File name: Pandora243s1_Toronto-CNTower_20240507_L2Fit_fwvt1c5d20240208p1-8.txt
File generation date: 20241016T112906.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240507_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240507
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0474 492.1680 492.2887 492.4092 492.5298 492.6504 492.7709 492.8914 493.0119 493.1324 493.2529 493.3734 493.4938 493.6142 493.7346 493.8550 493.9754 494.0958 494.2161 494.3364 494.4567 494.5770 494.6973 494.8175 494.9378 495.0580 495.1782 495.2984 495.4186 495.5387 495.6589 495.7790 495.8991 496.0192 496.1392 496.2593 496.3793 496.4993 496.6193 496.7393 496.8593 496.9792 497.0992 497.2191 497.3390 497.4589 497.5787 497.6986 497.8184 497.9382 498.0580 498.1778 498.2976 498.4173 498.5371 498.6568 498.7765 498.8962 499.0158 499.1355 499.2551 499.3747 499.4943 499.6139 499.7334 499.8530 499.9725 500.0920 500.2115 500.3310 500.4504 500.5699 500.6893 500.8087 500.9281 501.0475 501.1668 501.2862 501.4055 501.5248 501.6441 501.7634 501.8826 502.0019 502.1211 502.2403 502.3595 502.4786 502.5978 502.7169 502.8360 502.9551 503.0742 503.1933 503.3123 503.4314 503.5504 503.6694 503.7884 503.9073 504.0263 504.1452 504.2641 504.3830 504.5019 504.6207 504.7396 504.8584 504.9772 505.0960 505.2148 505.3335 505.4523 505.5710 505.6897 505.8084 505.9271 506.0457 506.1644 506.2830 506.4016 506.5202 506.6387 506.7573 506.8758 506.9943 507.1128 507.2313 507.3498 507.4682 507.5867 507.7051 507.8235 507.9419 508.0602 508.1786 508.2969 508.4152 508.5335 508.6518 508.7700 508.8883 509.0065 509.1247 509.2429 509.3611 509.4792 509.5973 509.7155 509.8336 509.9517
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240507T100759.9Z 8893.422221 34 1 30.02 2 89.71 66.46 84.48 74.19 0.00 1 0.00 1 0 22 8.263e-03 8.191e-03 3.058e-04 3.043e-04 1.367884e+04 2.099436e+01 8.999224e+02 -6.000000e+00 4.579867e+02 279.32 -2.00 20.00 -2.00 505.44 0.00e+00 2.567311e-03 8.427960e-06 1.561412e-04 -6.000000e+00 2.303638e-04 279.32 -2.00 20.00 -2.00 501.13 0.00e+00 1.320520e+00 5.888452e-03 1.051826e-01 -6.000000e+00 1.649886e-01 230.15 -2.00 3.56 -2.00 502.62 0.00e+00 20.150 0.159 489.00 513.00 1 2.3960e+00 4.5005e-04 3.6643e-02 -6.0000e+00 1.2643e-02 -5.2196e-02 1.1225e-04 3.1460e-03 -6.0000e+00 3.2638e-03 9.6596e-03 1.6722e-03 2.9303e-05 1.2417e-04 -6.0000e+00 8.7146e-04 3.9311e-03 -3.3578e-05 12 8 8 10 0 0 10.24 27.66 9.40 0.00393 0.01553 159 159 1 4 0 188.800 36.00 20.00 27.66 18.09 3.9 908.42 -1452 -1097 -385 320 824 1314 1627 1588 1424 1024 703 184 -182 -313 -573 -612 -361 189 425 501 477 612 610 675 871 832 574 255 -194 -918 -1253 -1200 -835 -168 204 219 130 28 -273 -452 -345 -48 195 504 778 797 713 503 132 -407 -995 -1416 -1656 -1442 -858 -352 101 383 529 653 749 814 920 888 747 463 77 -193 -551 -775 -984 -862 -759 -577 -303 -547 -866 -1143 -1237 -1436 -1351 -1173 -1073 -943 -698 -657 -682 -676 -552 -542 -199 216 533 791 715 671 257 -367 -908 -1530 -1817 -1603 -1159 -634 -281 -228 -339 -515 -553 -454 -127 246 536 1038 1410 1573 1833 1762 1418 991 711 563 399 700 847 722 740 800 606 649 581 76 -265 -427 -770 -569 -142 71 220 491 455 415 504 529 484 309 25 -547 -1050 -1288 -1166 -1279 -958 -346 289 749 1219 1535 1486 1336 957 651 173 -170 -289 -529 -570 -334 179 402 481 461 594 595 649 843 810 559 247 -189 -876 -1181 -1135 -803 -163 199 217 129 28 -267 -441 -337 -48 194 499 778 802 717 503 130 -404 -969 -1356 -1605 -1378 -836 -346 102 383 530 655 753 823 934 905 759 467 77 -191 -551 -769 -973 -852 -757 -572 -302 -547 -858 -1140 -1220 -1411 -1328 -1158 -1049 -932 -696 -662 -679 -672 -546 -537 -198 216 537 797 709 660 250 -349 -866 -1445 -1716 -1508 -1125 -619 -285 -233 -349 -529 -566 -466 -130 254 557 1083 1475 1628 1916 1868 1493 1042 752 587 412 720 876 753 777 843 641 687 613 79 -276 -443 -804 -590 -150 76 237 529 497 459 552 584 536 342 28 -594 -1149 -1406 -1280
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SQ 20240507T101336.5Z 8893.426117 42 1 30.01 2 88.78 67.42 83.52 75.07 0.00 1 0.00 1 0 22 5.329e-03 5.291e-03 1.675e-04 1.671e-04 9.779894e+03 1.114111e+01 6.589025e+02 -6.000000e+00 2.953335e+02 279.32 -2.00 20.00 -2.00 505.40 0.00e+00 1.885524e-03 4.619367e-06 1.145189e-04 -6.000000e+00 1.485493e-04 279.32 -2.00 20.00 -2.00 500.97 0.00e+00 1.441276e+00 3.257208e-03 7.611830e-02 -6.000000e+00 1.063844e-01 230.15 -2.00 3.56 -2.00 502.49 0.00e+00 18.174 0.116 489.00 513.00 1 1.5101e+00 2.4920e-04 3.0561e-02 -6.0000e+00 8.1525e-03 -3.0916e-02 6.2524e-05 2.4184e-03 -6.0000e+00 2.1043e-03 3.0883e-02 1.1284e-03 1.6495e-05 9.1453e-05 -6.0000e+00 5.6193e-04 3.0672e-03 -2.1697e-05 12 8 8 10 0 0 -9.46 27.66 5.71 0.00307 0.01089 402 402 1 4 0 74.640 36.00 20.00 27.66 18.34 3.9 910.02 -923 -730 -252 181 448 842 1030 945 861 713 381 121 -198 -285 -347 -386 -178 90 296 275 285 449 415 498 581 517 336 172 -152 -553 -717 -687 -542 -60 114 56 52 25 -130 -268 -186 -73 95 319 476 542 480 292 43 -306 -663 -921 -1071 -1005 -614 -214 32 219 302 439 518 580 597 543 494 310 75 -190 -334 -488 -606 -537 -507 -369 -199 -325 -581 -708 -757 -839 -839 -770 -762 -610 -459 -461 -469 -400 -325 -256 -79 119 346 494 499 428 198 -208 -542 -945 -1197 -1048 -796 -436 -228 -308 -266 -294 -355 -275 -37 88 357 689 921 1051 1163 1147 924 650 492 393 301 476 516 346 442 535 404 441 402 42 -153 -231 -461 -395 -45 8 65 324 341 274 380 387 336 192 -1 -414 -754 -872 -773 -825 -662 -231 169 423 798 993 909 830 682 368 115 -188 -267 -329 -363 -170 86 291 270 282 446 408 491 577 515 335 170 -150 -533 -691 -664 -526 -59 114 57 52 26 -130 -266 -185 -73 94 322 484 547 484 296 43 -306 -647 -894 -1030 -972 -597 -211 33 221 306 443 525 590 603 550 497 314 75 -188 -332 -481 -594 -527 -501 -364 -198 -323 -573 -698 -738 -814 -815 -753 -751 -598 -455 -462 -466 -397 -322 -253 -79 120 346 495 501 421 192 -200 -519 -893 -1129 -1000 -772 -427 -229 -312 -270 -297 -356 -276 -37 89 366 711 956 1083 1210 1206 964 676 512 403 310 489 534 356 457 554 419 457 415 43 -155 -236 -473 -405 -46 9 68 342 365 293 409 420 366 209 -1 -440 -801 -921 -821
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