File name: Pandora243s1_Toronto-CNTower_20240602_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T134510.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240602_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240602T160859.5Z 8919.672911 379 1 30.68 2 25.41 141.77 46.49 231.47 0.00 1 0.00 1 0 17 1.317e-02 7.913e-03 8.009e-03 3.887e-03 1.978313e-01 1.965693e-03 2.397034e-03 -6.000000e+00 7.575025e-03 232.03 -2.00 3.56 -2.00 316.39 0.00e+00 4.047322e-04 2.221914e-04 3.425766e-05 -6.000000e+00 3.299777e-04 282.17 -2.00 20.00 -2.00 315.70 0.00e+00 1.107 0.000 302.00 328.00 3 6.7187e+00 5.1602e-03 1.5106e-02 -6.0000e+00 1.9020e-02 3.8847e-02 5.7569e-03 1.0430e-02 -6.0000e+00 2.0616e-02 -7.3679e-03 3.3176e-03 5.0692e-03 -6.0000e+00 1.2231e-02 -4.7954e-04 1.5466e-03 1.4043e-03 -6.0000e+00 5.1423e-03 1.7381e-04 -6.6672e-05 1.1002e-04 1.5908e-05 -6.0000e+00 3.5297e-04 -2.7427e-03 0.0000e+00 11 9 0 11 8 0 99.55 27.75 0.40 -0.00274 -0.00324 9 9 1 5 0 3407.810 36.00 20.00 27.75 21.94 3.8 933.70 -3966 -964 185 -3830 -5226 -5175 576 -375 -93 -2317 -1656 -1439 1159 -1695 77 3145 887 663 1283 2269 -1386 1790 1766 2554 537 767 -1304 -1343 1587 -22 -424 1415 1309 -509 -3246 -1940 -796 562 723 -404 -900 -536 -256 271 -531 -437 -36 -439 -1297 -32 -731 1458 750 1873 1495 1310 -653 784 712 -1052 -466 1141 1673 840 460 191 -1778 -266 -31 -34 366 841 894 -250 -266 -687 -2530 -2321 -2692 -1087 -1285 -1544 -1105 -1146 -439 303 979 1260 987 627 170 -296 -501 -1115 -360 -360 245 1498 790 -411 -223 -902 -1574 -1081 73 -458 -569 896 -159 630 829 596 635 -66 -531 -881 -347 -348 -402 -195 566 489 539 168 -412 369 108 -644 652 110 -81 135 -68 -300 284 10 159 351 61 -95 -44 -787 -240 -843 -208 39 -742 -919 -906 103 -76 -20 -524 -360 -327 287 -486 24 1011 297 229 453 816 -516 639 651 980 218 318 -534 -505 541 -8 -155 541 534 -207 -1249 -749 -340 278 426 -249 -590 -361 -175 184 -361 -294 -23 -303 -877 -22 -524 984 534 1374 1120 998 -512 598 534 -805 -370 959 1502 791 417 157 -1384 -200 -25 -31 361 852 895 -243 -238 -550 -2050 -1797 -2222 -901 -1185 -1558 -1168 -1269 -519 381 1280 1685 1315 797 199 -316 -488 -1064 -362 -399 299 1976 1089 -554 -280 -1053 -1776 -1283 94 -615 -799 1293 -223 922 1260 902 913 -96 -706 -1109 -437 -460 -574 -272 797 741 796 237 -553 467 130 -788 837 150 -115 196 -100 -459 421 15 253 571 100 -151 -68 -1180 -351 SS 20240602T163957.9Z 8919.694420 401 1 31.96 2 22.58 158.03 50.89 239.52 0.00 1 0.00 1 0 17 1.818e-02 9.976e-03 1.374e-02 6.344e-03 2.047487e-01 3.193756e-03 2.483146e-03 -6.000000e+00 1.045317e-02 232.03 -2.00 3.56 -2.00 316.49 0.00e+00 2.260946e-04 3.722188e-04 1.317861e-04 -6.000000e+00 4.554037e-04 282.18 -2.00 20.00 -2.00 315.77 0.00e+00 1.083 0.000 302.00 328.00 3 7.3497e+00 8.4167e-03 1.5229e-02 -6.0000e+00 2.6246e-02 6.8630e-02 9.4181e-03 1.0787e-02 -6.0000e+00 2.8451e-02 -1.7661e-02 5.4460e-03 5.2406e-03 -6.0000e+00 1.6880e-02 3.6093e-03 2.5257e-03 1.4208e-03 -6.0000e+00 7.0951e-03 9.2469e-05 -7.5575e-05 1.7967e-04 1.6228e-05 -6.0000e+00 4.8718e-04 -1.4133e-03 0.0000e+00 12 8 8 10 0 0 98.93 27.69 1.20 -0.00141 -0.00198 8 8 1 5 0 3994.230 36.00 20.00 27.69 23.54 3.7 946.23 3720 3667 1272 -4889 -9704 6200 -4959 -3612 1459 -5071 -2643 -2270 2059 -777 994 -994 2553 2102 2653 944 -2144 1044 -1006 3247 -1257 371 579 -615 213 -1754 -120 1864 -1378 -1316 -2104 -2911 -2228 -2833 1266 2331 -939 109 942 -77 -150 -519 -836 -1141 -182 -463 622 509 -289 905 -37 318 -341 1601 1080 -762 1130 1396 1289 1119 764 450 -545 -711 -984 1397 554 844 778 567 -895 -1974 -2946 -2598 -1217 -1427 -219 -777 -1526 -1222 -88 783 1398 915 1142 945 -604 -1383 -233 -1431 -2843 -428 -232 922 731 -357 -214 -645 -897 -162 -291 -993 279 -348 418 768 1257 1797 1667 -378 -921 -1828 -1428 -957 118 141 1198 676 277 759 -765 239 -686 -683 -107 158 367 1339 -125 -761 74 125 497 495 26 -451 506 -784 -667 695 717 249 -904 -1687 917 -890 -715 298 -1114 -549 -493 479 -209 292 -315 794 676 873 325 -759 354 -360 1167 -491 145 219 -216 69 -582 -41 668 -543 -507 -753 -1068 -908 -1365 698 1442 -637 75 658 -54 -105 -359 -562 -742 -114 -293 412 357 -214 691 -29 252 -274 1246 828 -597 905 1199 1191 1077 707 378 -430 -552 -832 1302 560 876 797 557 -821 -1630 -2224 -1873 -920 -1214 -205 -795 -1655 -1384 -96 907 1686 1136 1407 1107 -724 -1513 -230 -1395 -2992 -484 -289 1134 933 -445 -273 -763 -1021 -193 -377 -1360 393 -468 583 1129 1913 2704 2381 -558 -1246 -2356 -1843 -1290 170 196 1679 1031 413 1072 -1037 305 -837 -842 -139 217 525 1933 -185 -1179 110 194 786 801 42 -717 771 -1285 -1070 SS 20240602T164517.6Z 8919.698120 404 1 30.37 2 22.24 161.13 51.69 240.81 0.00 1 0.00 1 0 25 2.151e-02 1.157e-02 1.587e-02 7.097e-03 2.057345e-01 3.567381e-03 2.478522e-03 -6.000000e+00 1.236819e-02 232.03 -2.00 3.56 -2.00 316.59 0.00e+00 9.596335e-04 4.242476e-04 1.665205e-04 -6.000000e+00 5.387826e-04 282.18 -2.00 20.00 -2.00 315.86 0.00e+00 1.080 0.000 302.00 328.00 3 7.4494e+00 9.3921e-03 1.5206e-02 -6.0000e+00 3.1055e-02 7.5627e-02 1.0516e-02 1.0783e-02 -6.0000e+00 3.3661e-02 -1.6028e-02 6.0999e-03 5.2337e-03 -6.0000e+00 1.9971e-02 2.7938e-04 2.8507e-03 1.4918e-03 -6.0000e+00 8.3960e-03 8.3215e-05 -8.1550e-05 2.0140e-04 1.6099e-05 -6.0000e+00 5.7632e-04 -2.6121e-03 0.0000e+00 12 9 8 11 8 0 91.39 27.68 0.18 -0.00261 -0.00322 10 10 1 5 0 3036.340 36.00 20.00 27.68 23.94 3.8 949.68 -2740 219 -537 -6226 9286 -8082 1356 606 -1848 -4180 -9842 -1624 5461 4519 1863 -2982 -1265 1498 3530 383 -2288 -1126 3697 731 1019 -411 -1760 287 -2748 -475 822 975 57 -1422 -5504 -2766 -1018 -1923 1314 3539 67 -551 1287 950 97 501 -184 56 -2188 1223 -521 1382 562 741 -275 525 -248 1255 68 19 -264 2104 2520 828 50 -216 -2041 211 -1094 359 289 110 534 1401 -478 -2075 -2823 -2342 -3444 -1836 -259 -1022 -1014 -859 -59 1009 1936 555 827 858 -509 -1248 -657 -2925 -1437 -633 554 1522 2293 182 -1022 -865 -1647 -2406 -2254 -584 120 900 212 766 1211 939 744 -482 -923 -1039 -1023 -1008 1036 105 1734 245 1189 606 1464 -730 -22 -437 -804 563 -164 -275 876 -353 -815 -96 -44 583 455 378 -337 -114 -1213 -483 39 -104 -1142 1305 -1342 222 111 -376 -877 -2119 -338 1191 1123 530 -943 -401 476 1131 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