File name: Pandora243s1_Toronto-CNTower_20240723_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20241003T111712.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240723_L1_smca1c2d20230307p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240723T123259.1Z 8970.522906 285 1 29.84 2 64.13 86.55 92.60 251.13 0.00 1 0.00 1 0 25 3.367e-02 6.641e-03 3.190e-02 4.611e-03 3.463079e-01 2.343235e-03 4.105399e-03 -6.000000e+00 1.938448e-02 232.62 -2.00 3.56 -2.00 318.68 0.00e+00 -5.947860e-05 4.937035e-04 1.894301e-04 -6.000000e+00 8.564687e-04 286.39 -2.00 20.00 -2.00 317.86 0.00e+00 2.278 0.000 302.00 328.00 3 5.6123e+00 6.4767e-03 2.8913e-02 -6.0000e+00 4.8681e-02 3.4407e-02 7.4079e-03 1.8481e-02 -6.0000e+00 5.2690e-02 -3.9345e-03 4.9928e-03 8.9737e-03 -6.0000e+00 3.1323e-02 -1.1013e-03 2.6009e-03 2.4604e-03 -6.0000e+00 1.3228e-02 1.3571e-04 -1.0041e-04 1.3297e-04 2.5180e-05 -6.0000e+00 8.9521e-04 -7.9968e-03 3.1556e-06 11 8 0 10 0 0 98.24 27.35 0.71 -0.00800 -0.00875 11 11 1 5 0 2712.430 35.75 20.00 27.35 29.94 3.6 986.55 -5168 12794 -15461 1857 5674 -14975 5295 -16442 11187 5163 -4232 -1655 5135 3927 3728 -8056 -698 -3063 -1277 -2416 135 1033 -1248 2503 -508 2521 -4208 -3478 -9659 -3 384 41 3410 -1279 -3296 -2741 -2215 -1938 1434 145 113 -1196 450 843 675 -1619 662 -964 257 775 1142 1997 641 375 454 -77 847 333 407 -364 216 1768 1754 2175 745 67 -1145 -245 330 13 352 486 714 5 -528 825 -2119 -642 -1436 -216 -1051 -790 -2319 -1655 -1247 -3 609 475 453 1134 402 782 -509 152 -25 249 108 656 616 -641 -734 -1040 -784 -330 -490 -348 -1527 -262 96 589 246 903 193 246 313 -43 -29 -145 -215 12 -40 -385 456 745 280 -697 95 202 1178 432 -131 47 50 -50 66 83 9 -364 62 182 -312 -403 -99 -239 535 -862 79 212 -694 221 -976 558 283 -255 -106 358 325 357 -953 -81 -383 -164 -327 18 136 -177 367 -81 406 -711 -544 -1529 0 63 7 652 -256 -628 -529 -479 -498 432 51 43 -483 184 344 276 -679 267 -391 103 318 504 944 327 203 253 -44 492 193 229 -206 127 1114 1101 1451 496 42 -681 -159 213 10 280 398 577 4 -377 572 -1386 -404 -989 -153 -847 -703 -2229 -1661 -1340 -3 720 576 547 1296 427 756 -463 137 -25 270 131 886 802 -823 -958 -1243 -885 -387 -626 -466 -2168 -354 138 903 401 1482 308 365 428 -61 -41 -199 -317 19 -63 -592 677 1054 412 -989 128 276 1729 631 -205 76 82 -86 120 160 17 -731 124 352 -581 -720 -172 SS 20240723T123809.4Z 8970.526498 288 1 30.47 2 63.20 87.41 93.44 251.99 0.00 1 0.00 1 0 17 1.515e-02 5.138e-03 1.093e-02 2.155e-03 3.413296e-01 1.092808e-03 4.076678e-03 -6.000000e+00 8.724766e-03 232.62 -2.00 3.56 -2.00 318.14 0.00e+00 2.264565e-04 1.977339e-04 2.284025e-04 -6.000000e+00 3.854168e-04 286.39 -2.00 20.00 -2.00 317.33 0.00e+00 2.205 0.000 302.00 328.00 3 4.6419e+00 2.9593e-03 2.8218e-02 -6.0000e+00 2.1911e-02 3.5990e-02 3.3522e-03 1.8199e-02 -6.0000e+00 2.3714e-02 -1.3209e-02 2.1464e-03 8.8051e-03 -6.0000e+00 1.4097e-02 8.2308e-04 1.1038e-03 2.3873e-03 -6.0000e+00 5.9546e-03 3.8676e-04 3.8134e-05 6.0711e-05 2.4747e-05 -6.0000e+00 4.0282e-04 -8.3443e-03 4.8430e-05 10 0 0 10 0 0 99.67 27.35 0.35 -0.00834 -0.00806 18 18 1 5 0 1692.310 35.75 20.00 27.35 30.07 3.6 987.74 -5587 -837 -3848 -6421 -6500 -1375 -3655 -2567 -4459 -4363 -4590 -3005 -1441 -2543 1928 396 -335 329 360 -292 285 -362 -903 2897 -229 776 39 -2699 -1590 -934 1209 635 -130 -1293 -2739 -2810 -1226 -132 -352 -618 137 -649 -788 21 -207 356 -432 -373 142 150 439 1163 658 721 1231 727 993 706 579 -320 810 1433 1494 1105 875 -52 -971 222 645 530 557 59 368 -117 -134 -588 -1342 -588 -1016 -925 -706 -1226 -1453 -1132 -1095 -15 -21 445 387 426 184 79 80 -32 -66 508 56 609 624 -460 -1007 -481 -542 -336 -608 -696 -690 -299 -154 251 290 449 514 193 200 -190 256 -2 459 -77 222 -357 136 752 400 -36 278 497 833 325 -112 -54 -242 -176 -190 -66 -108 -128 62 165 -168 -489 -91 -352 -54 -259 -403 -370 -75 -224 -177 -348 -351 -369 -258 -142 -298 249 57 -51 52 60 -51 50 -64 -167 554 -48 166 8 -547 -303 -182 254 148 -33 -337 -674 -703 -340 -43 -127 -258 61 -305 -382 10 -100 171 -207 -176 66 72 227 645 390 414 726 442 613 431 346 -193 503 962 1098 869 679 -37 -672 152 482 451 474 52 320 -98 -111 -437 -919 -390 -734 -764 -606 -1171 -1479 -1207 -1164 -17 -24 536 464 487 209 82 77 -31 -69 586 68 813 817 -635 -1303 -566 -650 -391 -769 -926 -962 -407 -222 388 445 699 820 289 276 -266 359 -2 675 -121 350 -553 203 1072 582 -50 368 670 1212 479 -176 -87 -400 -285 -327 -120 -200 -228 110 302 -296 -826 -150 SS 20240723T124316.3Z 8970.530050 291 1 30.16 2 62.27 88.28 94.27 252.85 0.00 1 0.00 1 0 25 1.861e-02 5.686e-03 1.958e-02 3.541e-03 3.310718e-01 1.797621e-03 3.953479e-03 -6.000000e+00 1.071778e-02 232.62 -2.00 3.56 -2.00 318.34 0.00e+00 -9.369446e-05 3.416205e-04 3.035774e-04 -6.000000e+00 4.734099e-04 286.39 -2.00 20.00 -2.00 317.52 0.00e+00 2.138 0.000 302.00 328.00 3 5.4021e+00 4.9012e-03 2.7384e-02 -6.0000e+00 2.6916e-02 4.0020e-02 5.5712e-03 1.7722e-02 -6.0000e+00 2.9130e-02 -4.0826e-03 3.6308e-03 8.5621e-03 -6.0000e+00 1.7317e-02 -3.6002e-03 1.8743e-03 2.3431e-03 -6.0000e+00 7.3154e-03 1.9469e-04 -1.4619e-04 1.0121e-04 2.4127e-05 -6.0000e+00 4.9476e-04 -8.7691e-03 6.5922e-05 10 0 0 10 0 0 99.70 27.36 0.58 -0.00877 -0.00987 16 16 1 5 0 1884.880 35.75 20.00 27.36 30.22 3.6 988.45 -113 1475 2583 -8459 -12529 -6373 -4211 -1961 -986 957 -432 626 -636 -4001 716 -107 2300 -1320 -3665 895 -591 1273 -4332 -667 692 1524 -3596 -1846 595 1087 785 -121 1110 -144 108 -5159 -2196 2037 -683 -249 -696 -23 467 974 -556 317 -1340 -1477 -1027 250 -359 639 916 1381 580 1068 156 25 -567 295 1225 483 3112 2008 780 -17 -898 332 508 430 459 261 1095 386 -361 -188 -511 -809 -120 -848 -962 -963 -1982 -1062 -994 -294 -89 -280 158 -5 -133 -269 883 127 97 -748 398 1251 480 -532 -760 -211 -436 -497 -718 -470 -831 -28 -50 194 330 349 737 210 -75 -98 -63 332 277 -452 -36 -209 248 740 122 261 95 601 684 286 128 -154 -130 -54 -156 -89 202 -424 98 -95 -352 -222 75 -6 87 151 -502 -701 -337 -240 -125 -69 68 -31 48 -57 -434 85 -14 310 -194 -577 140 -95 200 -753 -120 130 294 -717 -337 100 187 148 -25 252 -33 23 -1176 -546 578 -241 -101 -307 -10 218 455 -264 149 -629 -684 -470 116 -181 313 475 753 329 618 93 15 -328 169 723 312 2140 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