File name: Pandora243s1_Toronto-CNTower_20240617_L2Fit_fout2c5d20240208p1-8.txt
File generation date: 20241016T141304.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v5d20240208.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240617_L1_smca1c5d20240208p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240617
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1273 305.2678 305.4083 305.5488 305.6893 305.8298 305.9703 306.1108 306.2512 306.3916 306.5321 306.6725 306.8129 306.9533 307.0937 307.2341 307.3744 307.5148 307.6551 307.7954 307.9358 308.0761 308.2164 308.3566 308.4969 308.6372 308.7774 308.9177 309.0579 309.1981 309.3383 309.4785 309.6187 309.7589 309.8990 310.0392 310.1793 310.3195 310.4596 310.5997 310.7398 310.8799 311.0199 311.1600 311.3001 311.4401 311.5801 311.7201 311.8601 312.0001 312.1401 312.2801 312.4201 312.5600 312.6999 312.8399 312.9798 313.1197 313.2596 313.3995 313.5393 313.6792 313.8191 313.9589 314.0987 314.2385 314.3783 314.5181 314.6579 314.7977 314.9374 315.0772 315.2169 315.3567 315.4964 315.6361 315.7758 315.9154 316.0551 316.1948 316.3344 316.4741 316.6137 316.7533 316.8929 317.0325 317.1721 317.3116 317.4512 317.5907 317.7303 317.8698 318.0093 318.1488 318.2883 318.4278 318.5672 318.7067 318.8461 318.9856 319.1250 319.2644 319.4038 319.5432 319.6825 319.8219 319.9613 320.1006 320.2399 320.3792 320.5186 320.6578 320.7971 320.9364 321.0757 321.2149 321.3541 321.4934 321.6326 321.7718 321.9110 322.0502 322.1893 322.3285 322.4676 322.6068 322.7459 322.8850 323.0241 323.1632 323.3023 323.4413 323.5804 323.7194 323.8585 323.9975 324.1365 324.2755 324.4145 324.5534 324.6924 324.8313 324.9703
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240617T101021.1Z 8934.423855 127 1 29.81 2 85.46 61.66 128.83 289.57 0.00 1 0.00 1 0 76 7.645e-01 3.774e-01 7.407e-01 3.830e-01 8.524001e-01 2.527371e-01 9.010311e-03 -6.000000e+00 5.225489e-01 232.80 -2.00 3.56 -2.00 318.72 0.00e+00 -6.776708e-02 3.449700e-02 1.019474e-02 -6.000000e+00 3.037788e-02 283.69 -2.00 20.00 -2.00 317.35 0.00e+00 10.518 0.022 302.00 328.00 3 2.0209e+00 6.9463e-01 1.5434e-01 -6.0000e+00 1.3329e+00 1.9229e+00 8.0199e-01 1.8646e-01 -6.0000e+00 1.4728e+00 -1.3835e+00 4.6385e-01 1.8907e-02 -6.0000e+00 8.7180e-01 5.1035e-01 2.2280e-01 6.3378e-02 -6.0000e+00 3.7081e-01 5.5820e-07 -5.4170e-03 1.0794e-02 1.3397e-04 -6.0000e+00 2.5895e-02 -1.8845e-02 0.0000e+00 12 8 8 10 0 0 -91.17 27.73 27.99 -0.01885 -0.05955 10 10 1 5 0 2980.110 36.00 20.00 27.73 26.88 3.7 967.26 900000 900000 900000 900000 68979 900000 112734 900000 900000 -37261 108113 900000 900000 900000 -85030 900000 900000 900000 900000 900000 900000 900000 -55286 40819 900000 900000 -6637 -68205 900000 900000 900000 -55503 900000 900000 900000 -129423 900000 900000 -3530 900000 -13314 -23214 900000 166461 900000 900000 900000 -35996 900000 900000 128862 900000 900000 119617 900000 -17320 900000 101878 -30571 900000 -97967 900000 900000 13800 900000 10558 900000 164684 900000 -10619 131951 900000 900000 900000 145121 45599 900000 900000 23191 174430 49915 52269 26571 12584 47988 900000 34430 6058 164270 -61622 218776 -40213 210188 122279 98710 -8343 -54794 2167 116152 -22734 15607 124418 88942 43407 5182 48520 23392 108871 14773 -23180 60427 15447 44950 5518 31318 15721 -14296 -19327 29800 22563 34435 36735 -46970 16718 45886 77525 -21508 16484 55271 -13713 -28195 96870 -18487 2805 -3326 -2967 15274 4333 -291 5045 -1477 22287 13368 900000 900000 900000 900000 25403 900000 41517 900000 900000 -13722 39815 900000 900000 900000 -33924 900000 900000 900000 900000 900000 900000 900000 -20360 15032 900000 900000 -2444 -35584 900000 900000 900000 -20440 900000 900000 900000 -63550 900000 900000 -1300 900000 -6686 -13212 900000 61303 900000 900000 900000 -13256 900000 900000 47456 900000 900000 44051 900000 -8698 900000 37519 -17399 900000 -81996 900000 900000 5082 900000 3888 900000 60649 900000 -5333 48594 900000 900000 900000 53444 16793 900000 900000 8541 64237 18382 19249 11564 6741 19279 900000 17290 4056 60496 -74270 80569 -33657 77406 45032 36352 -6425 -75212 1886 42775 -27400 12017 45819 32755 20345 3817 24366 15663 40094 13601 -35000 44507 19342 43040 7722 32294 17948 -21586 -31317 30728 25759 34240 33821 -95137 17239 33797 39970 -28515 15177 38674 -21716 -57108 60646 -38807 5062 -6860 -6447 28124 8936 -622 9661 -2773 30368 18707
SS 20240617T113902.0Z 8934.485440 173 1 30.06 2 70.54 75.82 142.31 312.26 0.00 1 0.00 1 0 17 3.932e-02 5.215e-03 2.401e-02 2.659e-03 3.962017e-01 1.357371e-03 4.685103e-03 -6.000000e+00 2.266832e-02 232.80 -2.00 3.56 -2.00 319.07 0.00e+00 6.744049e-04 3.185501e-04 4.164861e-04 -6.000000e+00 9.911305e-04 283.70 -2.00 20.00 -2.00 318.32 0.00e+00 2.968 0.000 302.00 328.00 3 4.2294e+00 3.7794e-03 3.5759e-02 -6.0000e+00 5.6997e-02 2.1399e-02 4.3581e-03 2.1303e-02 -6.0000e+00 6.1735e-02 -2.7743e-02 3.1361e-03 1.0359e-02 -6.0000e+00 3.6635e-02 6.6332e-03 1.6367e-03 2.8695e-03 -6.0000e+00 1.5393e-02 2.7427e-04 -2.5548e-04 7.5877e-05 3.0467e-05 -6.0000e+00 1.0539e-03 -4.6971e-04 0.0000e+00 11 1 0 11 8 0 99.40 27.77 0.46 -0.00047 -0.00239 22 22 1 5 0 1366.070 36.00 19.99 27.77 27.03 3.6 967.49 -6622 -13577 -5472 -15394 -20883 -14696 4117 -19555 -6924 -8815 -7396 -9879 -1858 -3378 -2653 -7444 2301 -780 -4049 -2181 -3850 514 -999 -1121 -5458 -1715 -3767 50 -2339 -5271 -861 3081 452 -1367 -1113 -2533 138 -798 -1042 -1104 -475 732 471 -116 -307 512 -758 188 191 643 1896 1708 574 1559 1722 337 1071 1257 -6 1309 1428 1463 1687 1709 -166 768 269 253 379 921 -24 573 14 -505 -682 -207 -1657 -1716 -351 -917 -713 -853 -1885 -1382 -633 -141 422 305 159 504 260 -13 412 -196 51 -63 -195 257 214 -349 -1224 -383 -813 -524 -299 -662 -531 -8 -57 338 375 580 338 228 93 321 92 210 24 -242 236 -51 79 475 224 186 435 64 794 140 54 -62 -258 -312 -38 227 148 -12 -114 -72 -230 -429 -82 -208 -496 -186 -527 -693 -469 121 -827 -285 -384 -322 -492 -102 -223 -204 -664 198 -74 -417 -230 -415 53 -111 -135 -725 -228 -502 6 -278 -683 -120 459 76 -235 -179 -426 26 -179 -284 -348 -161 234 156 -39 -104 172 -256 69 71 248 716 700 255 728 831 170 545 631 -3 643 736 825 1047 1137 -111 474 161 153 254 640 -18 446 11 -370 -500 -135 -1018 -1048 -233 -706 -569 -757 -1802 -1386 -626 -148 462 342 178 534 276 -13 377 -182 52 -67 -233 341 277 -476 -1567 -444 -896 -604 -373 -871 -733 -10 -82 527 623 977 552 349 133 435 126 302 37 -394 384 -82 122 701 315 270 604 92 1151 221 92 -101 -434 -552 -71 447 279 -23 -220 -143 -438 -783 -146
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