File name: Pandora254s1_TubaCityAZ_20241003_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20241004T071938.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20241003_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20241003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241003T135309.7Z 9042.578585 48 1 54.62 2 84.63 99.31 94.13 98.40 0.00 1 0.00 1 0 25 5.286e-01 2.105e-02 5.122e-01 1.678e-02 9.559922e-01 9.778553e-03 9.902782e-03 -6.000000e+00 3.030311e-01 226.75 -2.00 3.37 -2.00 322.48 0.00e+00 3.682731e-03 6.201203e-03 2.792619e-03 -6.000000e+00 1.414157e-02 280.62 -2.00 20.00 -2.00 322.06 0.00e+00 9.339 0.013 302.00 328.00 3 7.2766e-01 4.1278e-02 9.4110e-02 -6.0000e+00 7.5694e-01 9.8180e-01 5.9285e-02 5.3362e-02 -6.0000e+00 8.2863e-01 -1.2578e+00 5.7107e-02 2.9266e-02 -6.0000e+00 4.8668e-01 4.8398e-01 2.5697e-02 1.1636e-02 -6.0000e+00 2.0471e-01 3.9155e-05 1.1899e-04 4.5066e-04 1.8999e-04 -6.0000e+00 1.4707e-02 1.9459e-02 12 8 8 10 0 0 33.02 25.14 0.78 0.01946 0.02035 64 6 1 5 0 853.250 33.75 20.00 25.14 19.11 3.6 922.20 -127990 -18390 -16031 900000 -188500 -217960 60609 900000 -136103 -63770 900000 -91217 -212309 -21028 -15747 -58379 -71559 -29805 204603 900000 -55461 -24997 126027 201480 10739 96895 66009 3259 -45621 25067 32103 -74864 -1495 28434 900000 900000 5234 -18244 46335 900000 17671 56643 110722 8415 39836 65647 18020 59117 -15323 11440 11174 14754 6682 32668 73628 15569 3638 20954 2139 18799 30063 7759 8158 41710 30777 35729 -5293 15696 4 30340 12305 21909 24679 6075 5959 1107 4297 -9375 4759 -1614 -4920 5212 14106 -2163 -525 4645 -3670 -823 1560 10118 -687 -3521 365 -1680 -8400 2563 1668 -3218 489 -1147 88 -3460 -4564 -5121 -2719 -1535 -392 -1464 481 -527 31 -691 757 -2095 -2415 -1890 1429 1046 818 -224 -355 1156 2255 1966 1209 1588 1213 1589 704 -788 762 -985 371 -199 -434 539 -1029 1952 1526 -960 -477 589 -2881 -2091 -300 -262 900000 -3337 -4748 990 900000 -2224 -1042 900000 -1490 -8199 -344 -257 -954 -1488 -487 3343 900000 -1071 -408 2059 3292 175 1583 1079 53 -745 410 525 -2780 -31 465 900000 900000 101 -515 826 900000 551 1262 1809 312 1065 1365 616 1405 -819 510 564 811 437 1795 2843 1110 297 1401 162 1145 1652 588 715 3036 2697 3269 -744 1898 1 4115 2192 3651 3871 1052 915 157 562 -1486 770 -343 -1294 1448 3987 -763 -194 1723 -1541 -343 630 3587 -253 -1265 126 -640 -4021 1323 1036 -2471 402 -965 68 -2459 -2909 -3255 -1817 -1071 -288 -1189 435 -564 37 -935 1042 -2941 -3283 -2485 1854 1436 1190 -338 -517 1560 2889 2454 1476 1882 1412 1994 1059 -1410 1521 -2186 873 -507 -1199 1550 -3050 5683 4417 -2686 -1222 1375 -6674 SS 20241003T140443.6Z 9042.586616 51 1 54.59 2 82.33 101.07 91.91 100.08 0.00 1 0.00 1 0 17 7.218e-01 8.831e-03 1.999e-01 2.776e-03 7.837432e-01 1.508538e-03 8.583145e-03 -6.000000e+00 4.057596e-01 226.75 -2.00 3.37 -2.00 321.75 0.00e+00 4.449526e-03 8.306052e-04 4.107956e-03 -6.000000e+00 1.786508e-02 280.61 -2.00 20.00 -2.00 321.25 0.00e+00 6.981 0.005 302.00 328.00 3 6.0770e-01 5.4543e-03 7.2774e-02 -6.0000e+00 1.0067e+00 1.4200e-01 8.6391e-03 4.6250e-02 -6.0000e+00 1.0951e+00 -1.8316e-01 9.7424e-03 2.8099e-02 -6.0000e+00 6.5199e-01 6.4393e-02 4.4295e-03 1.0417e-02 -6.0000e+00 2.7730e-01 3.8037e-04 1.3994e-04 7.2899e-05 1.3931e-04 -6.0000e+00 1.8901e-02 1.9171e-02 11 8 0 10 0 0 13.23 25.16 0.38 0.01917 0.02022 238 24 1 5 0 229.340 33.75 20.00 25.16 19.41 3.6 924.02 -278277 -306777 -266202 -214970 -236104 -198638 -177567 106178 -256807 -188818 -220024 -201174 -102796 -138809 -108012 -105366 -79042 -32381 -40707 -7715 -64870 -57565 -22511 -62701 -40956 -49877 -66986 -52509 -56110 77 -4993 -13600 -13501 -15739 -29843 -7560 -25920 1766 -7013 -5825 -6920 -2229 -8588 2966 10799 5313 432 2272 3842 -2245 3621 7130 6791 3243 12075 9702 2153 -355 2198 990 1921 4508 2378 4393 4156 786 4793 2492 5301 3862 2882 3470 1892 4197 797 -1988 -2142 -1459 -1861 1054 -835 155 -1276 -1511 -552 407 698 1476 663 1159 477 -283 -1109 -1782 -1589 -1022 -102 645 824 -528 -953 -1385 -1241 -998 -1679 -1369 -1435 -1120 -419 649 245 226 512 23 -199 -386 -151 223 371 424 295 587 1205 563 720 40 -262 705 265 133 60 -314 -377 -118 -48 -477 174 618 278 47 -272 -439 -212 -2123 -3775 -2424 -1164 -1453 -831 -655 287 -2718 -1115 -1895 -1683 -430 -1127 -851 -1011 -681 -199 -301 -44 -670 -552 -161 -741 -423 -601 -989 -659 -732 1 -61 -225 -267 -349 -735 -147 -674 42 -224 -224 -307 -103 -449 143 491 265 23 129 230 -156 271 587 623 341 1245 1074 266 -45 262 117 232 593 372 778 793 154 908 508 1175 1014 847 1059 577 1171 208 -477 -486 -341 -503 336 -322 69 -635 -801 -310 241 433 934 422 705 272 -153 -591 -1007 -1029 -777 -91 658 924 -601 -1017 -1323 -1064 -854 -1563 -1341 -1488 -1252 -517 823 353 349 798 35 -289 -541 -214 331 581 685 466 881 1729 786 967 58 -366 1037 412 237 119 -673 -857 -286 -125 -1203 442 1592 714 127 -679 -1025 -477 SS 20241003T142238.3Z 9042.599054 56 1 54.52 2 78.80 103.84 88.50 102.71 0.00 1 0.00 1 0 17 2.586e-01 5.960e-03 2.813e-02 7.453e-04 5.933352e-01 3.819063e-04 6.432419e-03 -6.000000e+00 1.453490e-01 226.74 -2.00 3.37 -2.00 320.63 0.00e+00 2.081570e-03 1.546951e-04 1.174191e-03 -6.000000e+00 6.399506e-03 280.61 -2.00 20.00 -2.00 320.04 0.00e+00 4.976 0.002 302.00 328.00 3 4.3455e-01 1.1878e-03 5.1314e-02 -6.0000e+00 3.6062e-01 2.2373e-02 1.5472e-03 3.0191e-02 -6.0000e+00 3.9229e-01 -2.0630e-02 1.5374e-03 1.6281e-02 -6.0000e+00 2.3355e-01 -1.6579e-03 7.6454e-04 5.6734e-03 -6.0000e+00 9.9332e-02 2.7102e-03 2.0594e-04 2.0319e-05 6.1966e-05 -6.0000e+00 6.7706e-03 1.9160e-02 10 0 0 10 0 0 13.91 25.15 0.32 0.01916 0.02071 691 70 1 5 0 78.890 33.75 20.00 25.15 20.28 3.6 929.71 -110108 -84939 -70873 -90010 -96605 -100480 -87628 -67906 -72590 -66925 -67298 -61882 -46206 -30024 -28831 -22994 -21133 -22601 -17182 -15517 -19310 -18056 -13880 -9960 -14883 -14905 -11443 -16235 -18611 -12011 -7301 -5346 -2153 -4247 -8364 -7038 -6124 -5596 -3839 -1771 -1759 -1357 430 479 274 2022 -441 653 -6 678 1187 713 1652 1952 2308 2591 1631 1088 510 776 1698 2211 2971 3340 1373 709 106 -268 735 544 1001 1009 789 561 -258 -922 -1498 -2329 -1251 -1085 -1124 -870 -2044 -1608 -822 -237 236 629 943 1072 701 237 -191 -387 -190 -340 241 1048 414 -133 -484 -920 -722 -284 -1202 -1357 -1117 -767 -90 388 530 377 302 101 -259 -30 138 32 255 -36 -151 391 652 358 358 -151 -147 868 373 -71 -51 -231 -399 -144 -114 -250 81 539 249 -60 -69 -373 -213 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