File name: Pandora243s1_Toronto-CNTower_20240710_L2Fit_fout2c2d20230307p1-8.txt
File generation date: 20241003T110525.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20240710_L1_smca1c2d20230307p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20240710
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off session 1
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240710T182851.1Z 8957.770036 352 1 30.69 2 25.49 217.55 50.10 124.04 0.00 1 0.00 1 0 17 1.328e-02 8.421e-03 7.074e-03 3.950e-03 1.579985e-01 2.007792e-03 1.907731e-03 -6.000000e+00 7.658661e-03 232.92 -2.00 3.56 -2.00 315.94 0.00e+00 5.195802e-04 2.065174e-04 3.205288e-05 -6.000000e+00 3.370738e-04 285.85 -2.00 20.00 -2.00 315.19 0.00e+00 1.107 0.000 302.00 328.00 3 6.7820e+00 5.2554e-03 1.3655e-02 -6.0000e+00 1.9252e-02 3.3565e-03 5.8456e-03 8.3701e-03 -6.0000e+00 2.0831e-02 8.2192e-03 3.3413e-03 4.0312e-03 -6.0000e+00 1.2376e-02 -4.2615e-03 1.5104e-03 1.1334e-03 -6.0000e+00 5.2235e-03 1.7902e-04 5.2813e-04 1.1168e-04 1.3137e-05 -6.0000e+00 3.5307e-04 -1.0201e-02 7.9475e-05 11 8 0 10 0 0 99.92 27.23 0.40 -0.01020 -0.00623 9 9 1 5 0 3409.830 35.50 20.00 27.23 25.47 3.7 958.37 1603 520 -6013 -1440 161 -5987 1115 -1987 114 -3161 -176 -1786 952 -134 -334 1117 619 2844 -1490 543 1061 -752 3789 952 1257 809 543 -1984 -1395 -332 2500 1089 740 -641 -3547 -1489 -2843 83 1098 -556 220 901 -1439 -331 -415 79 -60 -797 -936 -510 1333 2253 1023 452 345 887 355 37 -158 -228 44 1900 1492 1187 32 -104 -2014 -825 -688 760 911 396 576 446 -342 -850 -1763 -1852 -1738 -965 -371 -1885 -1382 -1819 -1142 234 347 178 1071 1410 471 -384 -782 -396 -251 -80 368 1358 892 236 -982 -438 -884 -1297 -592 -907 -1823 450 768 528 706 653 505 -398 263 -1090 -594 110 -23 -40 401 424 350 716 617 579 113 360 129 -32 -287 -103 -306 135 172 -223 335 568 -157 -79 -362 -563 -416 405 139 -1677 -342 33 -1301 244 -501 31 -884 -46 -488 280 -45 -123 427 240 1105 -621 228 444 -316 1560 422 576 380 248 -855 -553 -128 981 457 331 -285 -1492 -618 -1332 44 691 -367 153 642 -1070 -243 -303 57 -42 -536 -667 -362 977 1728 754 348 270 701 285 29 -124 -180 36 1639 1386 1150 30 -88 -1597 -629 -566 696 900 407 586 437 -313 -697 -1444 -1439 -1417 -794 -337 -1891 -1451 -2007 -1347 292 454 240 1429 1787 553 -411 -761 -370 -247 -86 434 1744 1199 309 -1217 -499 -974 -1513 -748 -1208 -2557 642 1138 757 1048 963 707 -562 337 -1327 -722 139 -31 -58 602 631 508 987 804 717 133 423 161 -42 -394 -143 -432 195 265 -332 509 883 -247 -121 -591 -892 -645
SS 20240710T184503.2Z 8957.781287 362 1 7.32 2 27.42 224.78 47.82 128.31 0.00 1 0.00 1 0 17 7.733e-03 6.039e-03 2.719e-03 1.974e-03 1.564046e-01 1.020264e-03 1.906864e-03 -6.000000e+00 4.458168e-03 232.92 -2.00 3.56 -2.00 314.70 0.00e+00 3.620668e-04 8.239869e-05 1.554441e-05 -6.000000e+00 1.962345e-04 285.85 -2.00 20.00 -2.00 314.07 0.00e+00 1.126 0.000 302.00 328.00 3 4.6321e+00 2.6396e-03 1.3742e-02 -6.0000e+00 1.1207e-02 -2.5840e-02 2.9207e-03 8.2814e-03 -6.0000e+00 1.2126e-02 7.3854e-03 1.6680e-03 4.0022e-03 -6.0000e+00 7.2043e-03 -5.5113e-03 7.2429e-04 1.1142e-03 -6.0000e+00 3.0404e-03 1.5349e-03 2.1536e-04 5.4611e-05 1.4047e-05 -6.0000e+00 2.0556e-04 -9.7884e-03 6.5569e-05 12 1 1 12 9 1 98.91 27.20 0.50 -0.00979 -0.00817 8 37 1 5 0 813.360 35.50 20.00 27.20 26.50 3.6 964.37 -537 234 -851 -1327 -2410 -590 630 1603 1234 -316 -1510 -787 -804 825 116 822 -73 -85 485 737 543 1307 648 1521 787 -121 -410 -95 36 -70 636 1634 391 -805 -2087 -2633 -1492 -391 -546 -723 -193 -1087 -888 -1139 -433 -374 -319 -687 -820 583 921 854 570 1119 509 1191 736 675 488 494 742 876 1700 1107 266 -362 -632 81 354 264 419 204 829 239 298 -599 -637 -1013 -366 -667 -843 -1409 -1969 -1524 -1202 -225 -171 -23 347 336 81 4 -15 5 305 255 285 578 573 -216 -1048 -170 -277 -114 -358 -435 -531 -342 93 295 256 310 576 22 44 43 363 -237 150 44 -34 -331 43 499 440 173 582 358 801 458 -268 29 236 -92 -13 -145 35 -63 -170 114 -197 -487 -458 -205 93 -334 -467 -825 -195 222 580 488 -128 -595 -317 -358 375 59 406 -37 -44 255 399 295 695 356 868 470 -70 -246 -52 20 -37 330 884 228 -466 -1124 -1434 -895 -255 -401 -571 -161 -895 -744 -956 -359 -307 -266 -552 -636 446 737 724 479 974 453 1068 671 609 434 441 688 827 1626 1108 258 -334 -566 70 329 264 431 218 874 244 296 -565 -540 -861 -324 -629 -839 -1465 -2068 -1668 -1351 -269 -206 -28 427 412 96 4 -15 5 313 275 338 717 710 -261 -1250 -195 -305 -133 -434 -533 -680 -454 124 410 356 429 782 29 55 53 442 -292 190 58 -46 -443 58 644 560 210 696 430 969 587 -345 38 310 -126 -18 -204 51 -94 -254 166 -280 -701 -645
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