File name: Pandora243s1_Toronto-CNTower_20240817_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20241016T152048.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240817_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240817T125841.1Z 8995.540753 211 1 28.77 2 63.46 97.18 146.53 289.24 0.00 1 0.00 1 0 17 3.104e-02 7.473e-03 2.350e-02 4.783e-03 3.104338e-01 2.408025e-03 3.705388e-03 -6.000000e+00 1.783745e-02 231.54 -2.00 3.56 -2.00 318.25 0.00e+00 1.505888e-04 4.497048e-04 2.724265e-04 -6.000000e+00 7.924166e-04 286.59 -2.00 20.00 -2.00 317.42 0.00e+00 2.225 0.000 302.00 328.00 3 4.9714e+00 6.5397e-03 2.7154e-02 -6.0000e+00 4.4666e-02 5.6447e-02 7.4373e-03 1.6496e-02 -6.0000e+00 4.8383e-02 -5.6463e-03 4.7650e-03 7.9995e-03 -6.0000e+00 2.8792e-02 -3.5256e-03 2.4526e-03 2.1944e-03 -6.0000e+00 1.2179e-02 2.8572e-04 -4.2442e-04 1.3803e-04 2.2305e-05 -6.0000e+00 8.3158e-04 2.6121e-03 0.0000e+00 11 9 0 11 8 0 99.98 27.54 0.58 0.00261 -0.00058 10 10 1 5 0 2876.350 35.75 20.00 27.54 28.28 3.6 974.88 -13594 -5784 -14416 788 2931 -18077 -3795 -1721 -9863 -10 -4152 -7492 -854 -6010 4935 1833 2264 -4664 1874 -2351 4450 4120 3079 3217 274 -1414 6051 2990 1363 -565 -2715 -4567 -1429 979 -2416 -5614 -1051 -942 -39 -223 128 -684 -901 -606 853 1298 -933 -368 -199 1103 856 3811 582 -611 1269 528 -54 1018 338 157 1211 -372 2973 1610 1634 -241 -1073 308 -786 -527 168 1065 -228 -51 -1090 272 -2439 -2154 -1923 -642 -1597 -516 -1170 -203 -970 335 267 -42 565 602 -191 -291 -133 -785 551 35 426 826 537 48 -1161 -830 -1301 -319 425 -1297 -867 830 -126 305 596 521 304 -491 323 -238 431 -363 37 -72 555 -314 316 1238 -209 246 -48 -380 575 339 -77 -215 -211 -27 -352 727 -264 -420 9 794 -272 -774 -92 -983 -415 -1130 48 159 -1214 -242 -122 -837 -1 -341 -685 -84 -726 612 256 328 -761 299 -406 722 669 529 588 54 -295 1149 544 238 -103 -552 -1033 -341 228 -541 -1320 -265 -281 -14 -92 56 -318 -431 -290 402 608 -438 -169 -90 507 424 1966 329 -369 774 332 -35 640 209 97 773 -238 2006 1169 1162 -161 -681 211 -540 -411 141 914 -196 -42 -827 201 -1686 -1442 -1384 -472 -1333 -471 -1140 -206 -1064 388 324 -52 699 709 -209 -291 -123 -720 537 38 517 1109 758 67 -1513 -988 -1475 -375 538 -1753 -1222 1208 -179 463 954 843 473 -718 469 -329 594 -529 52 -109 846 -474 461 1864 -303 338 -64 -509 822 522 -115 -331 -332 -44 -617 1321 -496 -808 17 1465 -486 -1340 -155 SS 20240817T130341.4Z 8995.544229 214 1 31.61 2 62.57 98.11 147.33 290.53 0.00 1 0.00 1 0 17 4.631e-02 1.302e-02 5.221e-02 9.633e-03 3.057068e-01 4.848082e-03 3.683953e-03 -6.000000e+00 2.662063e-02 231.54 -2.00 3.56 -2.00 318.44 0.00e+00 -1.426229e-03 9.470278e-04 1.202291e-04 -6.000000e+00 1.182458e-03 286.59 -2.00 20.00 -2.00 317.61 0.00e+00 2.159 0.000 302.00 328.00 3 5.9463e+00 1.3249e-02 2.6583e-02 -6.0000e+00 6.6659e-02 6.2629e-02 1.5120e-02 1.6458e-02 -6.0000e+00 7.2203e-02 -6.5517e-03 9.7351e-03 7.9398e-03 -6.0000e+00 4.2967e-02 5.4412e-03 5.0039e-03 2.4781e-03 -6.0000e+00 1.8179e-02 1.1527e-04 -1.2608e-04 2.7898e-04 2.5118e-05 -6.0000e+00 1.2408e-03 1.4936e-03 0.0000e+00 12 9 8 11 8 0 99.00 27.51 1.14 0.00149 0.00055 8 8 1 5 0 3950.380 35.75 19.99 27.51 28.50 3.6 976.00 -4421 748 -1059 -8239 -7672 -1690 5072 -7283 -4201 -14031 9284 -8062 5381 -5047 -2787 32318 -10422 -10506 -7626 8386 1137 -8989 -7572 8597 -3674 -2078 4332 4196 2336 3566 -5585 5678 -9019 4746 -3878 -10092 -2640 7760 -2396 3132 389 -2068 1842 1745 2777 -3639 1105 2912 659 -2155 384 -236 246 1501 3138 1758 -990 -1184 781 433 -311 2788 -588 1111 2961 3167 -544 536 -261 1973 -799 3444 -1525 842 583 -1192 -2758 -746 -1027 -1922 -1398 -2618 -2755 -1073 -2235 1258 2021 582 1080 -171 848 -426 -880 -4000 -1319 -297 1364 1057 1812 -1121 -736 -1010 -517 -1157 -347 -1195 112 -982 81 225 1371 751 13 -249 -162 -1556 511 -1249 -2146 1005 943 156 1116 712 242 -190 -56 1012 1396 665 644 423 -598 1235 -29 -21 114 146 343 276 -1064 -1044 -841 -264 45 -65 -493 -413 -87 269 -498 -309 -1174 672 -742 495 -593 -364 3218 -1655 -1747 -1282 1245 183 -1596 -1394 1446 -739 -426 814 729 388 596 -1107 1093 -2186 999 -827 -2332 -637 2005 -828 1183 163 -921 808 766 1200 -1668 472 1198 274 -945 177 -117 129 819 1736 1011 -595 -705 445 247 -186 1747 -415 816 2086 2047 -344 334 -179 1505 -678 2895 -1331 684 437 -812 -1741 -448 -665 -1426 -1159 -2425 -2712 -1090 -2471 1435 2397 718 1320 -202 908 -423 -810 -3754 -1296 -321 1617 1393 2484 -1537 -937 -1183 -571 -1347 -435 -1587 154 -1428 123 365 2113 1174 21 -385 -230 -2120 685 -1785 -3318 1596 1516 248 1708 1045 338 -253 -71 1291 1911 983 1003 680 -990 2090 -54 -41 202 265 621 532 -1995 -1881 -1476 SS 20240817T130821.8Z 8995.547474 217 1 9.17 2 61.73 98.98 148.07 291.77 0.00 1 0.00 1 0 17 1.224e-02 6.177e-03 8.548e-03 2.920e-03 2.916481e-01 1.485106e-03 3.522769e-03 -6.000000e+00 7.036859e-03 231.54 -2.00 3.56 -2.00 317.05 0.00e+00 5.129193e-04 2.022134e-04 9.729005e-05 -6.000000e+00 3.124869e-04 286.59 -2.00 20.00 -2.00 316.25 0.00e+00 2.101 0.000 302.00 328.00 3 3.5922e+00 3.9368e-03 2.5577e-02 -6.0000e+00 1.7621e-02 3.0248e-02 4.4142e-03 1.5443e-02 -6.0000e+00 1.9084e-02 -3.8287e-03 2.6180e-03 7.4863e-03 -6.0000e+00 1.1357e-02 -9.9350e-04 1.2779e-03 2.0666e-03 -6.0000e+00 4.8067e-03 1.3269e-03 -6.0316e-05 8.2135e-05 2.2959e-05 -6.0000e+00 3.2789e-04 -8.5141e-04 0.0000e+00 12 1 1 12 1 1 99.97 27.48 0.46 -0.00085 -0.00130 8 29 1 5 0 1018.690 35.75 19.99 27.48 28.69 3.6 977.42 -2178 -2709 -7699 -1533 637 -1867 770 -1426 4092 922 -545 -1732 -390 -539 -41 -1343 212 1881 1968 -407 1457 858 929 427 1328 1053 1134 -1797 -2601 -277 865 736 1302 -1559 -4141 -1298 -860 163 -615 -615 -636 -257 -1184 -1008 237 -982 -170 -1531 -622 241 1110 405 1227 645 1095 28 -163 735 1231 125 868 1858 2006 1213 684 -411 -59 896 1005 421 985 89 38 410 -551 -425 -583 -405 -1015 -504 -640 -1433 -1895 -1807 -1357 -105 -34 -44 190 525 -3 493 507 231 -340 51 437 477 593 -404 -1122 -52 -173 -484 -534 -433 -828 -321 -467 341 161 551 38 164 389 140 366 -44 283 -60 -10 -277 247 335 422 349 699 430 808 569 -32 -12 7 -101 -80 28 117 -112 -136 -309 -587 -179 -153 -264 -353 -1055 -179 66 -198 87 -186 555 133 -79 -271 -69 -101 -9 -315 51 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