File name: Pandora243s1_Toronto-CNTower_20240508_L2Fit_fout2c5d20240208p1-8.txt
File generation date: 20241016T111824.4Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240508_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240508
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240508T113323.0Z 8894.481517 103 1 2.49 2 74.73 80.48 75.55 74.65 0.00 1 0.00 1 0 17 1.725e-01 9.314e-03 1.026e-01 5.450e-03 5.772778e-01 2.784101e-03 6.749089e-03 -6.000000e+00 9.851062e-02 230.25 -2.00 3.56 -2.00 319.55 0.00e+00 2.811845e-03 7.836644e-04 5.400714e-04 -6.000000e+00 4.271721e-03 279.45 -2.00 20.00 -2.00 318.92 0.00e+00 3.726 0.001 302.00 328.00 3 2.4209e+00 7.8714e-03 4.7387e-02 -6.0000e+00 2.4649e-01 8.2099e-02 9.2845e-03 3.0595e-02 -6.0000e+00 2.6770e-01 -7.6860e-02 7.6801e-03 1.5445e-02 -6.0000e+00 1.5881e-01 2.8128e-02 4.0373e-03 5.2093e-03 -6.0000e+00 6.6832e-02 6.3949e-04 -6.0619e-04 1.4477e-04 5.2351e-05 -6.0000e+00 4.6201e-03 -4.8256e-04 0.0000e+00 12 9 1 12 9 1 99.51 27.40 0.40 -0.00048 -0.00504 5 72 1 5 0 413.920 35.75 20.00 27.40 19.07 3.7 911.37 -39822 -62459 -98024 -39660 -84138 -29434 -63477 -30743 37577 -55119 -12631 -43518 -1247 -27475 -28259 -4357 -18498 -17773 -3754 -20639 -61 773 -7452 3995 -7356 -9639 -13890 -16249 -20595 -1190 7439 5632 6886 -4380 -4120 -12031 -9010 -2106 -911 -4080 2884 1333 -1144 -1376 3351 5033 2836 1318 3796 1686 510 2545 1999 2115 1534 1808 1854 -110 1161 497 807 2397 1807 1946 1172 798 1780 948 721 916 1389 1069 927 -438 -305 974 -2568 -2152 -1240 -1407 -1205 -1523 -2085 -1832 -1844 178 -710 200 1020 -251 572 -771 -73 658 1312 -475 -4 617 -355 -78 -1190 -369 -1246 -832 -484 -1089 -1500 -281 213 572 -144 240 392 293 242 459 690 135 151 -661 501 -269 369 293 542 1273 831 1180 948 134 -467 545 -89 -501 134 -468 189 116 -252 -399 -44 -217 -584 -571 -1261 -2917 -611 -1878 -391 -1316 -523 359 -1406 -222 -1226 -29 -1051 -1337 -188 -1013 -1058 -207 -1415 -3 44 -487 253 -555 -779 -1166 -1338 -1773 -94 640 575 787 -570 -506 -1650 -1365 -326 -170 -923 667 332 -305 -374 881 1328 777 377 1100 491 168 904 776 884 674 757 791 -47 518 223 351 1139 976 1072 659 431 1014 524 447 606 992 787 666 -299 -202 573 -1476 -1262 -817 -1021 -943 -1348 -1880 -1739 -1774 178 -751 213 1073 -254 563 -716 -68 601 1335 -534 -5 802 -471 -101 -1514 -442 -1398 -961 -602 -1358 -1981 -374 306 868 -229 394 632 449 364 661 1005 207 236 -1080 798 -416 575 438 808 1810 1146 1704 1467 222 -807 941 -162 -925 264 -930 379 237 -513 -779 -83 -408 -1073
SS 20240508T113926.8Z 8894.485727 107 1 29.98 2 73.65 81.47 74.51 75.56 0.00 1 0.00 1 0 17 1.165e-01 5.747e-03 6.509e-03 4.686e-04 5.443761e-01 2.381785e-04 6.360250e-03 -6.000000e+00 6.657034e-02 230.25 -2.00 3.56 -2.00 319.27 0.00e+00 1.059048e-03 6.121475e-05 2.758332e-04 -6.000000e+00 2.886308e-03 279.45 -2.00 20.00 -2.00 318.61 0.00e+00 3.494 0.001 302.00 328.00 3 4.9726e-01 6.6660e-04 4.4509e-02 -6.0000e+00 1.6657e-01 3.5795e-02 7.7783e-04 2.8780e-02 -6.0000e+00 1.8089e-01 -4.8125e-02 6.1677e-04 1.4220e-02 -6.0000e+00 1.0731e-01 1.6641e-02 3.2551e-04 4.1917e-03 -6.0000e+00 4.5170e-02 5.7686e-03 -2.6112e-04 1.2585e-05 4.2513e-05 -6.0000e+00 3.1213e-03 -2.0512e-03 0.0000e+00 10 0 0 10 0 0 64.28 27.41 0.45 -0.00205 -0.00401 629 629 1 5 0 47.660 35.75 20.00 27.41 19.05 3.8 912.96 -39669 -38556 -36896 -43483 -51404 -44015 -41201 -31752 -33732 -29842 -31470 -27768 -18512 -14830 -8070 -8780 -5809 -4637 -3255 -3650 -4755 -4483 -3321 -2967 -4640 -3241 -4080 -5586 -5838 -4432 -1066 -1143 -215 -1845 -3535 -4173 -2743 -1939 -148 731 392 76 541 761 768 763 343 360 28 945 1385 1859 1686 1651 1281 1068 843 606 383 706 1013 1581 2243 1826 975 239 -20 195 535 603 557 374 286 -172 -398 -725 -1109 -1013 -817 -703 -812 -1282 -1746 -1816 -1095 -480 -175 133 493 506 580 345 122 108 -18 15 343 439 56 -458 -582 -444 -538 -508 -680 -799 -668 -342 17 270 276 343 274 191 188 177 191 109 -29 -217 -103 43 222 417 398 352 633 628 493 392 65 161 -89 -84 -92 -133 26 73 -82 -110 -285 -208 -445 -761 -816 -789 -920 -1095 -901 -919 -740 -899 -809 -907 -898 -680 -651 -402 -504 -355 -305 -225 -266 -354 -337 -265 -257 -439 -316 -399 -528 -548 -452 -123 -152 -29 -258 -475 -583 -431 -365 -33 193 104 22 158 225 229 232 106 113 9 327 530 719 709 748 610 528 427 303 187 342 515 822 1303 1089 590 139 -11 115 353 427 428 296 221 -126 -283 -464 -670 -623 -565 -534 -668 -1126 -1656 -1725 -1109 -514 -186 144 526 541 573 335 113 104 -19 17 413 569 74 -619 -730 -526 -626 -613 -846 -997 -879 -457 25 412 438 540 441 291 279 252 276 165 -45 -350 -164 67 346 620 590 501 867 901 757 638 110 276 -158 -153 -173 -262 50 143 -161 -214 -543 -376 -813
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