File name: Pandora254s1_TubaCityAZ_20240412_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240715T144227.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240412_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240412T132559.7Z 8868.559719 44 1 54.89 2 84.63 82.78 107.75 36.10 0.00 1 0.00 1 0 25 6.721e-01 2.469e-02 5.413e-01 1.862e-02 1.080375e+00 1.148734e-02 1.079902e-02 -6.000000e+00 3.916576e-01 228.02 -2.00 3.37 -2.00 322.70 0.00e+00 7.917931e-03 7.056186e-03 3.266399e-03 -6.000000e+00 1.914748e-02 275.26 -2.00 20.00 -2.00 322.32 0.00e+00 9.352 0.013 302.00 328.00 3 6.9953e-01 4.7838e-02 1.0295e-01 -6.0000e+00 9.7941e-01 1.3738e+00 6.7987e-02 7.7890e-02 -6.0000e+00 1.0793e+00 -1.7994e+00 6.4393e-02 3.3772e-02 -6.0000e+00 6.3143e-01 7.0350e-01 2.9347e-02 1.4552e-02 -6.0000e+00 2.6071e-01 3.2542e-05 -8.3496e-05 4.9904e-04 1.9432e-04 -6.0000e+00 1.8300e-02 2.9209e-02 12 8 8 10 0 0 23.58 24.70 0.75 0.02921 0.02858 63 6 1 5 0 871.080 33.75 20.10 24.70 13.52 4.3 892.83 -13409 900000 -64635 -141764 -98744 -30471 -104001 -136619 -76041 -118376 -94743 -191693 900000 900000 122263 29514 57483 -74574 900000 900000 900000 136939 -105387 900000 900000 900000 900000 10830 117864 -19513 -45568 900000 900000 -25122 900000 38902 900000 84680 210830 184628 900000 58226 -24641 67601 126104 6038 99938 134236 100841 121530 231863 243250 62090 105538 69339 20060 57742 53150 54109 -6500 87323 85201 25992 47335 64371 58499 8773 49177 6401 39671 75990 -3663 14562 16629 27961 2404 14835 1738 -12052 -4964 6994 9874 5262 10150 3418 2972 8291 4613 1047 -5459 -4317 6537 -3120 -1771 8820 -7126 2501 -3111 3626 148 -2652 -3296 -5489 -2236 -5774 -7009 159 -146 -3444 -2877 139 -575 -1466 -1811 -478 -1731 -2711 2294 -1614 976 3419 -743 5106 2619 2841 3432 1432 1518 -1174 -72 640 -121 -584 425 248 -987 563 1962 796 -431 -1416 -1795 -753 -243 900000 -1170 -3637 -1788 -552 -1883 -2474 -1377 -2143 -1716 -6626 900000 900000 2214 534 1041 -2455 900000 900000 900000 2480 -3817 900000 900000 900000 900000 196 2134 -353 -1125 900000 900000 -744 900000 704 900000 1533 3818 3343 900000 1150 -1136 1224 2283 199 1810 2431 1826 2201 4198 4405 2044 2432 2397 1156 2281 2100 1960 -407 2156 2384 1540 2649 3285 3178 809 3562 800 4095 5917 -643 2030 2048 2683 261 1370 198 -1899 -908 1368 2199 1362 2647 1009 926 2537 1487 345 -1829 -1329 1728 -921 -571 3066 -3548 1363 -2129 2580 109 -1878 -2053 -3071 -1198 -3440 -4455 101 -102 -2875 -2839 155 -715 -1914 -2371 -601 -2160 -3504 2978 -2297 1372 4463 -944 5852 2992 3153 3698 1554 1820 -1749 -126 1270 -268 -1398 1092 689 -2903 1647 5702 2300 -1176 -3555 -4129 -1640 SS 20240412T133730.1Z 8868.567710 47 1 54.48 2 82.32 84.45 106.40 38.24 0.00 1 0.00 1 0 17 8.457e-01 9.894e-03 2.443e-01 3.003e-03 9.055131e-01 1.672624e-03 9.317533e-03 -6.000000e+00 4.768851e-01 228.02 -2.00 3.37 -2.00 322.06 0.00e+00 5.313065e-03 9.222306e-04 2.521962e-03 -6.000000e+00 2.047730e-02 275.26 -2.00 20.00 -2.00 321.63 0.00e+00 6.975 0.005 302.00 328.00 3 5.8836e-01 6.0859e-03 7.5567e-02 -6.0000e+00 1.1888e+00 3.0397e-01 1.0387e-02 5.0013e-02 -6.0000e+00 1.2937e+00 -3.8846e-01 1.2275e-02 3.0687e-02 -6.0000e+00 7.6704e-01 1.4669e-01 5.4945e-03 1.3494e-02 -6.0000e+00 3.2333e-01 3.3059e-04 2.8304e-04 7.7226e-05 1.6571e-04 -6.0000e+00 2.2159e-02 2.9169e-02 12 8 8 10 0 0 12.01 24.73 0.35 0.02917 0.03130 233 24 1 5 0 233.800 33.75 20.03 24.73 14.01 4.3 897.03 -278066 -216172 -169778 -172157 -294707 -318062 -301133 -282971 -294809 -142032 -214662 -274415 -173096 -157448 -85851 -92970 -40574 -144971 -104129 -139197 -97047 -105541 -78207 -85027 -47867 -96677 -88240 -76528 -106022 -6072 -20371 -44763 36466 -33625 -3227 -15843 -20643 -11728 -22105 -10990 -12594 12851 3178 15067 -8460 -250 8361 16320 6779 7219 2371 7854 16511 7299 15328 8440 8868 6627 6599 4991 426 7732 7552 11634 7235 5617 5399 5149 6004 5670 6404 3640 873 4159 -300 2402 -4767 -3665 -2742 -902 279 126 -286 -1779 601 1774 641 1396 312 1643 -262 -1180 -746 -1523 -1046 -1200 51 663 235 -506 -734 -1399 -1711 -489 -2186 -1390 -1474 -1015 -5 78 6 -114 168 -161 -762 -336 237 328 -62 429 335 833 1364 1136 315 -124 1 845 367 203 -43 -89 -308 -93 -125 -252 246 492 161 5 43 -547 -693 -1481 -748 -497 -504 -2197 -2964 -2566 -2260 -2983 -416 -1143 -3215 -1014 -1090 -389 -569 -173 -2007 -1053 -2112 -982 -1152 -687 -883 -370 -1287 -1104 -835 -1581 -39 -195 -691 301 -609 -45 -251 -381 -237 -615 -332 -439 376 109 472 -342 -10 311 602 300 353 140 504 1083 581 1208 746 805 607 580 434 40 763 878 1516 1064 841 832 849 1111 1229 1517 918 220 938 -63 439 -898 -727 -636 -253 92 49 -123 -823 290 897 342 756 170 842 -127 -549 -344 -764 -611 -841 42 632 247 -534 -721 -1219 -1335 -378 -1848 -1226 -1381 -1032 -6 93 9 -167 252 -237 -1081 -460 329 477 -96 672 505 1177 1840 1632 440 -169 1 1207 564 363 -87 -192 -714 -230 -334 -706 697 1403 456 13 105 -1251 -1532 SS 20240412T135502.5Z 8868.579890 52 1 54.46 2 78.78 86.99 104.20 41.37 0.00 1 0.00 1 0 17 3.899e-01 6.302e-03 4.072e-02 7.996e-04 6.826195e-01 4.164180e-04 7.334595e-03 -6.000000e+00 2.198727e-01 228.02 -2.00 3.37 -2.00 320.95 0.00e+00 3.093839e-03 1.797115e-04 1.668599e-03 -6.000000e+00 9.441154e-03 275.26 -2.00 20.00 -2.00 320.46 0.00e+00 4.969 0.002 302.00 328.00 3 4.2707e-01 1.3130e-03 5.4442e-02 -6.0000e+00 5.4809e-01 5.4415e-02 1.8016e-03 3.5382e-02 -6.0000e+00 5.9649e-01 -5.4971e-02 1.9660e-03 2.0491e-02 -6.0000e+00 3.5365e-01 1.2218e-02 9.5898e-04 8.2351e-03 -6.0000e+00 1.4907e-01 2.4376e-03 3.8982e-04 2.1066e-05 9.2451e-05 -6.0000e+00 1.0216e-02 2.9053e-02 10 0 0 10 0 0 6.59 24.77 0.33 0.02905 0.03198 692 70 1 5 0 78.690 33.50 19.96 24.77 15.63 4.2 907.43 -135311 -130716 -111497 -133979 -130823 -146717 -111212 -120271 -112036 -122236 -104955 -100918 -81857 -56135 -56901 -49912 -40609 -32458 -33584 -23308 -30307 -32840 -24084 -21670 -20853 -23343 -24970 -18755 -21834 -18771 -16526 -9289 -8648 -9093 -11404 -10948 -9641 -3567 -4665 -1591 -2739 -1872 -1379 -454 330 -637 465 -437 -491 2099 1638 1636 3134 3473 2865 2074 1352 370 364 648 890 2753 3663 3812 1926 957 1108 237 1296 1118 1225 1477 881 332 -428 -922 -2064 -2140 -1193 -1300 -900 -955 -1980 -1621 -789 -159 403 490 1049 1174 783 75 -495 -358 -351 -514 430 1084 440 -273 -439 -984 -643 -51 -1162 -1374 -1065 -790 -58 421 477 153 245 -62 -389 59 139 173 441 83 -132 458 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