150527 137803 5243 125084 29630 -27443 -10425 -60716 -26006 900000 63148 12147 155570 -68060 14194 126192 72445 209729 175013 169929 -5939 -46023 -9857 54027 137644 166160 36665 17953 27350 54992 39126 -11200 225435 81530 46959 105225 -11058 46827 -47599 4293 -54296 29586 74643 60893 -879 48977 37450 211336 10658 66759 -977 13880 -25095 -89936 -66761 127366 -14092 83369 -19477 25309 23728 45433 21257 73335 4252 1966 22915 16864 16490 6771 108212 16511 19301 38882 -1861 16973 5714 27838 -4962 -15255 39623 21715 -32028 24923 49707 -3896 17023 3569 14212 22433 1733 -464 31911 -14645 14932 11430 -6297 2358 1427 -20905 7098 -6275 11954 -3525 -22450 23288 -16534 6413 -5857 -3725 7847 -2960 116 -2923 1812 -9715 2617 1919 -7329 25288 14259 4187 -456 900000 900000 6592 2732 -3678 -6831 900000 11658 11885 1119 12931 14594 13423 12398 11832 11038 8519 11554 9692 -17504 10353 12637 1923 13109 6696 -8539 -2390 -24857 -8688 900000 9927 2904 7643 -29870 2975 10332 12338 10303 12610 12244 -2198 -21555 -2776 7255 7664 7075 6004 3881 6002 9906 8842 -4475 8860 13885 10920 12062 -3368 6748 -16525 942 -24185 6298 10268 9573 -271 9945 9567 11421 3979 14912 -380 3900 -8498 -45361 -28862 8718 -4721 12615 -9684 9209 9403 14895 9037 18494 2099 949 8338 5893 5287 2342 14425 6365 8692 17090 -1441 12474 4961 18554 -4076 -11651 15131 9779 -25731 11673 19341 -2891 12082 3498 14694 23599 2348 -646 31271 -22423 17322 14206 -9528 3160 1763 -29448 7186 -7053 10939 -3683 -28794 22066 -29128 10860 -13061 -9165 19081 -8045 333 -9000 5378 -32519 7508 5103 -19299 48193 29795 SS 20240229T123656.2Z 8825.525651 276 1 29.82 2 83.42 107.18 78.84 235.87 0.00 1 0.00 1 0 25 5.419e-01 2.815e-02 2.011e-01 7.261e-03 1.322828e+00 4.115814e-03 1.433522e-02 -6.000000e+00 3.042309e-01 225.15 -2.00 3.56 -2.00 322.41 0.00e+00 -1.226587e-02 1.963608e-03 1.880788e-03 -6.000000e+00 1.363915e-02 272.11 -2.00 20.00 -2.00 322.00 0.00e+00 7.943 0.010 302.00 328.00 3 1.0916e-01 1.4584e-02 1.0506e-01 -6.0000e+00 7.5306e-01 2.2855e+00 1.7880e-02 7.4655e-02 -6.0000e+00 8.2241e-01 -2.7728e+00 1.3578e-02 3.7229e-02 -6.0000e+00 4.8811e-01 1.0291e+00 7.1976e-03 1.4798e-02 -6.0000e+00 2.0689e-01 4.8953e-05 -9.3707e-04 1.5560e-04 2.1077e-04 -6.0000e+00 1.4598e-02 1.4110e-03 0.0000e+00 12 8 8 10 0 0 -1.72 27.29 0.99 0.00141 -0.00563 70 70 1 5 0 425.980 35.50 20.00 27.29 -1.42 4.0 759.79 42616 -18792 900000 82216 108271 -20568 -47918 -16110 146958 92925 -50317 -56545 94852 63401 52725 86998 47931 64375 32876 66079 28385 -47025 45903 196977 -32558 900000 -56718 -41475 -58199 -59510 -51023 280935 54678 10131 108738 -22860 3468 120349 72681 118722 173456 105612 15503 -27235 14291 26155 25585 134458 57395 30515 40582 47130 35011 9339 119446 63804 42328 45686 6212 24036 -5896 26208 -25357 29742 44380 26961 10172 26545 43059 58729 26876 35749 14216 10950 8801 -32666 -20401 22233 -1662 22030 -3032 -1594 14052 4658 4012 11031 1128 3553 6468 -1757 8789 2079 3136 934 -2152 906 -4752 -2364 -5858 -3284 -5342 -4559 4353 -2275 -12123 -2058 3279 -4734 229 -1714 -3015 821 -1261 2034 1619 -2336 468 561 -1647 457 3927 -1036 2007 2253 4632 -599 -1015 2837 -935 1667 161 262 955 -966 469 -296 833 -706 418 -111 -1460 761 -1587 2057 -1572 900000 1640 1324 -847 -2652 -674 1229 1315 -3011 -4075 1770 1877 1968 2463 2036 2278 1481 1913 1041 -3359 1359 1394 -2325 900000 -4307 -2269 -3483 -4097 -3940 1989 2013 552 1924 -1424 177 2215 2572 3025 2701 3214 1097 -2680 850 1314 1286 2379 2356 1814 2470 2969 2701 1005 4481 4290 3475 3331 589 1701 -551 1948 -3679 2863 3895 2863 1361 3307 5181 6817 4528 5440 2465 1705 1184 -5827 -3191 2549 -296 3836 -818 -497 4138 1586 1437 3795 434 1323 2253 -621 2600 646 1023 361 -1053 526 -3201 -1837 -5160 -2790 -4238 -3086 2582 -1425 -8890 -1431 2323 -3714 203 -1878 -3981 1169 -1779 2816 2215 -3285 657 824 -2562 686 5777 -1470 2631 2865 5622 -751 -1283 3935 -1529 3210 336 614 2443 -2558 1321 -873 2440 -2095 1190 -292 -3745 1715 -3486 SS 20240229T124713.8Z 8825.532799 279 1 30.00 2 81.65 109.03 80.39 237.77 0.00 1 0.00 1 0 25 5.659e-01 2.282e-02 1.143e-01 2.620e-03 1.128258e+00 1.424172e-03 1.226858e-02 -6.000000e+00 3.169380e-01 225.15 -2.00 3.56 -2.00 321.82 0.00e+00 7.885522e-03 7.061567e-04 2.080332e-03 -6.000000e+00 1.379802e-02 272.11 -2.00 20.00 -2.00 321.41 0.00e+00 6.480 0.005 302.00 328.00 3 2.5579e-01 4.7864e-03 8.8389e-02 -6.0000e+00 7.8551e-01 1.1360e+00 6.8061e-03 6.6168e-02 -6.0000e+00 8.5744e-01 -1.5230e+00 7.0468e-03 3.3377e-02 -6.0000e+00 5.0894e-01 6.1294e-01 3.3260e-03 1.3412e-02 -6.0000e+00 2.1604e-01 2.2978e-04 -1.4821e-03 5.7081e-05 1.5861e-04 -6.0000e+00 1.5219e-02 6.8225e-04 0.0000e+00 12 8 8 10 0 0 10.38 27.30 0.71 0.00068 -0.01045 159 159 1 5 0 188.630 35.75 20.00 27.30 -1.03 4.0 762.22 -157384 -191834 900000 -38982 -138126 -177378 -187644 -206506 -113215 -146835 -177604 -174382 -76602 -80820 -56304 -33261 -35508 34680 -46863 2851 -17548 -86776 -13357 -11678 -76243 203043 -72231 -83486 -88011 -82357 -67542 69035 8248 10952 17172 -16612 -14076 25812 24672 47193 63551 48901 7414 7324 20844 30114 26206 51386 33571 30614 10348 33641 30459 31827 49847 35042 30216 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