File name: Pandora254s1_TubaCityAZ_20240623_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240715T141316.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240623_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240623T142457.9Z 8940.600670 253 1 39.00 2 65.24 78.17 100.31 244.02 0.00 1 0.00 1 0 17 1.214e-02 6.253e-03 1.398e-03 3.801e-04 3.068181e-01 1.915071e-04 3.465645e-03 -6.000000e+00 6.937747e-03 231.52 -2.00 3.37 -2.00 317.54 0.00e+00 4.835222e-04 2.934266e-05 1.761671e-04 -6.000000e+00 3.030871e-04 282.70 -2.00 20.00 -2.00 316.80 0.00e+00 2.372 0.000 302.00 328.00 3 1.6021e+00 5.1185e-04 2.5315e-02 -6.0000e+00 1.7398e-02 1.4187e-02 5.7580e-04 1.5305e-02 -6.0000e+00 1.8857e-02 -7.0328e-03 3.5062e-04 7.4282e-03 -6.0000e+00 1.1197e-02 -7.9462e-04 1.7491e-04 2.0601e-03 -6.0000e+00 4.7185e-03 9.7390e-03 4.6930e-04 1.0528e-05 2.1375e-05 -6.0000e+00 3.1830e-04 2.6048e-02 12 1 1 12 1 1 99.98 26.21 0.30 0.02605 0.02957 536 76 1 5 0 72.610 34.50 20.00 26.21 31.69 3.8 1008.84 -1628 -1904 -897 -4670 -4804 -3746 -2111 -353 -1230 -2392 -4205 -2793 -1578 -903 126 -347 41 491 593 1255 291 62 1027 882 9 540 -203 -1352 -1508 -97 751 779 1383 -1669 -3468 -2573 -2386 -1208 -531 -462 -903 -700 -358 -688 126 -111 -267 -195 -740 184 982 644 1075 1411 1102 1364 1040 565 356 512 1110 1552 1913 2087 206 -437 -433 -688 683 412 354 614 331 655 -24 -406 -743 -1447 -585 -1085 -1221 -1238 -2196 -1540 -862 -574 -156 191 632 485 342 39 -244 51 62 -61 389 1049 190 -318 -447 -879 -680 -40 -831 -1081 -780 -658 -58 358 595 359 450 175 -67 59 109 83 392 128 -174 271 592 391 696 216 199 921 452 91 13 -247 -351 -98 -9 -162 11 403 130 -124 -153 -580 -592 -141 -183 -88 -448 -409 -303 -180 -33 -131 -273 -485 -329 -209 -139 22 -68 9 106 133 292 70 15 248 207 2 140 -53 -336 -385 -24 202 208 403 -519 -1022 -735 -749 -439 -232 -217 -467 -378 -199 -387 70 -62 -147 -106 -398 99 560 398 702 897 728 918 717 389 240 342 762 1146 1540 1672 168 -356 -329 -515 542 347 327 590 317 601 -20 -336 -559 -1048 -445 -947 -1119 -1258 -2247 -1638 -978 -653 -186 234 772 569 396 42 -254 52 63 -70 460 1374 250 -413 -576 -1041 -807 -49 -1051 -1442 -1022 -904 -84 521 916 561 678 261 -92 80 150 112 569 199 -259 417 884 560 941 298 260 1212 646 132 20 -370 -537 -156 -15 -274 19 708 230 -213 -253 -974 -972 SS 20240623T143027.5Z 8940.604485 257 1 8.54 2 64.16 78.87 101.26 244.73 0.00 1 0.00 1 0 17 1.122e-02 6.484e-03 3.518e-03 1.341e-03 2.958237e-01 6.769131e-04 3.355582e-03 -6.000000e+00 6.412987e-03 231.52 -2.00 3.37 -2.00 316.80 0.00e+00 5.290244e-04 8.585736e-05 8.387695e-05 -6.000000e+00 2.801819e-04 282.70 -2.00 20.00 -2.00 316.08 0.00e+00 2.280 0.000 302.00 328.00 3 2.8504e+00 1.7853e-03 2.4335e-02 -6.0000e+00 1.6082e-02 2.4398e-02 1.9992e-03 1.4706e-02 -6.0000e+00 1.7431e-02 -8.6988e-03 1.1749e-03 7.1383e-03 -6.0000e+00 1.0350e-02 7.5233e-04 5.6482e-04 1.9960e-03 -6.0000e+00 4.3613e-03 3.0491e-03 4.3770e-04 3.6761e-05 2.1322e-05 -6.0000e+00 2.9425e-04 2.6589e-02 12 9 1 12 1 1 98.03 26.23 0.33 0.02659 0.02988 26 17 1 5 0 315.920 34.50 20.00 26.23 32.19 3.9 1012.49 -1544 -1043 -917 -4686 -4010 -4118 -1781 -2135 -545 -2699 -1903 -764 -338 -456 782 -152 -422 1125 1103 1836 -884 557 1143 1176 202 965 93 -1542 -657 -149 1669 1145 1598 -1773 -3398 -1686 -1564 -1370 -297 -130 -981 -345 -665 -949 344 -216 -183 228 -579 139 1051 564 1058 1212 1134 1180 788 404 448 335 1116 1401 1805 1604 395 -664 -470 -687 1034 201 336 477 277 620 -129 -661 -373 -995 -468 -929 -1248 -1245 -2338 -1513 -1182 -694 -184 119 526 571 468 -19 -92 145 128 -168 364 799 253 -305 -371 -860 -470 233 -918 -894 -839 -659 -58 365 495 333 512 164 -22 231 224 177 317 -47 -249 381 505 399 734 321 291 871 498 92 108 -206 -372 -88 25 -18 -2 580 -37 -258 -283 -604 -672 -213 -143 -130 -644 -533 -526 -237 -321 -82 -439 -303 -124 -62 -98 191 -42 -111 305 313 537 -271 166 348 381 70 344 34 -529 -208 -47 552 415 632 -691 -1354 -646 -607 -621 -150 -71 -595 -217 -434 -627 224 -141 -118 143 -361 87 692 377 747 904 823 873 597 306 331 246 840 1135 1502 1434 356 -557 -388 -557 884 187 324 478 276 592 -121 -559 -301 -774 -383 -821 -1182 -1241 -2514 -1687 -1343 -803 -223 149 654 681 539 -22 -94 152 135 -189 434 1010 341 -404 -460 -1023 -550 281 -1169 -1145 -1124 -885 -81 526 727 495 761 237 -31 300 292 242 446 -68 -365 545 731 554 1003 421 377 1138 675 129 159 -302 -555 -137 40 -30 -3 970 -62 -423 -463 -952 -1036 SS 20240623T143407.4Z 8940.607030 260 1 5.91 2 63.43 79.34 101.90 245.20 0.00 1 0.00 1 0 17 1.406e-02 6.835e-03 5.474e-03 2.177e-03 2.875291e-01 1.100563e-03 3.257919e-03 -6.000000e+00 8.038540e-03 231.52 -2.00 3.37 -2.00 316.71 0.00e+00 6.248638e-04 1.362110e-04 7.927324e-05 -6.000000e+00 3.512098e-04 282.70 -2.00 20.00 -2.00 315.98 0.00e+00 2.223 0.000 302.00 328.00 3 3.4403e+00 2.8983e-03 2.3687e-02 -6.0000e+00 2.0158e-02 2.3994e-02 3.2456e-03 1.4278e-02 -6.0000e+00 2.1850e-02 -7.5076e-03 1.8996e-03 6.9254e-03 -6.0000e+00 1.2974e-02 8.4712e-04 9.0658e-04 1.9473e-03 -6.0000e+00 5.4667e-03 1.7942e-03 3.2484e-04 5.9912e-05 2.0603e-05 -6.0000e+00 3.6885e-04 2.6763e-02 12 9 1 12 1 1 44.03 26.26 0.30 0.02676 0.02920 9 9 1 5 0 590.840 34.50 20.01 26.26 32.61 3.8 1015.49 -3242 -2843 -505 -4165 -5799 -6234 -2097 -1494 311 -3692 -5373 -1267 -2662 865 2355 314 481 859 1714 1367 -303 928 997 2194 -209 813 1138 -1431 -1017 431 1151 1080 2375 -1115 -2817 -2578 -1812 -813 -354 -181 -688 -620 -851 -544 372 -277 -296 41 -401 541 799 343 625 1121 1051 981 552 602 815 273 1078 1264 1850 2008 -54 -626 -668 -706 914 263 251 932 174 614 -549 -208 -210 -983 -546 -1177 -978 -929 -2493 -1727 -1102 -787 -391 105 714 556 127 338 231 -8 295 -47 477 861 172 -486 -317 -1040 -194 -18 -887 -895 -829 -573 -264 267 345 322 327 65 -20 141 237 404 556 133 -156 461 488 585 1135 463 -34 934 279 -156 23 -67 -233 89 36 -127 46 429 -71 -180 -344 -557 -725 -440 -423 -76 -605 -832 -862 -296 -236 49 -639 -932 -217 -526 191 590 82 131 243 501 417 -96 286 314 726 -75 299 417 -505 -332 138 393 401 952 -441 -1139 -1016 -718 -373 -181 -109 -423 -397 -564 -363 245 -184 -193 26 -252 340 532 231 445 841 814 730 421 456 603 214 814 1029 1543 1791 -49 -525 -552 -571 779 243 241 925 173 584 -517 -185 -169 -807 -444 -1033 -915 -962 -2657 -1909 -1237 -945 -470 129 877 657 146 370 244 -9 307 -52 584 1118 228 -634 -403 -1278 -223 -21 -1111 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