File name: Pandora243s1_Toronto-CNTower_20240830_L2Fit_fwvt1c2d20230307p1-8.txt File generation date: 20240831T052830.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240830_L1_smca1c2d20230307p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0337 492.1543 492.2749 492.3955 492.5160 492.6366 492.7571 492.8776 492.9981 493.1185 493.2390 493.3594 493.4798 493.6002 493.7206 493.8410 493.9614 494.0817 494.2020 494.3223 494.4426 494.5629 494.6831 494.8033 494.9236 495.0438 495.1639 495.2841 495.4043 495.5244 495.6445 495.7646 495.8847 496.0048 496.1248 496.2448 496.3648 496.4848 496.6048 496.7248 496.8447 496.9647 497.0846 497.2045 497.3244 497.4442 497.5641 497.6839 497.8037 497.9235 498.0433 498.1630 498.2828 498.4025 498.5222 498.6419 498.7616 498.8812 499.0009 499.1205 499.2401 499.3597 499.4793 499.5988 499.7184 499.8379 499.9574 500.0769 500.1963 500.3158 500.4352 500.5546 500.6740 500.7934 500.9128 501.0321 501.1515 501.2708 501.3901 501.5094 501.6286 501.7479 501.8671 501.9863 502.1055 502.2247 502.3439 502.4630 502.5821 502.7013 502.8203 502.9394 503.0585 503.1775 503.2965 503.4156 503.5345 503.6535 503.7725 503.8914 504.0103 504.1292 504.2481 504.3670 504.4859 504.6047 504.7235 504.8423 504.9611 505.0799 505.1986 505.3173 505.4361 505.5548 505.6734 505.7921 505.9107 506.0294 506.1480 506.2666 506.3852 506.5037 506.6223 506.7408 506.8593 506.9778 507.0963 507.2147 507.3331 507.4516 507.5700 507.6884 507.8067 507.9251 508.0434 508.1617 508.2800 508.3983 508.5166 508.6348 508.7531 508.8713 508.9895 509.1076 509.2258 509.3440 509.4621 509.5802 509.6983 509.8164 509.9344 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240830T114106.6Z 9008.486881 212 1 30.71 2 79.84 87.60 41.36 101.19 0.00 1 0.00 1 0 15 2.601e-03 2.587e-03 1.255e-03 1.252e-03 5.823824e+03 8.348772e+01 4.140924e+02 -6.000000e+00 1.480905e+02 285.48 -2.00 20.00 -2.00 505.29 0.00e+00 7.784094e-04 3.490087e-05 5.046818e-05 -6.000000e+00 7.373945e-05 285.48 -2.00 20.00 -2.00 500.41 0.00e+00 4.803350e-01 2.499567e-02 3.682397e-02 -6.000000e+00 5.190094e-02 230.36 -2.00 3.56 -2.00 502.01 0.00e+00 5.431 0.003 489.00 513.00 1 7.1169e+00 1.9198e-03 8.2210e-03 -6.0000e+00 3.9861e-03 1.1069e-02 4.8766e-04 1.0010e-03 -6.0000e+00 1.0276e-03 7.1352e-04 2.0769e-03 1.2759e-04 4.7550e-05 -6.0000e+00 2.7742e-04 -4.6549e-03 3.4447e-05 10 0 0 10 0 0 99.96 27.52 2.18 -0.00465 0.00975 13 13 1 4 0 2361.780 35.75 19.99 27.52 24.12 3.6 944.12 98 -408 -128 23 150 454 455 208 297 146 244 11 -178 -219 -345 -240 52 244 118 -79 -144 445 74 419 546 222 8 80 -136 -193 -202 -458 -105 99 -7 -365 -254 53 -203 182 19 189 171 70 289 225 288 95 80 -184 -399 -324 -385 -456 -120 -60 -382 -77 129 -18 118 104 64 122 -109 -49 103 143 -174 -356 -251 -128 16 50 -117 -148 -351 -11 -84 -581 -191 -116 -353 67 -75 -239 150 -163 -149 135 20 46 140 267 318 146 306 138 -275 -505 -399 -246 -689 -406 -360 -493 -317 -235 417 -100 52 -230 -185 248 519 174 543 615 229 -57 406 -82 516 225 234 -12 -8 129 432 260 199 21 -170 -104 172 -127 -95 89 14 252 214 132 14 91 228 -177 -166 -93 -402 160 -396 94 -398 -129 23 155 476 470 218 310 151 249 12 -183 -223 -349 -243 53 246 122 -84 -153 470 78 444 579 237 8 84 -140 -194 -205 -466 -105 101 -7 -392 -271 56 -213 188 20 196 179 74 299 234 297 101 84 -188 -396 -314 -379 -451 -117 -60 -392 -80 135 -18 119 105 65 123 -110 -50 105 143 -172 -349 -243 -123 16 49 -116 -147 -346 -10 -80 -552 -181 -111 -339 64 -73 -237 148 -162 -148 134 20 45 138 264 312 141 297 131 -255 -460 -361 -224 -648 -395 -350 -488 -313 -230 402 -97 51 -228 -185 249 524 177 555 611 228 -59 406 -82 502 219 229 -11 -8 127 423 255 194 21 -162 -98 160 -120 -91 87 14 245 211 131 14 91 229 -177 -164 -91 -397 155 -386 SQ 20240830T114840.2Z 9008.492132 218 1 31.34 2 78.47 88.90 40.06 102.80 0.00 1 0.00 1 0 15 3.686e-03 3.650e-03 2.986e-03 2.972e-03 4.851615e+03 1.990992e+02 3.484526e+02 -6.000000e+00 2.099248e+02 285.48 -2.00 20.00 -2.00 505.29 0.00e+00 5.937257e-04 8.273402e-05 4.213744e-05 -6.000000e+00 1.045149e-04 285.48 -2.00 20.00 -2.00 500.26 0.00e+00 5.990518e-01 5.986575e-02 3.081935e-02 -6.000000e+00 7.352952e-02 230.36 -2.00 3.56 -2.00 501.90 0.00e+00 4.839 0.002 489.00 513.00 1 8.4584e+00 4.5986e-03 7.2467e-03 -6.0000e+00 5.6477e-03 2.1158e-02 1.1703e-03 8.4547e-04 -6.0000e+00 1.4550e-03 2.0143e-04 1.3712e-03 3.0414e-04 3.6174e-05 -6.0000e+00 3.9322e-04 -7.6528e-03 9.6937e-05 10 0 0 10 0 0 98.36 27.41 2.41 -0.00765 0.00186 9 9 1 4 0 3481.430 35.75 20.00 27.41 24.09 3.6 944.31 -21 -118 88 81 150 350 464 417 384 198 148 365 -435 -94 -272 -632 2 146 -47 22 -55 19 178 302 298 -44 -5 230 -454 -72 -588 -184 -192 133 98 -345 -120 164 -198 181 166 -81 217 -661 -358 810 126 129 307 78 -410 -550 -478 -331 191 -268 192 -430 320 593 -65 -329 103 -119 -17 409 307 580 -447 -12 -104 -498 -85 -158 88 59 -676 -360 -192 -125 416 -72 -487 359 354 -672 148 277 -16 -153 -330 -147 -355 -236 66 716 613 70 -720 41 -485 -243 -277 -34 -137 -913 74 803 904 -540 231 -460 -181 758 5 186 717 765 -725 314 -714 179 459 -12 -43 -609 -95 212 92 349 97 -574 8 601 -382 -532 121 289 -22 300 84 14 -234 302 591 245 -399 -22 -231 219 78 -21 -118 86 82 155 369 497 451 416 213 156 380 -450 -95 -275 -645 2 154 -50 24 -60 21 195 332 328 -49 -6 250 -484 -75 -600 -187 -198 141 106 -364 -126 178 -214 192 176 -86 223 -691 -377 845 132 133 311 81 -417 -546 -467 -324 190 -275 192 -438 324 599 -66 -336 105 -121 -18 408 302 561 -431 -12 -102 -492 -84 -152 85 56 -648 -354 -186 -121 398 -70 -455 336 334 -648 142 266 -15 -147 -321 -144 -352 -235 65 688 576 65 -652 36 -426 -215 -251 -32 -133 -905 72 773 860 -521 223 -453 -180 754 5 188 727 778 -747 317 -716 175 443 -11 -42 -597 -93 207 89 338 93 -552 7 555 -354 -498 114 278 -22 297 80 14 -228 294 574 238 -385 -21 -223 209 75 SQ 20240830T121530.6Z 9008.510771 234 1 31.49 2 73.62 93.57 35.53 109.03 0.00 1 0.00 1 0 15 4.317e-03 4.273e-03 3.667e-03 3.645e-03 4.452412e+03 2.443760e+02 3.219394e+02 -6.000000e+00 2.458562e+02 285.48 -2.00 20.00 -2.00 505.28 0.00e+00 7.408371e-04 1.014896e-04 4.857225e-05 -6.000000e+00 1.224031e-04 285.48 -2.00 20.00 -2.00 500.18 0.00e+00 3.318282e-01 7.384398e-02 2.839050e-02 -6.000000e+00 8.611065e-02 230.35 -2.00 3.56 -2.00 501.82 0.00e+00 3.489 0.001 489.00 513.00 1 8.9300e+00 5.6805e-03 5.5066e-03 -6.0000e+00 6.6141e-03 2.8124e-02 1.4413e-03 7.4689e-04 -6.0000e+00 1.7038e-03 1.5413e-04 5.3007e-04 3.7283e-04 3.4292e-05 -6.0000e+00 4.6053e-04 -9.0389e-03 1.1029e-04 11 8 0 10 0 0 84.68 27.48 2.34 -0.00904 -0.00536 8 8 1 4 0 3935.560 36.00 20.00 27.48 24.38 3.6 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