File name: Pandora243s1_Toronto-CNTower_20240730_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20241016T145447.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240730_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240730T104622.3Z 8977.448869 232 1 28.91 2 84.00 70.34 33.40 111.47 0.00 1 0.00 1 0 25 5.633e-01 5.090e-02 5.130e-01 4.353e-02 9.185595e-01 2.651969e-02 1.300292e-02 -6.000000e+00 3.360243e-01 232.36 -2.00 3.56 -2.00 322.20 0.00e+00 2.134024e-02 1.419938e-02 1.638653e-02 -6.000000e+00 1.897207e-02 286.52 -2.00 20.00 -2.00 321.70 0.00e+00 8.525 0.012 302.00 328.00 3 9.1807e-01 9.9867e-02 1.2283e-01 -6.0000e+00 8.4783e-01 1.6410e+00 1.2354e-01 1.0194e-01 -6.0000e+00 9.2640e-01 -1.7254e+00 8.7703e-02 4.2826e-02 -6.0000e+00 5.4385e-01 6.3925e-01 4.3739e-02 9.3594e-03 -6.0000e+00 2.3185e-01 1.6858e-05 -3.0768e-03 1.2018e-03 3.2162e-04 -6.0000e+00 1.6176e-02 1.0298e-04 0.0000e+00 12 8 8 10 0 0 98.88 27.37 2.23 0.00010 -0.02302 12 12 1 5 0 2408.700 35.75 20.01 27.37 29.91 3.6 985.71 900000 900000 223922 47114 25964 -128289 -47699 -27019 900000 900000 -161072 900000 -60727 900000 92761 67565 76035 900000 41363 118548 900000 -62843 900000 43633 900000 -38963 900000 900000 131323 78229 900000 98221 900000 -18231 900000 -60952 900000 104957 7226 900000 114084 900000 -5917 21921 50910 6661 900000 197948 104665 41940 29436 -20634 39470 -29481 66664 15403 51670 110353 29788 -35047 30422 235934 96434 -2567 -6217 47483 -9509 -15449 58006 20974 10119 16647 17545 18375 -20358 66733 2405 19435 10189 30487 43005 326 -14910 32 -10523 26545 11603 32950 11187 -3371 9852 -9250 1230 -3823 12708 -577 -10921 1915 -6664 -740 -11099 -336 -12346 -12581 -10057 -3047 5395 -1114 3022 2972 -662 -1496 1625 5041 908 -915 1041 -2534 4108 1180 4246 1028 12299 -285 -1152 1389 -9353 -780 -4616 847 3903 -466 2104 -1686 488 -3721 1131 3402 684 -3096 -196 3189 -2241 900000 900000 9468 1992 1098 -9041 -2017 -1142 900000 900000 -11764 900000 -2568 900000 3922 2857 3215 900000 1749 5013 900000 -4831 900000 1845 900000 -1797 900000 900000 5553 3308 900000 4153 900000 -1261 900000 -5389 900000 4438 417 900000 4824 900000 -478 1348 2348 486 900000 8370 4426 2579 2263 -2855 3186 -4986 4356 1658 3774 4666 2405 -5254 2456 9976 5190 -424 -1123 4928 -1755 -3147 6867 3709 2353 3660 3635 3419 -4906 5926 386 2794 1896 5672 8365 112 -6494 12 -4850 8867 4661 10867 4541 -1511 3582 -3833 452 -1584 5212 -325 -8127 1474 -6171 -648 -10043 -242 -8875 -8937 -7441 -2216 3833 -923 2708 3092 -817 -2025 2184 6458 1167 -1164 1325 -3525 5663 1722 5835 1377 14093 -358 -1408 1609 -11786 -963 -6948 1407 7096 -968 4555 -4064 1237 -10354 3046 9062 1858 -8288 -470 6836 -4822 SS 20240730T105644.4Z 8977.456069 235 1 29.97 2 82.22 72.05 31.70 114.28 0.00 1 0.00 1 0 17 6.357e-01 1.530e-02 2.971e-01 6.559e-03 8.446775e-01 3.645619e-03 9.544140e-03 -6.000000e+00 3.664789e-01 232.36 -2.00 3.56 -2.00 321.87 0.00e+00 2.233424e-03 2.164840e-03 3.364047e-03 -6.000000e+00 1.622508e-02 286.52 -2.00 20.00 -2.00 321.34 0.00e+00 6.878 0.006 302.00 328.00 3 6.0300e-01 1.4541e-02 8.2887e-02 -6.0000e+00 9.1958e-01 4.9264e-01 2.1264e-02 5.1985e-02 -6.0000e+00 9.9542e-01 -6.5377e-01 2.0897e-02 2.7045e-02 -6.0000e+00 5.9192e-01 2.5817e-01 9.3853e-03 7.9159e-03 -6.0000e+00 2.4999e-01 1.6787e-04 -1.0004e-03 1.7076e-04 1.2519e-04 -6.0000e+00 1.7034e-02 1.2045e-03 0.0000e+00 12 8 8 10 0 0 72.69 27.45 1.01 0.00120 -0.00631 53 53 1 5 0 565.360 35.75 19.99 27.45 30.36 3.5 988.78 -209028 -157146 -98777 -170561 -262281 -249047 -226140 -183765 -216449 -151546 -229258 -158276 -86097 -157393 -29876 -27421 -44715 -53314 39965 -21360 32210 256 -11462 2939 -74098 -47483 38284 -43325 -64727 -55639 -67653 20330 14051 -49129 -35811 18519 -12346 -15499 -19648 4262 3324 28115 38507 12657 25754 9233 755 18881 8712 6604 8288 12058 24076 17813 24944 25104 29257 9428 8898 2646 11296 12105 14923 5424 14337 9087 17063 11859 1243 9744 13000 4696 5402 7521 -2448 3427 1603 -6969 685 -209 1726 676 -149 -1089 -2031 484 108 -391 285 371 -370 -656 1343 -5048 -2050 -2046 9 -1259 -1116 -418 -2262 -993 -3209 -795 -1637 -1604 -2566 16 -46 -135 -323 -87 385 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3.276775e-01 232.36 -2.00 3.56 -2.00 321.16 0.00e+00 2.037635e-03 5.888221e-04 1.821143e-03 -6.000000e+00 1.450669e-02 286.52 -2.00 20.00 -2.00 320.56 0.00e+00 5.821 0.004 302.00 328.00 3 1.3181e-01 4.1523e-03 6.9792e-02 -6.0000e+00 8.2222e-01 1.9619e-01 5.7483e-03 4.2218e-02 -6.0000e+00 8.9001e-01 -2.6521e-01 5.6943e-03 2.1774e-02 -6.0000e+00 5.2924e-01 1.0363e-01 2.6942e-03 6.5563e-03 -6.0000e+00 2.2353e-01 8.0147e-04 -6.3474e-04 5.8678e-05 8.7269e-05 -6.0000e+00 1.5230e-02 8.6103e-04 0.0000e+00 12 8 8 10 0 0 2.61 27.36 0.58 0.00086 -0.00391 130 130 1 5 0 230.130 35.75 20.00 27.36 30.61 3.5 990.72 -213283 -177232 -184611 -172480 -188462 -189305 -160732 -175889 -167489 -180506 -136220 -159510 -125596 -109017 -78927 -57300 -68210 -66175 -22350 -34158 -26473 -38301 -22896 -55656 -38386 -21254 -30939 -61942 -36961 -34984 -26139 -18648 -13624 -5129 -10787 -17896 -8531 -14089 -8024 -4804 4749 4745 -1574 3299 3592 2313 9757 2796 -3225 5482 6313 5015 8381 6086 6507 8053 5323 3971 2260 6125 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