File name: Pandora243s1_Toronto-CNTower_20240611_L2Fit_fwvt1c2d20230307p1-8.txt
File generation date: 20241003T104915.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240611_L1_smca1c2d20230307p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240611
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off session 1
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0337 492.1543 492.2749 492.3955 492.5160 492.6366 492.7571 492.8776 492.9981 493.1185 493.2390 493.3594 493.4798 493.6002 493.7206 493.8410 493.9614 494.0817 494.2020 494.3223 494.4426 494.5629 494.6831 494.8033 494.9236 495.0438 495.1639 495.2841 495.4043 495.5244 495.6445 495.7646 495.8847 496.0048 496.1248 496.2448 496.3648 496.4848 496.6048 496.7248 496.8447 496.9647 497.0846 497.2045 497.3244 497.4442 497.5641 497.6839 497.8037 497.9235 498.0433 498.1630 498.2828 498.4025 498.5222 498.6419 498.7616 498.8812 499.0009 499.1205 499.2401 499.3597 499.4793 499.5988 499.7184 499.8379 499.9574 500.0769 500.1963 500.3158 500.4352 500.5546 500.6740 500.7934 500.9128 501.0321 501.1515 501.2708 501.3901 501.5094 501.6286 501.7479 501.8671 501.9863 502.1055 502.2247 502.3439 502.4630 502.5821 502.7013 502.8203 502.9394 503.0585 503.1775 503.2965 503.4156 503.5345 503.6535 503.7725 503.8914 504.0103 504.1292 504.2481 504.3670 504.4859 504.6047 504.7235 504.8423 504.9611 505.0799 505.1986 505.3173 505.4361 505.5548 505.6734 505.7921 505.9107 506.0294 506.1480 506.2666 506.3852 506.5037 506.6223 506.7408 506.8593 506.9778 507.0963 507.2147 507.3331 507.4516 507.5700 507.6884 507.8067 507.9251 508.0434 508.1617 508.2800 508.3983 508.5166 508.6348 508.7531 508.8713 508.9895 509.1076 509.2258 509.3440 509.4621 509.5802 509.6983 509.8164 509.9344
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240611T122002.4Z 8928.513917 158 1 31.87 2 63.20 82.73 108.57 40.86 0.00 1 0.00 1 0 15 4.114e-03 4.104e-03 3.629e-03 3.611e-03 3.023905e+03 2.306467e+02 2.169844e+02 -6.000000e+00 2.322977e+02 283.11 -2.00 20.00 -2.00 505.28 0.00e+00 5.267907e-04 9.973930e-05 3.457144e-05 -6.000000e+00 1.159086e-04 283.11 -2.00 20.00 -2.00 500.26 0.00e+00 2.710579e-01 7.299044e-02 2.208112e-02 -6.000000e+00 8.235875e-02 232.60 -2.00 3.56 -2.00 501.89 0.00e+00 2.205 0.000 489.00 513.00 1 9.0988e+00 5.6001e-03 3.6549e-03 -6.0000e+00 6.3196e-03 1.1214e-02 1.4323e-03 5.4853e-04 -6.0000e+00 1.6285e-03 1.5688e-04 5.9609e-04 3.7255e-04 2.4695e-05 -6.0000e+00 4.3886e-04 -6.3587e-04 1.1680e-04 11 8 0 10 0 0 20.17 27.32 2.26 -0.00064 0.00350 8 8 1 4 0 3982.520 35.75 20.00 27.32 16.52 3.8 893.82 -140 -494 -536 22 253 733 300 -37 284 413 623 -146 395 -330 -263 -146 -381 577 80 -116 -274 220 79 473 -485 272 444 -11 25 177 -412 -354 446 -100 297 80 -258 489 -237 616 -101 -313 -20 -355 -148 482 -123 421 -809 -79 -629 -1021 -669 -1084 -175 -272 -105 53 -182 -175 234 859 199 977 -455 82 445 651 -433 120 -108 -201 287 -366 -281 -13 173 -54 317 5 -954 -687 -140 623 178 135 287 417 -694 -107 26 -156 -122 -70 -226 829 -32 -8 -104 -195 -826 -19 258 -454 -114 -199 -247 -388 72 -355 220 -362 -303 468 737 242 852 45 338 -130 175 40 -91 -636 -744 -470 590 371 149 486 261 25 -94 219 -98 -192 281 -378 588 313 58 914 254 148 -919 -121 93 -449 90 -319 187 -139 -496 -526 23 261 771 322 -40 307 442 656 -153 405 -336 -266 -148 -392 601 85 -126 -300 240 86 517 -536 299 483 -12 27 182 -417 -358 455 -106 321 87 -282 525 -254 647 -107 -333 -21 -385 -154 501 -128 452 -863 -82 -636 -1011 -651 -1063 -173 -278 -110 54 -184 -177 235 861 201 980 -460 82 434 655 -435 118 -106 -197 283 -348 -270 -12 163 -53 304 5 -924 -667 -130 579 168 129 274 398 -670 -103 25 -153 -121 -70 -224 800 -31 -7 -95 -174 -735 -17 235 -431 -111 -196 -242 -377 69 -341 212 -356 -301 467 739 245 862 46 343 -131 174 39 -88 -619 -727 -459 571 360 144 468 251 24 -88 202 -90 -178 263 -363 569 307 58 907 243 143 -896 -117 88 -439 86 -302 176
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SQ 20240611T123146.1Z 8928.522062 167 1 30.27 2 61.09 84.63 107.23 43.31 0.00 1 0.00 1 0 15 3.789e-03 3.751e-03 3.120e-03 3.107e-03 3.055885e+03 1.970643e+02 2.119333e+02 -6.000000e+00 2.139412e+02 283.11 -2.00 20.00 -2.00 505.27 0.00e+00 5.756713e-04 8.585401e-05 3.566486e-05 -6.000000e+00 1.067576e-04 283.11 -2.00 20.00 -2.00 500.28 0.00e+00 1.550900e-01 6.268638e-02 2.371844e-02 -6.000000e+00 7.588287e-02 232.60 -2.00 3.56 -2.00 501.90 0.00e+00 2.059 0.000 489.00 513.00 1 8.9045e+00 4.8142e-03 3.5616e-03 -6.0000e+00 5.8223e-03 1.2320e-02 1.2304e-03 5.6701e-04 -6.0000e+00 1.5011e-03 1.9593e-04 9.9438e-04 3.2084e-04 2.3605e-05 -6.0000e+00 4.0421e-04 -2.9496e-04 8.1682e-05 10 0 0 10 0 0 97.79 27.28 2.22 -0.00029 0.00660 8 8 1 4 0 3783.280 35.75 19.99 27.28 16.70 3.8 895.37 -164 143 -532 333 109 174 551 113 399 -367 458 -345 -79 -119 -91 -593 -412 264 330 -262 -165 373 -271 -314 187 403 512 -80 14 -480 -78 235 4 457 -112 -242 130 329 51 -69 168 -181 192 329 270 482 259 343 145 -195 276 -1121 -109 -1067 -333 -711 -82 -512 -37 427 79 14 -175 373 239 -16 171 16 -167 386 -731 376 -18 199 -482 187 -243 -217 -341 -1012 -57 239 -386 -314 -37 785 -120 -91 254 467 506 261 -286 -292 -51 474 120 -126 -682 -199 186 -989 -231 -167 105 -411 -293 193 -575 -103 -400 -362 -503 255 182 652 539 1057 151 -14 161 330 -116 352 298 -46 137 486 240 828 -184 -33 -279 -37 63 -220 -308 43 621 51 112 12 340 229 -451 -742 296 -360 -76 6 -480 -161 142 -544 333 112 183 586 122 429 -394 480 -359 -81 -120 -91 -599 -422 274 350 -284 -179 404 -295 -343 204 439 554 -86 15 -492 -78 234 4 476 -121 -264 141 352 54 -73 176 -191 203 352 292 521 280 366 152 -200 275 -1104 -105 -1039 -329 -724 -85 -515 -37 426 79 14 -177 375 240 -16 175 16 -166 377 -717 364 -18 197 -485 186 -241 -211 -328 -975 -55 229 -375 -307 -35 740 -115 -87 242 446 485 253 -283 -290 -51 458 114 -117 -622 -186 171 -887 -210 -158 102 -404 -288 186 -552 -98 -387 -354 -500 255 183 656 545 1067 153 -14 159 321 -112 338 287 -45 133 469 231 792 -176 -31 -261 -34 58 -203 -289 41 599 50 111 12 340 220 -436 -718 292 -351 -72 6 -453
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