File name: Pandora159s1_Wakkerstroom_20240712_L2Fit_fout2c3d20201207p1-8.txt File generation date: 20240712T221144.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Refilwe Kai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 159 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora159_OF_v6d20191004.txt Instrument calibration file used: Pandora159s1_CF_v3d20201207.txt Level 1 file used: Pandora159s1_Wakkerstroom_20240712_L1_smca1c3d20201207p1-8.txt Full location name: Global Change Institute, University of Witwatersrand field site in Wakkerstroom Short location name: Wakkerstroom Country of location: South Africa Location latitude [deg]: -27.3493 Location longitude [deg]: 30.1438 Location altitude [m]: 1760 Local noon date: 20240712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0731 305.2139 305.3547 305.4955 305.6363 305.7770 305.9178 306.0585 306.1992 306.3399 306.4806 306.6213 306.7620 306.9026 307.0433 307.1839 307.3246 307.4652 307.6058 307.7464 307.8869 308.0275 308.1681 308.3086 308.4492 308.5897 308.7302 308.8707 309.0112 309.1517 309.2921 309.4326 309.5730 309.7135 309.8539 309.9943 310.1347 310.2751 310.4155 310.5558 310.6962 310.8365 310.9769 311.1172 311.2575 311.3978 311.5381 311.6784 311.8186 311.9589 312.0991 312.2393 312.3795 312.5198 312.6599 312.8001 312.9403 313.0805 313.2206 313.3607 313.5009 313.6410 313.7811 313.9212 314.0612 314.2013 314.3414 314.4814 314.6214 314.7615 314.9015 315.0415 315.1814 315.3214 315.4614 315.6013 315.7413 315.8812 316.0211 316.1610 316.3009 316.4408 316.5807 316.7205 316.8604 317.0002 317.1400 317.2798 317.4196 317.5594 317.6992 317.8389 317.9787 318.1184 318.2582 318.3979 318.5376 318.6773 318.8170 318.9566 319.0963 319.2359 319.3756 319.5152 319.6548 319.7944 319.9340 320.0736 320.2131 320.3527 320.4922 320.6318 320.7713 320.9108 321.0503 321.1898 321.3292 321.4687 321.6081 321.7476 321.8870 322.0264 322.1658 322.3052 322.4446 322.5839 322.7233 322.8626 323.0019 323.1413 323.2806 323.4199 323.5591 323.6984 323.8377 323.9769 324.1162 324.2554 324.3946 324.5338 324.6730 324.8121 324.9513 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Spectrometer control temperature [°C], 999=no temperature signal Column 94: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 95: Temperature in head sensor [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240712T051542.9Z 8959.219246 48 1 49.95 2 85.50 62.50 135.13 120.44 0.00 1 0.00 1 0 17 5.708e-01 3.765e-02 4.891e-01 3.005e-02 9.147789e-01 1.809295e-02 8.641750e-03 -6.000000e+00 3.341778e-01 225.43 -2.00 3.06 -2.00 322.44 0.00e+00 1.633246e-02 9.745646e-03 9.379671e-03 -6.000000e+00 1.600338e-02 276.82 -2.00 20.00 -2.00 322.00 0.00e+00 10.658 0.007 302.00 328.00 3 2.0616e-01 6.8168e-02 1.1886e-01 -6.0000e+00 8.2993e-01 1.4629e+00 8.6209e-02 1.0719e-01 -6.0000e+00 9.1062e-01 -1.7472e+00 7.0146e-02 2.9767e-02 -6.0000e+00 5.3622e-01 6.6698e-01 3.4432e-02 1.6056e-02 -6.0000e+00 2.2946e-01 2.7119e-05 -2.7357e-03 8.6708e-04 1.1550e-04 -6.0000e+00 1.6590e-02 1.3683e-02 12 8 8 10 0 0 62.64 18.48 0.93 0.01368 -0.00687 38 8 4 8 0 1314.360 15.00 18.48 11.77 20.96 20.96 25.8 809.57 166249 900000 -21803 900000 -115300 900000 -53418 900000 -55314 -63621 -153329 900000 -36016 900000 -397 81868 30341 -585 900000 -783 900000 -6545 97093 900000 11736 -21965 137748 -4159 -69218 -22664 255332 900000 1460 900000 -32791 900000 72553 900000 114999 900000 152418 91116 900000 -10942 900000 58240 900000 44410 900000 -10720 39529 61779 226040 59476 64969 60273 65156 59360 16332 56211 -1470 184965 32132 89159 -16659 66882 20764 17024 83897 7635 22769 14374 53259 -9810 24929 -12736 55199 -14560 2521 -9277 -13514 2016 3920 17767 -4052 15488 -8478 3456 -216 18727 -5579 -2439 -1010 1229 5580 -3084 -4191 -223 -603 -4497 545 -4587 3570 -4391 -2266 -8262 6214 1409 163 -61 -5573 -2436 -6735 1816 -2357 4973 -2380 4401 -1874 -652 2211 3767 6470 -1894 2345 3 3170 1691 70 -578 3171 -1826 2416 -1170 666 601 -921 2491 -2743 2689 -1974 -129 -2075 4854 900000 -797 900000 -7534 900000 -1560 900000 -1615 -1858 -9142 900000 -1052 900000 -13 2390 919 -25 900000 -33 900000 -245 2835 900000 343 -778 4022 -121 -3473 -812 7455 900000 70 900000 -2034 900000 2118 900000 3358 900000 4450 2660 900000 -833 900000 2256 900000 2103 900000 -977 2427 3363 6600 3753 3965 3849 3891 3578 1409 3165 -149 5400 3002 5461 -3041 5389 2615 2323 6585 1434 3967 2769 6742 -2096 3362 -2193 4686 -2562 443 -2220 -3998 593 1236 5181 -1540 5127 -3694 1364 -88 6088 -2143 -863 -348 445 2268 -1626 -2671 -160 -480 -3745 405 -3181 2048 -2698 -1460 -5992 4145 1077 142 -62 -6861 -3171 -9428 2308 -3014 5796 -3045 5559 -2676 -945 3028 4830 7732 -2398 2787 4 3561 2076 102 -1001 5936 -3918 5329 -2864 1722 1634 -2588 6840 -7880 7004 -4969 -294 -4633 SS 20240712T052927.3Z 8959.228788 51 1 49.77 2 82.82 60.77 132.53 117.61 0.00 1 0.00 1 0 25 5.141e-01 7.891e-03 2.439e-01 3.757e-03 7.244949e-01 2.031952e-03 6.952270e-03 -6.000000e+00 2.889723e-01 225.43 -2.00 3.06 -2.00 321.68 0.00e+00 6.180661e-03 1.080012e-03 3.731782e-03 -6.000000e+00 1.362216e-02 276.82 -2.00 20.00 -2.00 321.21 0.00e+00 7.391 0.002 302.00 328.00 3 2.7093e-01 7.1990e-03 7.2898e-02 -6.0000e+00 7.1675e-01 1.3822e-01 1.0896e-02 4.8580e-02 -6.0000e+00 7.8185e-01 -1.2573e-01 1.2371e-02 1.9357e-02 -6.0000e+00 4.6394e-01 3.7981e-02 5.7292e-03 9.1527e-03 -6.0000e+00 1.9719e-01 4.8992e-04 -1.3199e-03 1.0502e-04 7.1396e-05 -6.0000e+00 1.3774e-02 1.3608e-02 11 8 0 10 0 0 79.37 18.48 0.34 0.01361 0.00369 194 42 4 8 0 253.900 15.00 18.48 13.43 20.96 20.96 26.4 821.91 -158855 -149834 -182001 -189615 -231998 -143016 -220738 -181464 -134300 900000 -155254 900000 -98159 1315 -46878 -2662 -35062 -71429 -35955 -63462 -9079 -58139 -3671 -55981 21151 -44974 -10746 -8719 -39476 -8008 -33400 -13826 -38053 -30255 -14548 2742 -6353 7388 -3666 10536 1153 4498 7231 465 1431 -11942 8624 -3773 10030 1733 8577 -697 9765 4878 1411 1737 2425 2643 1227 3232 3769 4342 2736 6748 -422 4874 -632 4924 3637 245 3424 -176 -378 425 465 -3951 2952 -882 755 455 -484 -1188 -1888 -1868 -2053 -868 -1036 -409 -512 1236 906 2779 675 1485 1126 -123 646 203 -308 -275 177 -93 1062 -131 -1070 -1532 -1794 -452 -281 -311 -636 -305 -60 515 465 1224 486 507 -208 -702 -472 113 -228 -460 656 -68 1685 1199 439 206 192 -30 299 426 -439 -481 96 -113 -746 238 -166 251 306 -640 -659 -1091 -1320 -2086 -576 -1911 -1329 -689 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3.7274e-03 6.2735e-02 -6.0000e+00 4.7760e-01 7.0361e-02 5.2909e-03 3.8129e-02 -6.0000e+00 5.2066e-01 -4.0394e-02 5.8006e-03 1.6782e-02 -6.0000e+00 3.0963e-01 3.6040e-03 2.7628e-03 6.5594e-03 -6.0000e+00 1.3118e-01 1.1818e-03 -1.1709e-03 5.8890e-05 6.1346e-05 -6.0000e+00 9.1766e-03 1.3436e-02 10 0 0 10 0 0 76.90 18.48 0.27 0.01344 0.00464 322 69 2 8 0 153.180 15.00 18.48 15.14 20.96 20.96 27.0 830.26 -100868 -139536 -91351 -118015 -128648 -132129 -151260 -67382 -110642 -56131 -111722 -90989 -59824 -11479 -34113 -10992 -27625 -19602 -26684 -12176 -1786 -16710 -24754 -19756 -1731 -24377 -17065 -23731 -14288 -18451 -4223 -3101 -10134 2974 1866 -819 -8142 -4145 -4818 221 -4099 3867 -2467 1629 -532 729 3106 1027 916 3259 4013 2123 5826 1516 1767 1627 -342 420 948 1882 1317 1242 2558 1510 128 2101 1054 2007 444 579 -236 -299 124 -364 -88 -83 -49 -18 354 -989 197 -1207 -1805 -1295 -857 -733 -276 -222 -35 155 759 823 802 1637 891 339 819 511 -477 -308 132 -46 1171 487 -1618 -934 -805 -735 -32 -399 -501 -271 127 268 738 1258 774 535 -410 -787 -849 94 -308 -226 418 -82 1327 1403 334 154 21 -19 223 266 -334 -402 65 -170 -479 -104 76 233 361 -388 -932 -407 -669 -755 -802 -1225 -273 -784 -250 -927 -718 -448 -70 -331 -102 -347 -254 -405 -170 -23 -254 -431 -360 -29 -538 -356 -519 -286 -426 -103 -90 -336 92 62 -28 -304 -180 -261 14 -296 279 -200 131 -45 62 266 94 88 333 456 277 807 239 294 284 -63 76 166 323 237 249 581 391 35 554 278 545 137 206 -93 -123 50 -138 -30 -26 -14 -5 120 -405 93 -662 -1088 -824 -581 -528 -208 -172 -27 114 517 524 493 1039 644 286 798 524 -535 -343 136 -46 1070 455 -1667 -1011 -918 -822 -39 -551 -766 -436 204 412 1063 1729 1080 786 -646 -1291 -1375 145 -459 -325 575 -109 1836 2039 511 267 39 -39 470 597 -809 -1021 169 -448 -1259 -262 180 515 774 SS 20240712T055114.4Z 8959.243916 59 1 49.57 2 78.66 57.87 128.27 113.57 0.00 1 0.00 1 0 25 9.420e-02 5.900e-03 2.274e-02 7.758e-04 5.178421e-01 3.948617e-04 5.184756e-03 -6.000000e+00 5.293228e-02 225.43 -2.00 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