File name: Pandora243s1_Toronto-CNTower_20240612_L2Fit_fwvt1c2d20230307p1-8.txt
File generation date: 20241003T105006.5Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240612_L1_smca1c2d20230307p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240612
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off session 1
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0337 492.1543 492.2749 492.3955 492.5160 492.6366 492.7571 492.8776 492.9981 493.1185 493.2390 493.3594 493.4798 493.6002 493.7206 493.8410 493.9614 494.0817 494.2020 494.3223 494.4426 494.5629 494.6831 494.8033 494.9236 495.0438 495.1639 495.2841 495.4043 495.5244 495.6445 495.7646 495.8847 496.0048 496.1248 496.2448 496.3648 496.4848 496.6048 496.7248 496.8447 496.9647 497.0846 497.2045 497.3244 497.4442 497.5641 497.6839 497.8037 497.9235 498.0433 498.1630 498.2828 498.4025 498.5222 498.6419 498.7616 498.8812 499.0009 499.1205 499.2401 499.3597 499.4793 499.5988 499.7184 499.8379 499.9574 500.0769 500.1963 500.3158 500.4352 500.5546 500.6740 500.7934 500.9128 501.0321 501.1515 501.2708 501.3901 501.5094 501.6286 501.7479 501.8671 501.9863 502.1055 502.2247 502.3439 502.4630 502.5821 502.7013 502.8203 502.9394 503.0585 503.1775 503.2965 503.4156 503.5345 503.6535 503.7725 503.8914 504.0103 504.1292 504.2481 504.3670 504.4859 504.6047 504.7235 504.8423 504.9611 505.0799 505.1986 505.3173 505.4361 505.5548 505.6734 505.7921 505.9107 506.0294 506.1480 506.2666 506.3852 506.5037 506.6223 506.7408 506.8593 506.9778 507.0963 507.2147 507.3331 507.4516 507.5700 507.6884 507.8067 507.9251 508.0434 508.1617 508.2800 508.3983 508.5166 508.6348 508.7531 508.8713 508.9895 509.1076 509.2258 509.3440 509.4621 509.5802 509.6983 509.8164 509.9344
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240612T094526.8Z 8929.406560 44 1 28.97 2 89.34 57.78 122.95 351.85 0.00 1 0.00 1 0 36 1.565e-02 1.542e-02 1.919e-03 1.902e-03 1.349649e+04 1.345066e+02 8.268700e+02 -6.000000e+00 8.839825e+02 283.20 -2.00 20.00 -2.00 505.51 0.00e+00 3.938777e-03 5.350040e-05 2.238930e-04 -6.000000e+00 4.411152e-04 283.20 -2.00 20.00 -2.00 501.31 0.00e+00 8.601815e-01 3.672577e-02 1.173740e-01 -6.000000e+00 3.136604e-01 232.65 -2.00 3.56 -2.00 502.77 0.00e+00 19.359 0.141 489.00 513.00 1 5.6582e+00 2.8132e-03 3.4774e-02 -6.0000e+00 2.4064e-02 -4.6842e-02 6.9340e-04 3.1482e-03 -6.0000e+00 6.2099e-03 4.1979e-04 4.3242e-03 1.8811e-04 1.1615e-04 -6.0000e+00 1.6694e-03 -1.2110e-03 2.8090e-05 12 8 8 10 0 0 58.72 27.47 18.84 -0.00121 0.02878 12 12 1 4 0 2413.940 35.75 19.99 27.47 19.97 3.9 922.05 -3373 -3531 -1390 919 873 2112 2498 2760 2335 1836 664 109 -1031 -1286 -1835 -1481 -866 103 845 814 763 1503 1149 1387 1946 1715 1181 524 -873 -1547 -2373 -2299 -1716 -148 594 517 593 404 -239 -287 -529 625 702 1464 1916 2149 1784 1261 626 -765 -1677 -2665 -2734 -2911 -1459 -318 886 1144 1412 1438 1593 1580 1796 1712 1301 785 516 -198 -1033 -1468 -1794 -1779 -1419 -1016 -820 -1224 -1218 -2173 -2120 -2730 -2483 -2086 -2009 -1096 -1385 -1165 -828 -1033 -1029 -956 -450 155 646 1216 1467 796 653 -821 -1782 -2841 -3502 -2411 -1609 -360 -110 -315 -274 -915 -860 -1149 -186 122 1259 1929 2680 3036 3521 3209 2497 1777 1266 942 577 1236 1406 1165 1395 1214 769 1265 365 -152 -553 -1014 -1613 -1536 -820 -325 131 812 888 430 876 554 1113 689 146 -983 -2064 -2127 -2486 -2863 -3056 -1217 816 764 1872 2248 2502 2126 1665 602 98 -927 -1147 -1642 -1330 -786 95 790 773 730 1433 1105 1340 1884 1602 1108 490 -810 -1471 -2243 -2181 -1585 -139 570 504 576 390 -231 -276 -513 606 690 1451 1918 2160 1799 1267 624 -758 -1636 -2573 -2621 -2821 -1430 -318 898 1127 1396 1426 1583 1580 1803 1724 1310 787 512 -195 -1017 -1437 -1751 -1740 -1397 -1009 -820 -1227 -1207 -2142 -2064 -2660 -2416 -2035 -1975 -1080 -1385 -1173 -834 -1041 -1034 -960 -453 157 658 1234 1464 780 621 -770 -1649 -2616 -3237 -2240 -1535 -355 -112 -318 -278 -930 -870 -1172 -191 127 1310 2012 2795 3183 3719 3443 2712 1932 1365 1003 609 1298 1484 1242 1493 1307 833 1364 396 -164 -592 -1084 -1675 -1614 -873 -351 143 899 995 489 1000 638 1278 791 167 -1118 -2340 -2400 -2836
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SQ 20240612T095409.9Z 8929.412615 57 1 30.07 2 87.99 59.27 123.17 354.27 0.00 1 0.00 1 0 22 5.585e-03 5.543e-03 2.773e-04 2.766e-04 1.314323e+04 1.947606e+01 8.560947e+02 -6.000000e+00 3.154537e+02 283.20 -2.00 20.00 -2.00 505.41 0.00e+00 2.163520e-03 7.725768e-06 1.347643e-04 -6.000000e+00 1.573753e-04 283.20 -2.00 20.00 -2.00 500.94 0.00e+00 1.317371e+00 5.412288e-03 9.552823e-02 -6.000000e+00 1.117904e-01 232.65 -2.00 3.56 -2.00 502.46 0.00e+00 16.006 0.079 489.00 513.00 1 2.7617e+00 4.1446e-04 2.6087e-02 -6.0000e+00 8.5784e-03 -4.1878e-02 1.0366e-04 2.6306e-03 -6.0000e+00 2.2103e-03 1.1902e-02 9.9457e-04 2.6971e-05 1.0548e-04 -6.0000e+00 5.9575e-04 2.0839e-04 1.1859e-04 12 8 8 10 0 0 62.88 27.46 6.11 0.00021 0.00711 153 153 1 4 0 196.500 35.75 19.99 27.46 20.36 3.8 923.01 -893 -668 -227 272 504 916 1108 1061 914 722 462 136 -168 -347 -409 -397 -174 94 266 255 287 512 421 479 631 506 366 125 -227 -602 -742 -690 -562 -47 63 -32 62 15 -177 -287 -198 -30 93 350 499 547 466 300 1 -408 -677 -940 -1015 -944 -580 -281 15 223 351 461 557 621 566 516 502 360 87 -131 -323 -576 -655 -523 -519 -389 -266 -419 -637 -732 -845 -882 -941 -776 -809 -703 -480 -491 -513 -482 -404 -239 -21 117 372 503 458 459 179 -220 -591 -1028 -1240 -1073 -811 -467 -326 -345 -293 -346 -302 -220 -91 53 377 701 987 1148 1302 1303 980 652 550 451 374 526 545 402 464 568 390 431 379 -20 -215 -244 -431 -410 -84 -10 48 331 337 270 379 385 332 242 34 -381 -701 -850 -762 -807 -602 -210 255 477 870 1071 1038 881 704 446 130 -159 -326 -390 -374 -166 90 261 250 284 506 418 479 623 502 363 125 -223 -588 -715 -666 -543 -46 63 -32 62 16 -178 -287 -198 -30 93 355 503 555 472 302 1 -405 -667 -908 -986 -923 -569 -279 15 225 357 468 567 635 574 523 507 366 87 -130 -324 -571 -646 -516 -516 -386 -265 -419 -630 -725 -828 -858 -916 -759 -799 -690 -476 -492 -508 -477 -404 -239 -20 116 374 505 453 449 173 -210 -554 -952 -1148 -1007 -773 -457 -327 -349 -298 -351 -304 -222 -93 53 387 723 1021 1177 1347 1365 1020 677 572 461 384 538 553 412 477 585 403 445 390 -21 -218 -246 -435 -419 -86 -11 50 352 358 290 405 414 358 260 36 -407 -741 -894 -805
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