File name: Pandora254s1_TubaCityAZ_20240512_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240715T143100.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240512_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240512T125310.5Z 8898.536927 47 1 53.93 2 84.74 71.10 114.12 21.28 0.00 1 0.00 1 0 25 6.182e-01 3.203e-02 5.561e-01 2.749e-02 1.251119e+00 1.765298e-02 1.368576e-02 -6.000000e+00 3.707249e-01 230.10 -2.00 3.37 -2.00 322.82 0.00e+00 1.245215e-02 1.066287e-02 4.161302e-03 -6.000000e+00 1.738085e-02 278.53 -2.00 20.00 -2.00 322.44 0.00e+00 9.491 0.013 302.00 328.00 3 5.8908e-01 7.3768e-02 1.0511e-01 -6.0000e+00 9.3036e-01 2.2565e+00 9.3356e-02 7.1956e-02 -6.0000e+00 1.0143e+00 -2.5363e+00 7.3004e-02 3.6559e-02 -6.0000e+00 5.9490e-01 9.0596e-01 3.6798e-02 2.0686e-02 -6.0000e+00 2.5085e-01 1.9709e-05 6.4409e-04 6.9160e-04 3.6586e-04 -6.0000e+00 1.7621e-02 3.0940e-02 12 8 8 10 0 0 42.67 24.58 0.87 0.03094 0.03578 46 5 1 5 0 1172.150 33.50 19.84 24.58 11.71 4.3 880.80 81609 -17760 900000 900000 900000 -66787 900000 900000 900000 -15614 -89350 -6367 900000 -113020 -2795 900000 20753 24857 49071 202433 900000 -19109 168772 900000 90106 27222 143925 133977 900000 -92322 175063 -29446 900000 -71797 24630 -82271 7527 -5355 38707 95006 75401 900000 47782 -24804 900000 80341 -23345 900000 193309 132746 184966 900000 110572 900000 5829 92269 126373 49629 57595 64051 900000 169663 98359 73720 6606 87825 16913 42267 68003 73374 60198 62788 41275 36396 12095 28372 32833 7958 56380 17234 6352 5148 25095 12593 14738 25047 -3774 11304 1025 17830 -3079 -13041 -8068 -11837 213 1965 566 2225 -2612 -3388 -7181 3219 -6852 -126 -9417 -3767 -9636 -5067 -5451 -4045 4173 -1529 -1755 -1386 -3622 -1836 2771 -2143 4230 1736 -245 519 4914 2627 3887 3570 -738 3374 2300 -548 897 284 -925 371 -743 322 -343 841 824 185 -511 -368 -2704 2180 -672 900000 900000 900000 -2081 900000 900000 900000 -417 -2387 -170 900000 -8508 -88 900000 655 785 1311 5408 900000 -650 4508 900000 2407 727 3845 3579 900000 -4932 4676 -1359 900000 -5754 658 -5794 219 -195 1034 2538 2014 900000 1392 -1446 900000 2146 -1304 900000 5164 3546 4941 900000 2954 900000 439 2913 3376 2169 2098 2022 900000 4532 2866 3222 610 3626 1479 3079 4294 4989 5467 5535 4190 3403 1228 2122 2280 787 4217 2394 1188 1141 5028 2994 3583 5687 -1169 3020 296 4096 -806 -3623 -2198 -3795 74 829 295 1361 -1863 -2434 -4930 1711 -3477 -59 -5106 -2022 -5869 -3289 -4164 -3685 4147 -1793 -2166 -1718 -4499 -2212 3287 -2816 5458 2290 -309 596 5145 2737 3904 3519 -757 3768 3214 -950 1774 629 -2270 982 -2147 957 -1034 2513 2404 501 -1257 -816 -5873 SS 20240512T130450.4Z 8898.545028 50 1 54.37 2 82.50 72.73 113.27 23.82 0.00 1 0.00 1 0 17 9.483e-01 1.196e-02 2.853e-01 4.008e-03 1.001749e+00 2.258605e-03 1.053987e-02 -6.000000e+00 5.387814e-01 230.10 -2.00 3.37 -2.00 322.22 0.00e+00 5.666926e-03 1.363062e-03 4.815490e-03 -6.000000e+00 2.327201e-02 278.53 -2.00 20.00 -2.00 321.81 0.00e+00 7.116 0.006 302.00 328.00 3 6.8964e-01 9.0689e-03 8.2163e-02 -6.0000e+00 1.3483e+00 4.9138e-01 1.5755e-02 5.8361e-02 -6.0000e+00 1.4644e+00 -6.3790e-01 1.8109e-02 3.5589e-02 -6.0000e+00 8.6838e-01 2.4636e-01 7.9031e-03 1.4773e-02 -6.0000e+00 3.6537e-01 2.3091e-04 3.4507e-04 9.9662e-05 2.4353e-04 -6.0000e+00 2.4863e-02 3.1232e-02 12 8 8 10 0 0 19.65 24.61 0.41 0.03123 0.03383 192 19 1 5 0 283.130 33.50 19.90 24.61 12.35 4.3 884.97 -331916 -317982 -272771 -264933 -331257 -219831 -241860 -292261 -306016 -305215 -287619 -215217 -135208 -155244 -200811 -177644 -107671 -89594 -70373 -129653 -65864 -67855 -91502 -142795 -104280 -47478 -73658 -103992 -74277 433 -40868 -1358 -43316 -15393 43391 -56729 -19790 11626 -18784 12 10728 31248 9459 7392 25908 13751 -5576 23742 55039 6181 29985 8628 39264 34528 5892 15484 11521 1868 9459 16164 -847 8218 10431 14630 11103 10414 6291 5585 7634 8091 8523 5028 6521 4645 1855 4822 -1488 -2155 -2138 3872 2547 1250 -1317 101 1047 3179 2292 2035 465 1330 1478 -1332 -33 -1974 -1189 -1936 -969 675 -701 -551 -1776 -1342 -1754 -1806 -2121 -2774 -2278 -1199 -663 223 617 -202 -887 -103 -573 -735 333 383 429 328 787 1766 1682 513 281 -79 114 730 555 -146 120 -168 -170 152 -244 -87 158 566 94 -46 -25 -643 -863 -2948 -2938 -1745 -1506 -3296 -859 -1031 -2285 -3044 -3253 -2759 -1223 -528 -938 -2569 -2272 -803 -637 -450 -1566 -421 -434 -780 -2232 -1186 -321 -654 -1219 -660 2 -407 -12 -677 -197 293 -1028 -274 154 -418 0 243 623 248 202 597 371 -192 659 1226 251 1113 455 1703 1741 424 1059 842 147 658 1017 -65 652 958 1515 1293 1233 807 777 1185 1458 1679 1057 1305 868 316 709 -225 -355 -421 891 715 416 -499 40 438 1376 1043 945 217 588 606 -537 -13 -882 -625 -1240 -734 591 -686 -537 -1625 -1071 -1246 -1281 -1620 -2240 -1947 -1112 -696 272 865 -310 -1409 -160 -863 -1080 494 597 703 545 1243 2584 2358 704 373 -102 145 1010 917 -259 239 -366 -397 382 -663 -246 450 1624 266 -122 -61 -1447 -1873 SS 20240512T131525.8Z 8898.552381 53 1 54.50 2 80.45 74.20 112.42 26.09 0.00 1 0.00 1 0 17 7.411e-01 7.553e-03 9.980e-02 1.520e-03 8.376952e-01 8.222683e-04 8.984023e-03 -6.000000e+00 4.210590e-01 230.10 -2.00 3.37 -2.00 321.60 0.00e+00 4.317330e-03 4.325670e-04 3.719340e-03 -6.000000e+00 1.818647e-02 278.53 -2.00 20.00 -2.00 321.12 0.00e+00 5.751 0.003 302.00 328.00 3 6.0668e-01 2.9218e-03 6.6618e-02 -6.0000e+00 1.0537e+00 1.5663e-01 4.5666e-03 4.7534e-02 -6.0000e+00 1.1444e+00 -1.8097e-01 5.2103e-03 2.8984e-02 -6.0000e+00 6.7863e-01 6.0712e-02 2.3817e-03 1.1489e-02 -6.0000e+00 2.8555e-01 9.0381e-04 5.2174e-04 3.8653e-05 1.5842e-04 -6.0000e+00 1.9429e-02 3.0881e-02 11 8 0 10 0 0 -9.65 24.65 0.34 0.03088 0.03480 400 41 1 5 0 136.230 33.75 19.96 24.65 13.20 4.3 890.85 -255649 -228304 -218048 -240209 -272606 -245063 -222681 -214412 -210852 -193872 -178391 -209619 -166566 -135338 -110656 -107509 -110401 -62233 -69603 -50852 -67472 -69833 -37873 -73783 -67446 -51107 -74484 -61987 -59438 -34284 -27306 -25038 -16594 -20385 -25125 -34035 -29187 -3810 -12176 -8759 -8724 3641 -2645 1948 4701 720 5128 -544 1372 4456 3520 3408 3668 7782 4679 4768 4897 1465 1963 1458 2061 5968 6588 4904 4467 1117 2192 1808 2843 2442 2348 3357 940 1861 1269 -1191 -1851 -2753 -1293 -1147 -19 -601 -1512 -1766 -724 -83 336 497 1355 786 604 -210 -1414 -1176 -773 -1096 119 1024 344 -437 -651 -1168 -856 -368 -1226 -1419 -1373 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