File name: Pandora243s1_Toronto-CNTower_20240602_L2Fit_fwvt1c5d20240208p1-8.txt
File generation date: 20241016T135040.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240602_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240602
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0474 492.1680 492.2887 492.4092 492.5298 492.6504 492.7709 492.8914 493.0119 493.1324 493.2529 493.3734 493.4938 493.6142 493.7346 493.8550 493.9754 494.0958 494.2161 494.3364 494.4567 494.5770 494.6973 494.8175 494.9378 495.0580 495.1782 495.2984 495.4186 495.5387 495.6589 495.7790 495.8991 496.0192 496.1392 496.2593 496.3793 496.4993 496.6193 496.7393 496.8593 496.9792 497.0992 497.2191 497.3390 497.4589 497.5787 497.6986 497.8184 497.9382 498.0580 498.1778 498.2976 498.4173 498.5371 498.6568 498.7765 498.8962 499.0158 499.1355 499.2551 499.3747 499.4943 499.6139 499.7334 499.8530 499.9725 500.0920 500.2115 500.3310 500.4504 500.5699 500.6893 500.8087 500.9281 501.0475 501.1668 501.2862 501.4055 501.5248 501.6441 501.7634 501.8826 502.0019 502.1211 502.2403 502.3595 502.4786 502.5978 502.7169 502.8360 502.9551 503.0742 503.1933 503.3123 503.4314 503.5504 503.6694 503.7884 503.9073 504.0263 504.1452 504.2641 504.3830 504.5019 504.6207 504.7396 504.8584 504.9772 505.0960 505.2148 505.3335 505.4523 505.5710 505.6897 505.8084 505.9271 506.0457 506.1644 506.2830 506.4016 506.5202 506.6387 506.7573 506.8758 506.9943 507.1128 507.2313 507.3498 507.4682 507.5867 507.7051 507.8235 507.9419 508.0602 508.1786 508.2969 508.4152 508.5335 508.6518 508.7700 508.8883 509.0065 509.1247 509.2429 509.3611 509.4792 509.5973 509.7155 509.8336 509.9517
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240602T135305.9Z 8919.578540 294 1 31.57 2 46.66 100.33 35.76 182.99 0.00 1 0.00 1 0 15 4.226e-03 4.249e-03 3.656e-03 3.636e-03 5.405019e+03 2.425523e+02 3.778027e+02 -6.000000e+00 2.368882e+02 282.16 -2.00 20.00 -2.00 505.28 0.00e+00 5.684575e-04 1.003168e-04 4.312610e-05 -6.000000e+00 1.186288e-04 282.16 -2.00 20.00 -2.00 500.23 0.00e+00 2.027539e-01 7.364044e-02 3.789183e-02 -6.000000e+00 8.442670e-02 232.02 -2.00 3.56 -2.00 501.86 0.00e+00 1.455 0.000 489.00 513.00 1 9.2407e+00 5.6533e-03 3.9121e-03 -6.0000e+00 6.4755e-03 7.1686e-03 1.4359e-03 9.1906e-04 -6.0000e+00 1.6706e-03 1.5087e-04 1.0072e-03 3.6644e-04 3.8363e-05 -6.0000e+00 4.4580e-04 -3.4845e-03 1.8951e-05 11 8 0 10 0 0 55.76 27.82 2.34 -0.00348 0.00350 8 8 1 4 0 3945.570 36.00 19.99 27.82 24.23 3.7 949.14 -565 -446 56 267 -357 370 1159 333 611 48 816 282 -4 -26 -649 -384 -525 360 0 424 -272 795 -283 -382 5 738 359 73 113 -422 -1149 -230 -347 -213 222 -417 502 105 -629 349 110 -231 -30 727 -232 319 491 -16 117 248 -649 -199 -40 -595 1158 -409 -448 120 -258 -72 -784 -28 -75 -481 321 549 -66 -814 510 18 -178 -18 66 -246 357 -392 -813 -472 -303 -164 -57 -73 -311 129 -323 -577 -110 560 524 315 -420 404 -304 101 -271 327 -227 -376 -161 40 21 -404 -719 136 -607 -533 -26 -332 659 -494 95 -280 390 408 183 164 79 351 516 -136 466 418 -96 533 -360 28 16 281 -288 562 -120 393 423 277 0 59 136 -66 81 306 657 -197 777 112 296 117 67 -301 -948 -396 -644 -561 -448 57 269 -372 391 1235 361 660 52 858 294 -4 -26 -659 -390 -541 376 0 459 -298 863 -311 -421 5 806 392 79 119 -435 -1170 -232 -357 -226 240 -459 545 114 -676 368 116 -245 -33 781 -254 349 533 -17 124 255 -656 -196 -38 -580 1133 -418 -469 120 -261 -72 -796 -29 -76 -489 322 543 -64 -830 507 18 -174 -18 65 -246 358 -376 -773 -462 -292 -157 -55 -70 -303 120 -305 -551 -105 532 497 300 -405 390 -299 99 -265 312 -212 -343 -143 36 19 -353 -649 127 -586 -523 -26 -320 624 -472 91 -273 382 403 183 164 80 355 519 -136 457 403 -92 507 -347 26 15 269 -277 534 -115 368 390 252 0 54 127 -63 78 299 645 -197 772 113 297 112 66 -292 -908 -373 -609
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SQ 20240602T144354.8Z 8919.613829 331 1 31.99 2 37.83 111.92 37.60 203.46 0.00 1 0.00 1 0 22 4.822e-03 4.813e-03 3.922e-03 3.902e-03 5.842582e+03 2.587220e+02 4.206718e+02 -6.000000e+00 2.703312e+02 282.17 -2.00 20.00 -2.00 505.23 0.00e+00 3.028227e-04 1.074480e-04 3.194532e-05 -6.000000e+00 1.353668e-04 282.17 -2.00 20.00 -2.00 500.25 0.00e+00 2.416233e-01 7.893128e-02 3.653187e-02 -6.000000e+00 9.630367e-02 232.03 -2.00 3.56 -2.00 501.86 0.00e+00 1.265 0.000 489.00 513.00 1 9.3551e+00 6.0579e-03 3.6675e-03 -6.0000e+00 7.3871e-03 4.0566e-03 1.5436e-03 9.2940e-04 -6.0000e+00 1.9049e-03 1.3812e-04 -1.5041e-04 3.9087e-04 4.6836e-05 -6.0000e+00 5.0859e-04 -1.9660e-03 4.0373e-05 12 8 8 10 0 0 33.50 27.83 2.29 -0.00197 -0.00301 8 8 1 4 0 3998.310 36.00 20.00 27.83 23.72 3.6 943.93 -773 29 71 374 58 507 1189 848 469 -108 500 -313 -212 -96 182 -208 -172 1307 -8 -11 -331 470 -14 129 548 357 -421 351 278 -578 -981 -200 -551 -406 218 -377 -272 -22 -171 -29 532 173 100 -65 -693 949 -78 123 -191 -719 -583 73 -721 -1091 -195 -1177 -312 366 254 -120 224 -144 -93 866 629 -79 304 -324 -123 698 -751 -4 1233 -558 -68 406 -571 -771 -587 257 -323 -117 -1382 179 -49 -302 -1034 311 180 252 -119 -237 517 450 -156 302 532 2 -331 -793 -610 -144 -482 -267 -219 -600 -287 346 336 32 -379 -63 -211 -152 637 464 700 894 -19 -159 56 10 341 -547 -214 35 539 686 342 -351 -8 -244 861 -31 298 -425 235 290 -698 260 318 94 -145 253 293 311 669 45 -317 -396 -32 -761 29 72 392 62 529 1253 905 502 -115 522 -325 -217 -97 191 -209 -175 1339 -9 -12 -360 507 -15 140 594 388 -459 375 291 -592 -989 -200 -562 -426 233 -411 -295 -24 -181 -30 553 181 105 -70 -754 1018 -84 131 -200 -740 -583 71 -694 -1056 -191 -1198 -322 380 265 -126 234 -151 -98 902 653 -82 308 -326 -121 676 -732 -4 1186 -553 -68 401 -563 -748 -561 242 -306 -112 -1343 172 -48 -298 -1036 308 178 249 -119 -239 523 457 -150 299 512 2 -305 -720 -549 -130 -450 -259 -208 -582 -277 328 315 30 -362 -61 -206 -150 625 458 694 888 -19 -157 54 9 322 -520 -203 33 510 648 323 -333 -7 -228 781 -28 268 -387 216 272 -673 251 310 93 -143 251 291 307 650 44 -300 -370 -30
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