File name: Pandora243s1_Toronto-CNTower_20240613_L2Fit_fwvt1c5d20240208p1-8.txt
File generation date: 20241016T141121.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240613_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240613
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0474 492.1680 492.2887 492.4092 492.5298 492.6504 492.7709 492.8914 493.0119 493.1324 493.2529 493.3734 493.4938 493.6142 493.7346 493.8550 493.9754 494.0958 494.2161 494.3364 494.4567 494.5770 494.6973 494.8175 494.9378 495.0580 495.1782 495.2984 495.4186 495.5387 495.6589 495.7790 495.8991 496.0192 496.1392 496.2593 496.3793 496.4993 496.6193 496.7393 496.8593 496.9792 497.0992 497.2191 497.3390 497.4589 497.5787 497.6986 497.8184 497.9382 498.0580 498.1778 498.2976 498.4173 498.5371 498.6568 498.7765 498.8962 499.0158 499.1355 499.2551 499.3747 499.4943 499.6139 499.7334 499.8530 499.9725 500.0920 500.2115 500.3310 500.4504 500.5699 500.6893 500.8087 500.9281 501.0475 501.1668 501.2862 501.4055 501.5248 501.6441 501.7634 501.8826 502.0019 502.1211 502.2403 502.3595 502.4786 502.5978 502.7169 502.8360 502.9551 503.0742 503.1933 503.3123 503.4314 503.5504 503.6694 503.7884 503.9073 504.0263 504.1452 504.2641 504.3830 504.5019 504.6207 504.7396 504.8584 504.9772 505.0960 505.2148 505.3335 505.4523 505.5710 505.6897 505.8084 505.9271 506.0457 506.1644 506.2830 506.4016 506.5202 506.6387 506.7573 506.8758 506.9943 507.1128 507.2313 507.3498 507.4682 507.5867 507.7051 507.8235 507.9419 508.0602 508.1786 508.2969 508.4152 508.5335 508.6518 508.7700 508.8883 509.0065 509.1247 509.2429 509.3611 509.4792 509.5973 509.7155 509.8336 509.9517
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240613T094907.3Z 8930.409112 55 1 31.42 2 88.76 58.34 126.55 340.15 0.00 1 0.00 1 0 22 9.199e-03 9.014e-03 3.630e-03 3.602e-03 2.036458e+04 2.722863e+02 1.320585e+03 -6.000000e+00 5.179841e+02 283.30 -2.00 20.00 -2.00 505.52 0.00e+00 3.848776e-03 1.011113e-04 2.300979e-04 -6.000000e+00 2.589483e-04 283.30 -2.00 20.00 -2.00 501.16 0.00e+00 1.382488e+00 6.992374e-02 1.406960e-01 -6.000000e+00 1.837894e-01 232.72 -2.00 3.56 -2.00 502.64 0.00e+00 18.038 0.114 489.00 513.00 1 6.7754e+00 5.3492e-03 3.2130e-02 -6.0000e+00 1.4102e-02 -4.8703e-02 1.3150e-03 3.7961e-03 -6.0000e+00 3.6368e-03 1.5626e-04 1.2351e-03 3.3205e-04 1.5083e-04 -6.0000e+00 9.7047e-04 -1.9761e-02 1.2843e-04 12 8 8 10 0 0 71.48 27.65 9.33 -0.01976 -0.01119 8 8 1 4 0 3926.650 36.00 20.00 27.65 25.38 3.8 959.31 -1089 -749 177 496 880 1722 1980 2695 1113 884 732 524 10 -1083 -582 -812 -528 -51 423 -595 432 1637 552 677 1045 1116 463 -154 -293 -974 -1019 -1611 -1722 173 -95 776 -383 -423 -227 -91 -270 229 -474 279 957 824 207 -587 337 -506 -836 -1629 -1389 -1018 -118 -653 360 189 705 429 110 923 735 1073 407 839 341 -238 -741 -659 -829 -455 -1032 -640 -679 -839 -1080 -533 -2009 -1769 -1571 -923 -1233 -578 -639 -1090 -92 -669 -250 -505 -303 322 718 1503 524 1203 -18 -148 -1246 -2259 -1443 -1891 -1444 -1217 -251 -84 -235 -215 -296 -172 -760 -107 589 687 1594 1855 1631 1928 896 125 356 324 620 540 844 249 987 1537 620 515 573 -486 215 -120 -1095 -590 -562 -104 682 1232 333 156 565 513 86 282 750 -152 -743 -867 -1447 -903 -629 152 441 803 1598 1869 2552 1072 846 692 490 9 -1007 -537 -754 -497 -49 393 -568 410 1543 528 651 1010 1083 452 -149 -280 -912 -939 -1497 -1635 167 -94 776 -386 -425 -225 -90 -269 229 -484 287 991 861 218 -616 345 -513 -829 -1592 -1341 -986 -116 -667 373 190 709 433 111 936 752 1096 417 846 341 -236 -730 -642 -843 -461 -1012 -633 -678 -837 -1066 -515 -1942 -1692 -1497 -878 -1186 -559 -625 -1083 -91 -661 -244 -493 -297 316 709 1468 506 1114 -16 -136 -1126 -2032 -1284 -1720 -1295 -1148 -246 -85 -240 -219 -301 -175 -791 -112 619 725 1674 1957 1750 2002 950 134 372 333 655 568 892 255 1010 1572 642 533 590 -501 218 -122 -1123 -610 -593 -111 740 1353 375 178 648 592 99 325 852 -172 -835 -971 -1640
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SQ 20240613T100944.5Z 8930.423432 76 1 28.45 2 85.53 61.80 127.66 346.15 0.00 1 0.00 1 0 29 3.609e-03 3.579e-03 1.089e-04 1.088e-04 1.337614e+04 7.719640e+00 8.903487e+02 -6.000000e+00 2.031905e+02 283.31 -2.00 20.00 -2.00 505.36 0.00e+00 2.076842e-03 3.029413e-06 1.293552e-04 -6.000000e+00 1.015793e-04 283.31 -2.00 20.00 -2.00 500.71 0.00e+00 1.025869e+00 2.150246e-03 8.914644e-02 -6.000000e+00 7.210127e-02 232.72 -2.00 3.56 -2.00 502.27 0.00e+00 10.631 0.023 489.00 513.00 1 1.6590e+00 1.6479e-04 1.7060e-02 -6.0000e+00 5.5323e-03 -2.9685e-02 4.1393e-05 2.3198e-03 -6.0000e+00 1.4269e-03 7.6427e-02 9.5623e-04 1.0427e-05 1.0544e-04 -6.0000e+00 3.8068e-04 -1.3074e-03 9.5485e-06 12 1 1 12 1 1 18.90 27.60 3.12 -0.00131 0.00533 674 712 1 4 0 42.140 36.00 20.00 27.60 25.89 3.6 959.65 -446 -300 -63 206 336 622 756 652 618 503 302 110 -121 -159 -208 -218 -86 71 208 122 140 275 266 299 380 337 188 103 -98 -375 -430 -408 -361 -34 20 -83 -54 -25 -140 -250 -164 -103 -2 168 277 280 298 158 -29 -241 -518 -621 -723 -673 -413 -197 -48 84 186 277 355 399 368 311 290 195 20 -142 -248 -368 -422 -362 -327 -231 -90 -240 -414 -472 -485 -535 -574 -473 -487 -420 -281 -295 -365 -285 -206 -123 23 146 337 415 380 363 178 -134 -367 -675 -881 -790 -618 -385 -211 -314 -230 -187 -213 -147 -47 -2 148 380 584 681 831 833 571 358 309 229 161 321 416 252 304 392 221 284 303 -15 -124 -81 -272 -214 99 58 70 271 278 227 308 321 260 164 27 -248 -493 -548 -502 -417 -281 -60 200 332 619 757 653 619 500 300 108 -119 -155 -201 -212 -85 71 210 124 143 280 269 303 388 345 192 104 -98 -372 -423 -403 -359 -34 21 -85 -55 -25 -141 -253 -166 -104 -2 172 286 288 305 162 -30 -242 -514 -609 -708 -656 -410 -197 -49 85 190 282 361 408 379 321 297 198 20 -142 -248 -364 -419 -359 -323 -231 -89 -239 -412 -463 -474 -520 -557 -461 -479 -412 -279 -292 -363 -283 -204 -121 23 145 336 412 376 353 170 -126 -341 -625 -814 -732 -585 -372 -207 -313 -230 -186 -211 -145 -47 -2 150 382 589 690 851 854 590 368 313 230 162 321 417 252 305 395 222 286 303 -15 -123 -80 -269 -214 99 58 72 278 289 236 322 334 271 171 28 -256 -504 -556 -511
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