File name: Pandora243s1_Toronto-CNTower_20240326_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T105153.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240326_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240326T165009.1Z 8851.701494 453 1 31.30 2 41.70 167.60 140.94 324.10 0.00 1 0.00 1 0 17 1.661e-02 9.578e-03 5.232e-03 2.814e-03 1.963831e-01 1.405636e-03 2.401462e-03 -6.000000e+00 9.358623e-03 226.63 -2.00 3.56 -2.00 315.96 0.00e+00 -1.373365e-04 1.438812e-04 2.969614e-05 -6.000000e+00 4.030390e-04 274.50 -2.00 20.00 -2.00 315.40 0.00e+00 1.338 0.000 302.00 328.00 3 6.3394e+00 3.6348e-03 1.6387e-02 -6.0000e+00 2.3255e-02 3.3792e-02 4.0631e-03 1.0087e-02 -6.0000e+00 2.5345e-02 -1.5353e-03 2.3497e-03 4.9840e-03 -6.0000e+00 1.5036e-02 -2.8180e-03 1.0782e-03 1.4034e-03 -6.0000e+00 6.3501e-03 2.0808e-04 -3.9806e-04 7.9400e-05 1.7162e-05 -6.0000e+00 4.4444e-04 -9.0168e-04 0.0000e+00 12 9 8 11 32 0 99.14 27.43 0.81 -0.00090 -0.00389 10 10 1 5 0 3129.110 35.75 20.00 27.43 14.59 3.8 880.52 -765 -3465 3259 5508 5322 -2834 -1665 -3805 150 2525 -3351 -1518 -366 2267 1220 4047 -2455 -995 -3846 13 2628 1018 1445 3014 -2088 1728 272 -1105 -3223 -1670 -710 5127 338 574 2345 -5159 -1087 -585 1912 1245 908 -823 -565 -1127 -1622 -502 -1900 -1146 -1330 2997 -1367 1396 746 70 270 309 -1672 606 1735 920 -1652 2186 1602 525 -285 342 -1425 533 -400 1480 -790 1008 929 1198 -749 -1587 -727 -854 -1485 -291 -1470 -1628 -2135 -171 -911 958 298 109 610 553 515 -533 2176 -357 -126 264 651 1868 229 631 -1258 -513 463 -234 -1115 -488 -133 -99 -398 609 -196 697 170 -320 219 -1785 101 369 -609 19 497 -747 622 210 964 96 -352 -707 418 56 -357 136 643 214 -61 -800 402 104 -435 851 -1170 145 396 -184 -898 772 1137 986 -569 -359 -941 39 645 -881 -410 -109 739 406 1384 -912 -375 -1534 5 1010 394 576 1245 -945 770 119 -450 -1248 -636 -282 2038 150 249 1015 -2226 -504 -318 1208 825 642 -610 -426 -851 -1223 -370 -1374 -793 -896 1949 -983 1033 583 58 225 262 -1460 510 1417 760 -1458 1998 1461 504 -265 309 -1219 439 -361 1367 -804 1039 948 1167 -685 -1416 -582 -655 -1217 -265 -1388 -1679 -2330 -191 -1028 1134 373 140 776 668 614 -583 2112 -347 -130 298 751 2340 303 803 -1522 -612 526 -283 -1373 -626 -177 -137 -580 868 -293 1028 239 -446 277 -2173 131 463 -834 28 731 -1099 879 283 1224 126 -440 -894 517 74 -490 190 902 313 -88 -1228 625 166 -700 1315 -1786 211 605 SS 20240326T165522.7Z 8851.705124 456 1 30.95 2 41.51 169.55 141.48 325.89 0.00 1 0.00 1 0 17 3.132e-02 1.422e-02 8.041e-03 3.996e-03 1.981275e-01 2.000138e-03 2.387993e-03 -6.000000e+00 1.765209e-02 226.63 -2.00 3.56 -2.00 316.13 0.00e+00 -1.068911e-04 2.121430e-04 7.614718e-05 -6.000000e+00 7.600962e-04 274.50 -2.00 20.00 -2.00 315.56 0.00e+00 1.334 0.000 302.00 328.00 3 6.8270e+00 5.1777e-03 1.6367e-02 -6.0000e+00 4.3863e-02 3.9165e-02 5.7986e-03 1.0080e-02 -6.0000e+00 4.7802e-02 1.5980e-03 3.3509e-03 4.9873e-03 -6.0000e+00 2.8359e-02 -1.7543e-04 1.5572e-03 1.4203e-03 -6.0000e+00 1.1979e-02 1.2703e-04 -4.2931e-04 1.1282e-04 1.6303e-05 -6.0000e+00 8.3804e-04 -2.7182e-03 0.0000e+00 12 9 8 11 32 0 97.90 27.45 0.59 -0.00272 -0.00594 9 9 1 5 0 3437.940 35.75 20.00 27.45 14.61 3.8 880.86 -3414 -2553 9687 8762 21002 -734 -2510 -7229 -2976 3414 -293 435 -2029 5824 -300 -1720 -3453 -904 -6258 1177 1958 1146 3243 5049 -6428 2577 -824 -3180 -6184 -2559 -2997 7651 1676 301 4571 -7286 -745 -789 3003 1950 3133 -615 -66 -1912 -2925 1573 -1415 -1200 -45 5104 -3281 1794 222 -800 4422 -606 -1938 1288 2823 1286 -993 2103 2550 -563 901 -1047 -2812 1192 4 854 -227 2167 413 2040 -1295 -1841 -5439 -1103 -1407 -403 -1161 -1775 -2111 480 -332 619 258 -1441 969 522 280 145 -511 -1204 395 -261 -2123 2326 1125 1125 -1473 -523 741 324 -82 -795 118 674 466 157 -438 721 490 17 1625 -1868 -581 380 -988 196 379 -693 882 226 1333 533 -1168 -475 -273 659 -525 -834 1708 -131 -13 -627 -228 88 -736 -406 138 620 280 -757 -588 1933 1574 2987 -129 -489 -1656 -712 776 -67 103 -551 1643 -100 -616 -1281 -336 -2529 454 749 438 1255 2019 -2728 1126 -361 -1310 -2441 -972 -1204 2934 728 130 1744 -3177 -340 -385 1685 1259 2125 -447 -48 -1431 -2196 1117 -1001 -818 -29 3195 -2363 1300 171 -651 3479 -509 -1669 1061 2243 1040 -855 1890 2248 -534 809 -946 -2402 961 4 775 -224 2157 413 1926 -1165 -1622 -4492 -834 -1131 -360 -1065 -1790 -2248 522 -391 772 313 -1824 1191 664 327 154 -498 -1255 394 -289 -2642 3043 1429 1496 -1878 -609 817 379 -105 -1071 152 900 652 232 -680 1101 713 23 2124 -2384 -734 499 -1309 274 538 -982 1200 319 1760 674 -1424 -580 -353 895 -752 -1221 2469 -185 -20 -987 -366 144 -1221 -652 213 922 409 SS 20240326T170038.0Z 8851.708773 459 1 31.35 2 41.35 171.52 142.00 327.72 0.00 1 0.00 1 0 17 2.999e-02 1.656e-02 8.884e-03 4.363e-03 1.971454e-01 2.173052e-03 2.350032e-03 -6.000000e+00 1.689869e-02 226.63 -2.00 3.56 -2.00 316.25 0.00e+00 -5.128719e-04 2.362481e-04 1.474843e-04 -6.000000e+00 7.276762e-04 274.50 -2.00 20.00 -2.00 315.67 0.00e+00 1.331 0.000 302.00 328.00 3 6.9594e+00 5.6447e-03 1.6272e-02 -6.0000e+00 4.1991e-02 4.1577e-02 6.3223e-03 1.0001e-02 -6.0000e+00 4.5762e-02 5.3962e-03 3.6611e-03 4.9078e-03 -6.0000e+00 2.7149e-02 -9.1799e-03 1.7011e-03 1.4656e-03 -6.0000e+00 1.1468e-02 1.1217e-04 -1.8973e-04 1.2329e-04 1.6353e-05 -6.0000e+00 8.0232e-04 -2.3518e-03 0.0000e+00 12 9 8 11 40 0 94.95 27.45 0.91 -0.00235 -0.00378 9 9 1 5 0 3482.710 35.75 20.00 27.45 14.70 3.8 882.06 -384 -4531 15654 4190 -8083 -771 -7828 -6233 13 2798 -1286 2794 583 2293 -1229 8719 -3409 -1129 -4414 1810 885 -525 695 6228 -5039 637 55 -4254 -5841 -4164 -4398 8339 -240 808 4612 -8088 2063 964 3517 2330 2924 1113 -3381 -1959 -3447 1239 -1954 -1198 -2174 5097 2007 3643 2255 -122 977 -580 -1134 1126 2885 1022 1252 3166 1004 -128 -300 -431 -2942 510 79 314 -798 2412 629 1931 -804 -3112 -5583 -1207 -1633 -1191 -2197 -2213 -2335 1156 -567 2883 -330 415 691 386 130 -1178 2904 -1096 -371 74 -2922 1678 1116 880 -1201 -1124 969 394 -3435 -883 -24 439 -669 570 628 735 -38 -514 889 -2634 -762 34 -1079 853 3850 -751 909 859 2012 136 -828 -191 -1032 765 -9 371 2194 -1158 279 -977 532 -1434 312 43 10 -228 -598 -79 -1018 2811 752 -1472 -131 -1552 -1368 3 620 -288 629 149 649 -400 2715 -1220 -407 -1690 670 331 -197 267 2393 -2260 277 23 -1721 -2232 -1561 -1738 3079 -103 336 1703 -3452 891 496 1914 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