File name: Pandora243s1_Toronto-CNTower_20240614_L2Fit_fwvt1c2d20230307p1-8.txt
File generation date: 20241003T105209.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240614_L1_smca1c2d20230307p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240614
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off session 1
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0337 492.1543 492.2749 492.3955 492.5160 492.6366 492.7571 492.8776 492.9981 493.1185 493.2390 493.3594 493.4798 493.6002 493.7206 493.8410 493.9614 494.0817 494.2020 494.3223 494.4426 494.5629 494.6831 494.8033 494.9236 495.0438 495.1639 495.2841 495.4043 495.5244 495.6445 495.7646 495.8847 496.0048 496.1248 496.2448 496.3648 496.4848 496.6048 496.7248 496.8447 496.9647 497.0846 497.2045 497.3244 497.4442 497.5641 497.6839 497.8037 497.9235 498.0433 498.1630 498.2828 498.4025 498.5222 498.6419 498.7616 498.8812 499.0009 499.1205 499.2401 499.3597 499.4793 499.5988 499.7184 499.8379 499.9574 500.0769 500.1963 500.3158 500.4352 500.5546 500.6740 500.7934 500.9128 501.0321 501.1515 501.2708 501.3901 501.5094 501.6286 501.7479 501.8671 501.9863 502.1055 502.2247 502.3439 502.4630 502.5821 502.7013 502.8203 502.9394 503.0585 503.1775 503.2965 503.4156 503.5345 503.6535 503.7725 503.8914 504.0103 504.1292 504.2481 504.3670 504.4859 504.6047 504.7235 504.8423 504.9611 505.0799 505.1986 505.3173 505.4361 505.5548 505.6734 505.7921 505.9107 506.0294 506.1480 506.2666 506.3852 506.5037 506.6223 506.7408 506.8593 506.9778 507.0963 507.2147 507.3331 507.4516 507.5700 507.6884 507.8067 507.9251 508.0434 508.1617 508.2800 508.3983 508.5166 508.6348 508.7531 508.8713 508.9895 509.1076 509.2258 509.3440 509.4621 509.5802 509.6983 509.8164 509.9344
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240614T094244.5Z 8931.404681 49 1 29.96 2 89.74 57.18 128.01 324.85 0.00 1 0.00 1 0 22 8.965e-03 8.858e-03 3.418e-04 3.402e-04 2.086099e+04 2.534626e+01 1.340631e+03 -6.000000e+00 5.067531e+02 283.41 -2.00 20.00 -2.00 505.46 0.00e+00 3.013673e-03 9.552874e-06 1.919905e-04 -6.000000e+00 2.527400e-04 283.41 -2.00 20.00 -2.00 501.11 0.00e+00 1.195274e+00 6.623941e-03 1.408730e-01 -6.000000e+00 1.794634e-01 232.78 -2.00 3.56 -2.00 502.60 0.00e+00 20.047 0.156 489.00 513.00 1 2.5701e+00 5.0698e-04 3.7254e-02 -6.0000e+00 1.3772e-02 -5.6676e-02 1.2550e-04 3.9303e-03 -6.0000e+00 3.5489e-03 8.1726e-03 1.8632e-03 3.1101e-05 1.5932e-04 -6.0000e+00 9.5628e-04 2.7368e-03 9.4153e-05 12 8 8 10 0 0 84.07 27.77 9.44 0.00274 0.01566 146 146 1 4 0 205.190 36.00 20.00 27.77 24.96 3.8 955.34 -1201 -867 -25 718 1211 1740 1910 1856 1671 1314 842 312 -79 -303 -455 -465 -202 194 484 462 485 640 643 740 838 734 527 210 -452 -1058 -1346 -1274 -1004 -171 86 59 -90 -107 -462 -555 -376 -177 104 453 759 705 702 343 7 -595 -1127 -1504 -1700 -1564 -939 -333 119 427 586 648 807 962 924 856 757 368 33 -350 -624 -927 -1092 -1001 -878 -605 -498 -697 -1070 -1168 -1315 -1447 -1367 -1202 -1035 -930 -864 -846 -826 -843 -747 -508 -124 156 568 821 784 680 279 -360 -1052 -1760 -2009 -1765 -1366 -859 -433 -354 -448 -421 -482 -363 -142 169 520 1075 1493 1781 1953 1924 1473 962 638 514 516 817 982 895 926 961 705 654 476 40 -235 -352 -688 -577 -146 141 274 590 463 428 573 589 661 487 167 -456 -1040 -1217 -1190 -1057 -757 -23 647 1120 1607 1796 1729 1562 1223 795 292 -74 -279 -420 -432 -190 183 465 442 468 620 625 724 809 713 512 203 -439 -1009 -1269 -1205 -968 -165 85 59 -89 -105 -452 -552 -368 -175 103 457 759 710 706 344 7 -592 -1101 -1472 -1653 -1532 -918 -334 120 435 599 651 812 973 941 874 770 372 33 -354 -626 -924 -1084 -994 -880 -601 -498 -698 -1063 -1164 -1296 -1417 -1337 -1180 -1024 -930 -858 -849 -832 -847 -745 -505 -124 156 571 820 766 654 264 -338 -973 -1617 -1850 -1654 -1302 -843 -428 -360 -454 -426 -487 -368 -146 175 541 1118 1551 1828 2030 2035 1553 1017 666 537 531 835 1010 928 968 1009 743 690 502 42 -244 -365 -719 -601 -155 149 296 636 508 468 632 653 733 539 184 -498 -1128 -1341 -1299
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SQ 20240614T094822.6Z 8931.408595 57 1 30.29 2 88.88 58.14 128.58 326.42 0.00 1 0.00 1 0 22 5.529e-03 5.441e-03 1.926e-03 1.918e-03 1.685443e+04 1.427594e+02 1.102102e+03 -6.000000e+00 3.125517e+02 283.41 -2.00 20.00 -2.00 505.45 0.00e+00 2.127894e-03 5.355869e-05 1.384864e-04 -6.000000e+00 1.558818e-04 283.41 -2.00 20.00 -2.00 500.95 0.00e+00 1.557426e+00 3.767774e-02 1.125296e-01 -6.000000e+00 1.106814e-01 232.78 -2.00 3.56 -2.00 502.47 0.00e+00 18.313 0.119 489.00 513.00 1 5.8518e+00 2.8864e-03 3.1724e-02 -6.0000e+00 8.4938e-03 -2.0662e-02 7.1515e-04 3.2176e-03 -6.0000e+00 2.1885e-03 3.8510e-04 1.0334e-03 1.8192e-04 1.2066e-04 -6.0000e+00 5.8977e-04 -6.3821e-03 1.5398e-04 12 8 8 10 0 0 99.83 27.81 4.53 -0.00638 0.00079 15 15 1 4 0 2019.140 36.00 20.00 27.81 25.01 3.7 955.62 -495 -657 -402 735 569 770 1109 841 723 730 1124 -32 -338 -579 192 -589 -322 564 33 11 266 430 379 672 544 477 187 186 -412 -785 -769 -923 -832 254 -145 -316 -169 22 35 -202 -112 392 -124 119 781 599 205 324 291 -395 -646 -916 -725 -1166 -573 -332 -380 213 625 120 165 490 605 465 339 202 -143 234 -613 -60 -690 -122 -466 -787 -108 -534 -1095 -678 -654 -1157 -775 -280 -782 -50 -107 -512 -384 -110 -219 -253 -131 414 299 343 515 502 341 -216 -713 -1236 -969 -1195 -641 -744 -456 -7 -354 -136 -119 -471 -255 -18 51 402 843 993 1247 1085 631 499 288 793 234 305 520 52 414 656 8 190 520 29 -438 -49 -4 -461 33 321 190 469 530 20 486 441 429 155 23 -255 -702 -802 -744 -427 -575 -362 679 542 719 1054 809 698 699 1058 -30 -315 -535 176 -546 -302 538 33 11 266 432 383 680 555 488 191 189 -412 -767 -739 -891 -819 255 -145 -319 -170 22 35 -199 -110 389 -125 121 801 619 213 332 293 -392 -628 -873 -710 -1108 -554 -330 -387 220 644 124 171 510 632 487 354 209 -147 235 -614 -60 -679 -119 -462 -792 -109 -540 -1100 -667 -635 -1120 -746 -269 -763 -49 -107 -516 -388 -111 -219 -253 -131 417 292 334 512 483 317 -195 -633 -1086 -847 -1066 -590 -720 -442 -7 -356 -136 -118 -471 -258 -18 53 414 870 1031 1306 1112 655 516 294 822 241 312 534 54 431 684 8 192 540 30 -450 -50 -4 -461 33 332 200 503 576 22 539 475 462 167 24 -279 -760 -865 -807
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