File name: Pandora243s1_Toronto-CNTower_20240604_L2Fit_fout2c5d20240208p1-8.txt File generation date: 20241016T134726.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240604_L1_smca1c5d20240208p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240604T102225.2Z 8921.432237 109 1 29.49 2 83.72 64.70 66.20 86.02 0.00 1 0.00 1 0 25 7.044e-01 5.014e-02 5.652e-01 4.137e-02 1.018438e+00 2.491900e-02 1.133950e-02 -6.000000e+00 4.129061e-01 232.14 -2.00 3.56 -2.00 322.36 0.00e+00 -5.914408e-03 1.338048e-02 4.420548e-03 -6.000000e+00 2.162719e-02 282.36 -2.00 20.00 -2.00 321.89 0.00e+00 8.233 0.011 302.00 328.00 3 1.9295e+00 9.7235e-02 1.0088e-01 -6.0000e+00 1.0443e+00 1.7062e+00 1.1731e-01 6.4033e-02 -6.0000e+00 1.1385e+00 -1.9350e+00 7.6810e-02 2.9189e-02 -6.0000e+00 6.6774e-01 7.1761e-01 3.9234e-02 8.1769e-03 -6.0000e+00 2.8223e-01 8.0714e-06 -2.6100e-03 1.0947e-03 1.2606e-04 -6.0000e+00 2.0061e-02 -4.2531e-04 0.0000e+00 12 8 8 10 0 0 71.16 27.70 1.93 -0.00043 -0.02004 13 13 1 5 0 2268.340 36.00 20.00 27.70 27.92 3.6 972.40 4017 900000 -58138 44393 6611 110010 3234 -125813 900000 900000 900000 -18662 -58815 -42437 -94272 50005 900000 -7377 66391 25353 67571 900000 103883 900000 -37604 139626 241024 900000 748 900000 900000 12428 -66232 19967 900000 253025 65834 900000 85259 127873 175111 900000 82906 307596 94184 189197 137123 6228 57019 118810 116628 94424 85316 -19942 35503 176821 38236 28786 -8025 -12402 39282 8929 22131 20932 192368 65643 78052 20610 44144 120459 37068 68387 59780 29463 15787 47260 -24506 4867 -29951 19755 7947 -12636 4710 -12205 24525 24135 -13039 15101 19757 -1941 -11501 1872 -3870 -1989 -16662 -8089 -1421 900 587 -8409 7248 2324 4608 4488 -10033 -2180 -5893 -2250 -5417 -3514 -4660 4178 -6181 288 63 -5060 558 5451 3089 1909 1235 6615 -231 62 2622 2451 1869 3325 7818 524 -2576 -755 1287 1076 -13 -2562 60 3650 866 -1750 -2124 -1901 257 162 900000 -3314 1786 266 4427 130 -9704 900000 900000 900000 -751 -3443 -2484 -10691 2012 900000 -405 2672 1020 2719 900000 4180 900000 -2476 5619 9699 900000 30 900000 900000 546 -7027 877 900000 10182 2649 900000 3431 5146 7047 900000 3336 12378 3790 7614 5518 433 2503 4781 4693 3800 4058 -2918 3117 7116 3357 2633 -969 -1452 2730 915 2267 2450 7741 5043 5425 2714 5168 8241 6265 8531 7698 4624 2478 4755 -4832 764 -7834 3816 2047 -4627 1592 -5157 7599 7867 -6349 5591 6838 -789 -4767 648 -1433 -792 -9052 -4818 -938 677 485 -7546 5162 1534 2652 2583 -7147 -1509 -4506 -1820 -5145 -3832 -5926 5313 -9005 390 83 -6842 728 7107 4338 2759 1725 8226 -295 76 3050 2781 2099 4001 10665 900 -5173 -1634 2941 2664 -35 -7444 172 10194 2450 -4767 -5326 -4369 551 SS 20240604T103250.5Z 8921.439473 112 1 29.72 2 82.01 66.40 64.34 87.67 0.00 1 0.00 1 0 17 5.109e-01 2.662e-02 3.656e-01 1.683e-02 9.037969e-01 9.294851e-03 1.000229e-02 -6.000000e+00 2.938625e-01 232.14 -2.00 3.56 -2.00 321.95 0.00e+00 -3.605501e-03 4.788779e-03 4.802471e-03 -6.000000e+00 1.280829e-02 282.36 -2.00 20.00 -2.00 321.45 0.00e+00 6.721 0.006 302.00 328.00 3 2.5097e+00 3.4326e-02 8.6864e-02 -6.0000e+00 7.3800e-01 1.1410e+00 4.3422e-02 6.3702e-02 -6.0000e+00 7.9995e-01 -1.5093e+00 3.3738e-02 2.6480e-02 -6.0000e+00 4.7460e-01 6.0899e-01 1.6170e-02 8.2971e-03 -6.0000e+00 1.9945e-01 2.4080e-05 -7.2396e-04 4.3394e-04 1.0373e-04 -6.0000e+00 1.3693e-02 -2.8381e-04 0.0000e+00 12 8 8 10 0 0 79.64 27.72 1.26 -0.00028 -0.00572 18 18 1 5 0 1650.960 36.00 20.01 27.72 27.67 3.6 970.93 37391 -73877 -11761 -86432 -11129 -95989 -18219 -118813 -6984 249497 -123372 -20327 33049 15742 25172 -67607 167401 -21227 26263 22923 -26070 246348 30802 -42586 65203 14632 182399 -56571 74857 15873 23538 138582 -17525 59653 80181 24914 -11607 59253 25507 70829 22225 40607 35071 52335 48830 26102 90708 59298 18266 22347 52963 35518 29777 18201 100050 52434 27025 27870 17764 35645 72216 26985 23389 12318 11335 12175 7799 14853 15403 11046 15446 10312 2994 -5945 -195 275 -4320 13168 1923 -6792 -9828 5334 4437 -2546 -6220 2480 1143 -778 -3758 10483 295 -5769 2158 -1515 -7922 -1132 -3282 -2642 -1737 110 -639 -2197 -5594 -5364 -6726 -1283 -4976 531 -319 803 -2582 1206 136 -1278 1441 -1587 -65 -158 -60 2366 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-6.000000e+00 3.429002e-01 232.14 -2.00 3.56 -2.00 321.60 0.00e+00 3.017836e-03 1.573330e-03 1.675945e-03 -6.000000e+00 1.494484e-02 282.36 -2.00 20.00 -2.00 321.07 0.00e+00 5.711 0.004 302.00 328.00 3 2.2704e+00 1.0607e-02 7.0920e-02 -6.0000e+00 8.6116e-01 2.9722e-01 1.5502e-02 4.5552e-02 -6.0000e+00 9.3341e-01 -3.9658e-01 1.6109e-02 2.4554e-02 -6.0000e+00 5.5378e-01 1.5270e-01 7.3940e-03 8.2986e-03 -6.0000e+00 2.3274e-01 9.6694e-05 -6.4420e-04 1.4256e-04 1.0188e-04 -6.0000e+00 1.5976e-02 -9.1131e-04 0.0000e+00 12 8 8 10 0 0 11.03 27.73 0.61 -0.00091 -0.00575 43 43 1 5 0 702.540 36.00 20.00 27.73 27.51 3.6 971.18 -91552 -246419 -152848 -98650 -220733 -148505 -93122 -277372 -218935 -173668 -125286 -177110 -130028 -128738 -114346 -87845 -15470 -112792 -67413 -10354 -10377 -32054 -80971 -62345 -58258 -19219 -72088 -29894 6975 -1053 -21763 -11943 -20171 -12318 -19496 -9223 -25301 -16844 -6679 -1704 16927 7186 5236 13021 -959 1902 16425 13515 -5433 15227 20912 19624 9667 18057 10926 15132 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