File name: Pandora243s1_Toronto-CNTower_20240803_L2Fit_fwvt1c3d20240624p1-8.txt File generation date: 20241016T150932.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240803_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240803T102537.1Z 8981.434458 81 1 31.68 2 88.17 67.62 76.34 69.37 0.00 1 0.00 1 0 15 1.926e-02 1.901e-02 4.063e-03 4.040e-03 1.267422e+04 2.853363e+02 7.555449e+02 -6.000000e+00 1.097713e+03 286.59 -2.00 20.00 -2.00 505.46 0.00e+00 4.055751e-03 1.134159e-04 2.358124e-04 -6.000000e+00 5.464740e-04 286.59 -2.00 20.00 -2.00 501.17 0.00e+00 3.606411e-01 7.768513e-02 1.125085e-01 -6.000000e+00 3.832190e-01 232.21 -2.00 3.56 -2.00 502.65 0.00e+00 16.438 0.086 489.00 513.00 1 6.4956e+00 5.9575e-03 2.7784e-02 -6.0000e+00 2.9450e-02 -2.0296e-02 1.4783e-03 2.7841e-03 -6.0000e+00 7.5751e-03 2.7961e-04 -1.5045e-03 3.9703e-04 1.0789e-04 -6.0000e+00 2.0311e-03 1.9178e-02 2.8936e-05 12 8 8 10 0 0 13.94 27.51 22.93 0.01918 0.00874 8 8 1 4 0 3959.150 35.75 20.00 27.51 30.86 3.6 994.26 -3638 -3329 -1449 -359 1487 2031 3175 3314 2921 1716 671 -795 -501 -1529 -2051 -2785 -1034 1802 195 946 689 2029 436 1633 2929 2728 1620 748 -752 -2395 -2348 -3295 -1961 -335 364 767 1020 499 -326 -472 499 564 835 1508 1897 1551 2134 1999 1135 -409 -2264 -4057 -2967 -3235 -2158 -627 1922 1751 994 1618 1878 2115 2868 1877 1358 161 599 263 -1384 -959 -2232 -1275 -1055 -1388 -269 -1384 -2218 -3080 -2684 -3376 -2747 -2132 -3297 -1696 -1016 -1548 -201 -1156 -1174 -1192 -589 -553 1336 1493 2291 1772 819 94 -1315 -3538 -4211 -3904 -2219 -1066 -248 180 -497 -1340 -1121 -963 -799 488 2332 2633 2752 3552 3757 4009 3590 2292 1783 1077 1263 1116 1886 1341 1369 1508 1000 1415 374 92 -1587 -1248 -1257 -2291 -1028 -529 796 521 890 519 1307 1637 1036 198 662 -1322 -1926 -3170 -2898 -3195 -2960 -1305 -331 1389 1832 2885 3038 2689 1584 618 -732 -454 -1385 -1859 -2555 -946 1640 185 903 663 1933 423 1577 2813 2637 1581 729 -729 -2299 -2213 -3142 -1881 -327 363 772 1024 499 -326 -471 495 565 845 1540 1956 1536 2100 1953 1103 -416 -2289 -4086 -2925 -3219 -2068 -611 1873 1737 1000 1620 1880 2127 2880 1908 1381 164 599 260 -1379 -941 -2204 -1248 -1039 -1389 -269 -1398 -2233 -3078 -2639 -3322 -2686 -2084 -3288 -1681 -1012 -1566 -201 -1167 -1182 -1199 -592 -563 1351 1511 2271 1723 781 88 -1213 -3283 -3913 -3663 -2114 -1048 -251 186 -520 -1406 -1167 -1005 -803 492 2342 2661 2797 3610 3853 4149 3749 2410 1857 1111 1285 1135 1915 1379 1415 1562 1041 1467 390 95 -1650 -1282 -1292 -2405 -1086 -567 857 572 985 582 1465 1838 1172 225 740 -1482 -2137 -3535 -3243 SQ 20240803T102830.1Z 8981.436459 85 1 29.38 2 87.69 68.11 75.87 69.81 0.00 1 0.00 1 0 36 1.348e-02 1.333e-02 1.424e-03 1.417e-03 1.809963e+04 1.043622e+02 1.143288e+03 -6.000000e+00 7.685656e+02 286.59 -2.00 20.00 -2.00 505.45 0.00e+00 3.454696e-03 3.996678e-05 2.063271e-04 -6.000000e+00 3.827698e-04 286.59 -2.00 20.00 -2.00 501.09 0.00e+00 6.380627e-01 2.740340e-02 1.261063e-01 -6.000000e+00 2.689991e-01 232.21 -2.00 3.56 -2.00 502.58 0.00e+00 15.175 0.068 489.00 513.00 1 5.1332e+00 2.1012e-03 2.5710e-02 -6.0000e+00 2.0662e-02 -5.9117e-02 5.2176e-04 3.2295e-03 -6.0000e+00 5.3318e-03 1.2722e-03 2.8908e-03 1.3278e-04 1.3185e-04 -6.0000e+00 1.4233e-03 2.8150e-02 -2.1875e-04 12 8 8 10 0 0 61.93 27.51 16.89 0.02815 0.04820 15 15 1 4 0 1958.420 35.75 20.00 27.51 31.00 3.6 994.52 -2517 -2147 -784 304 1361 1993 2403 2486 2306 1310 1344 -65 -418 -737 -1430 -1146 -769 127 566 555 591 1107 705 1150 1745 1338 1029 589 -435 -1562 -2272 -2194 -1337 -306 359 334 76 119 -210 -578 -309 188 379 785 1311 1778 1597 888 467 -637 -1480 -2266 -2405 -2250 -1442 -477 415 1116 1337 790 1012 1550 1917 1882 1125 730 164 -283 -888 -1444 -1579 -1777 -1499 -975 -769 -952 -1378 -2088 -1887 -2194 -1966 -1604 -1673 -800 -935 -1075 -882 -838 -1003 -678 -115 205 893 1399 1284 1079 418 -342 -1420 -2590 -2612 -2696 -1869 -844 -170 -96 -580 -487 -798 -730 -329 352 804 1427 1995 2609 2932 2918 2240 1220 911 276 818 965 1304 1280 1325 1180 1066 749 651 -184 -849 -863 -1563 -1083 -620 -174 268 927 546 721 849 806 1062 795 303 -578 -1761 -2205 -2010 -2168 -1872 -696 277 1265 1815 2222 2321 2158 1227 1243 -61 -384 -672 -1307 -1050 -714 120 543 541 581 1086 697 1097 1668 1290 993 566 -414 -1520 -2190 -2119 -1258 -294 353 334 76 118 -207 -571 -305 187 381 798 1344 1827 1585 880 475 -642 -1467 -2215 -2332 -2193 -1429 -466 413 1119 1346 801 1028 1575 1953 1923 1153 744 166 -284 -886 -1433 -1559 -1761 -1494 -979 -779 -965 -1385 -2079 -1852 -2144 -1916 -1565 -1648 -791 -937 -1090 -896 -849 -1012 -681 -115 208 905 1410 1271 1037 390 -323 -1324 -2406 -2421 -2452 -1750 -822 -167 -97 -593 -496 -812 -745 -338 365 839 1489 2079 2722 3090 3019 2353 1290 952 285 856 1006 1362 1348 1356 1216 1100 775 672 -189 -870 -880 -1610 -1124 -653 -187 291 1018 591 789 936 893 1174 878 333 -631 -1920 -2401 -2199 SQ 20240803T103122.2Z 8981.438451 89 1 30.95 2 87.21 68.59 75.40 70.24 0.00 1 0.00 1 0 29 1.016e-02 1.004e-02 1.465e-03 1.458e-03 1.923063e+04 1.094345e+02 1.216008e+03 -6.000000e+00 5.788931e+02 286.59 -2.00 20.00 -2.00 505.46 0.00e+00 2.931841e-03 4.117588e-05 1.848370e-04 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