File name: Pandora243s1_Toronto-CNTower_20240606_L2Fit_fout2c5d20240208p1-8.txt
File generation date: 20241016T135838.8Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240606_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240606
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240606T113712.7Z 8923.484175 125 1 23.04 2 70.90 76.43 68.24 73.47 0.00 1 0.00 1 0 17 7.518e-02 6.342e-03 6.385e-02 4.663e-03 4.297801e-01 2.375718e-03 5.001030e-03 -6.000000e+00 4.326760e-02 232.27 -2.00 3.56 -2.00 319.37 0.00e+00 2.283176e-05 6.213273e-04 3.140898e-04 -6.000000e+00 1.886486e-03 282.57 -2.00 20.00 -2.00 318.66 0.00e+00 3.020 0.000 302.00 328.00 3 4.7090e+00 6.6830e-03 3.7191e-02 -6.0000e+00 1.0869e-01 5.3478e-02 7.8108e-03 2.2932e-02 -6.0000e+00 1.1779e-01 -1.7638e-02 5.9894e-03 1.1199e-02 -6.0000e+00 6.9885e-02 -7.1367e-05 3.1413e-03 3.0930e-03 -6.0000e+00 2.9370e-02 1.5074e-04 -9.7217e-05 1.3388e-04 3.1969e-05 -6.0000e+00 2.0149e-03 -1.2614e-03 0.0000e+00 12 1 1 12 1 1 99.92 27.87 0.65 -0.00126 -0.00199 10 14 1 5 0 2094.300 36.00 20.00 27.87 26.35 3.6 963.22 -33013 3003 47859 13557 -6285 -30474 -2847 -9112 -27932 9263 -13840 30203 -10442 765 -7909 8214 -6542 -7506 -932 -11820 6031 -3339 -12824 -7982 -4357 -3717 -5255 -5987 111 744 -5493 4234 1498 -3343 -1427 -7298 -3277 1200 1266 -1404 2641 2065 -1866 1525 678 2173 2550 -2536 -671 939 100 1501 1539 2336 1922 1570 -967 -162 -120 599 1973 278 2119 1631 937 526 -1564 -381 850 78 1032 41 1534 156 -885 -788 -1435 -1060 -125 -1811 -1653 -2175 -1318 -675 -749 -557 577 170 104 330 307 -500 721 -444 482 280 306 924 70 60 -969 -322 284 -765 -530 -395 -756 -175 -242 330 665 202 100 401 -237 -52 -133 -567 62 29 201 209 524 307 625 -156 158 -335 524 -67 82 142 24 391 150 -364 -249 231 37 -367 -586 -75 195 -946 66 675 247 -129 -818 -65 -253 -1042 249 -478 755 -470 37 -489 482 -476 -590 -72 -1070 461 -282 -1271 -817 -458 -404 -571 -615 10 74 -654 514 207 -486 -191 -1072 -526 221 284 -375 736 607 -590 469 211 671 780 -819 -215 312 37 590 649 1042 894 687 -443 -73 -58 286 973 139 1151 957 548 289 -849 -208 509 53 761 32 1137 111 -580 -462 -787 -578 -75 -1272 -1317 -1939 -1243 -611 -730 -578 619 187 114 343 294 -485 651 -411 486 293 361 1214 98 81 -1231 -370 306 -872 -653 -510 -1029 -250 -343 506 1087 338 163 609 -336 -76 -196 -817 95 46 322 326 791 444 929 -224 217 -478 815 -105 138 247 42 735 279 -713 -498 470 76 -720 -1097 -143 365
SS 20240606T114538.6Z 8923.490030 128 1 2.70 2 69.41 77.76 66.82 74.68 0.00 1 0.00 1 0 25 3.926e-02 8.280e-03 4.305e-02 6.568e-03 4.029559e-01 3.335094e-03 4.761779e-03 -6.000000e+00 2.259975e-02 232.27 -2.00 3.56 -2.00 318.30 0.00e+00 8.890765e-04 6.361326e-04 2.445193e-04 -6.000000e+00 9.851854e-04 282.58 -2.00 20.00 -2.00 317.56 0.00e+00 2.815 0.000 302.00 328.00 3 3.6829e+00 9.0767e-03 3.4713e-02 -6.0000e+00 5.6771e-02 4.1425e-02 1.0304e-02 2.1381e-02 -6.0000e+00 6.1518e-02 -2.8385e-02 6.8398e-03 1.0400e-02 -6.0000e+00 3.6499e-02 8.2534e-03 3.5529e-03 2.9627e-03 -6.0000e+00 1.5344e-02 5.2992e-04 2.1455e-04 1.8322e-04 3.0070e-05 -6.0000e+00 1.0521e-03 -3.4499e-03 0.0000e+00 12 9 1 12 1 1 999.00 27.84 0.39 -0.00345 -0.00184 2 33 1 5 0 898.460 36.00 19.99 27.84 26.73 3.6 966.37 6436 17947 3955 7915 -9634 -11703 -21325 2153 -21469 2843 1101 5026 -2517 -4397 -1097 -7211 6956 -1366 -5949 -1907 3276 -4422 -1456 -2619 -3057 -2281 -423 -8097 -5050 -2944 -928 4837 -1746 -3242 1450 -2595 -1143 1297 755 235 404 382 -1896 -658 192 2355 -797 -1587 1646 184 1695 504 34 3026 1096 -511 450 -410 3478 779 671 1033 3080 -428 1119 287 -510 240 496 162 1422 171 -14 -422 -397 -53 -1910 40 -1322 60 -1043 -771 -1351 -1751 -1992 395 12 877 895 672 -447 476 -210 1048 -936 -514 856 105 398 -814 -1953 -1038 -452 -562 -694 -953 -275 -847 127 -4 872 1282 -252 267 162 812 321 231 -769 -657 -14 436 525 308 821 1147 52 333 449 210 -86 578 527 22 -118 7 -315 147 227 -361 -612 -459 -489 268 724 185 324 -432 -547 -1216 110 -1540 166 66 325 -210 -445 -126 -975 869 -198 -863 -277 499 -664 -225 -439 -545 -418 -75 -1452 -850 -514 -178 980 -417 -785 314 -603 -297 393 255 92 172 170 -823 -308 89 1080 -374 -751 760 83 823 268 20 1788 635 -309 274 -249 2135 457 413 694 2239 -322 818 197 -364 172 368 129 1207 152 -13 -349 -320 -38 -1390 28 -979 50 -944 -728 -1365 -1873 -2169 448 13 1005 1075 769 -476 490 -204 1018 -1016 -591 1037 136 539 -1084 -2577 -1238 -535 -662 -886 -1216 -366 -1198 182 -6 1363 2028 -391 405 228 1135 456 329 -1183 -1013 -21 649 796 447 1184 1577 70 457 641 327 -136 943 846 37 -205 13 -586 266 411 -658 -1068 -799 -832
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