File name: Pandora177s1_WestportCT_20230718_L2Fit_fout2c3d20221101p1-8.txt File generation date: 20240313T202049.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v3d20221101.txt Level 1 file used: Pandora177s1_WestportCT_20230718_L1_smca1c3d20221101p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20230718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 360 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1790 305.3198 305.4607 305.6015 305.7423 305.8831 306.0238 306.1646 306.3054 306.4461 306.5868 306.7276 306.8683 307.0090 307.1497 307.2904 307.4310 307.5717 307.7124 307.8530 307.9936 308.1343 308.2749 308.4155 308.5561 308.6967 308.8372 308.9778 309.1184 309.2589 309.3994 309.5400 309.6805 309.8210 309.9615 310.1019 310.2424 310.3829 310.5233 310.6638 310.8042 310.9446 311.0850 311.2254 311.3658 311.5062 311.6466 311.7869 311.9273 312.0676 312.2079 312.3482 312.4885 312.6288 312.7691 312.9094 313.0497 313.1899 313.3302 313.4704 313.6106 313.7508 313.8910 314.0312 314.1714 314.3116 314.4517 314.5919 314.7320 314.8721 315.0123 315.1524 315.2925 315.4325 315.5726 315.7127 315.8527 315.9928 316.1328 316.2728 316.4129 316.5529 316.6928 316.8328 316.9728 317.1128 317.2527 317.3926 317.5326 317.6725 317.8124 317.9523 318.0922 318.2320 318.3719 318.5118 318.6516 318.7914 318.9313 319.0711 319.2109 319.3507 319.4904 319.6302 319.7700 319.9097 320.0494 320.1892 320.3289 320.4686 320.6083 320.7480 320.8876 321.0273 321.1669 321.3066 321.4462 321.5858 321.7254 321.8650 322.0046 322.1442 322.2837 322.4233 322.5628 322.7024 322.8419 322.9814 323.1209 323.2604 323.3998 323.5393 323.6788 323.8182 323.9576 324.0971 324.2365 324.3759 324.5153 324.6546 324.7940 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230718T112430.9Z 8599.475358 95 1 20.43 2 71.82 77.62 77.45 69.42 0.00 1 0.00 1 0 25 9.158e-02 1.187e-02 8.793e-02 6.155e-03 4.067305e-01 3.285274e-03 5.261642e-03 -6.000000e+00 5.558006e-02 232.84 -2.00 3.51 -2.00 319.81 0.00e+00 3.560903e-03 1.008271e-03 3.187239e-03 -6.000000e+00 2.487952e-03 289.51 -2.00 20.00 -2.00 318.98 0.00e+00 3.162 0.001 302.00 328.00 3 4.0823e+00 9.6645e-03 4.0065e-02 -6.0000e+00 1.3933e-01 2.5876e-02 1.1507e-02 2.6548e-02 -6.0000e+00 1.5057e-01 -1.7122e-02 8.5781e-03 1.3182e-02 -6.0000e+00 8.9749e-02 -4.2640e-03 4.3600e-03 3.6004e-03 -6.0000e+00 3.7188e-02 2.3106e-04 2.1977e-03 1.9987e-04 6.6401e-05 -6.0000e+00 2.7837e-03 5.2891e-02 2.2551e-04 12 9 9 12 1 1 99.90 23.21 0.23 0.05289 0.06941 8 5 1 5 0 2249.670 26.62 20.00 23.21 30.13 21.7 1055.10 -44781 11461 -26045 26926 -43545 5313 -14895 -30579 -11359 -37690 -31221 -8490 -8238 -23757 -9616 -5929 -3773 -5346 -9621 -170 1371 -9811 2358 657 -90 -7260 -13171 7074 -16312 -9771 -6796 7763 4235 -5610 -5208 -7047 2405 -3986 -308 2747 -2849 -4088 836 3159 919 -1493 474 -605 -1836 3630 4164 -216 2467 962 1690 614 1798 -27 184 1415 1984 4874 5436 3005 1683 867 -1437 -614 2163 1806 1293 346 71 1347 -1182 -1279 -2812 -2223 -580 -3926 -886 -3171 -2336 -564 165 2020 708 2003 2082 -568 359 102 -2195 -393 -1232 -320 842 -165 -434 -292 -2226 -2283 -621 99 -2211 -1751 -1313 -1356 770 1333 1353 -63 958 -573 587 -613 49 174 619 945 583 1042 1683 993 289 10 -1309 1074 210 -1248 -1039 -1145 177 -212 857 -9 614 736 427 -589 -304 -1612 331 -1219 197 -667 388 -1185 87 -322 -869 -291 -1312 -1062 -255 -293 -1198 -496 -332 -225 -347 -689 -12 94 -758 166 50 -7 -651 -1239 529 -1527 -895 -674 755 464 -691 -625 -874 302 -636 -56 559 -671 -1034 208 785 237 -398 124 -161 -503 985 1211 -71 852 355 644 243 713 -11 73 559 820 2138 2597 1562 889 441 -718 -312 1177 1101 853 237 48 856 -710 -699 -1461 -1156 -325 -2594 -643 -2595 -2036 -513 149 1908 711 2023 2074 -557 347 91 -1913 -344 -1187 -322 938 -203 -562 -371 -2678 -2539 -660 109 -2639 -2206 -1732 -1893 1132 2102 2117 -101 1569 -897 853 -871 70 262 982 1553 966 1679 2604 1490 419 13 -1805 1505 323 -2109 -1852 -2118 316 -402 1699 -19 1306 1580 914 -1239 -610 -3152 635 SS 20230718T112916.3Z 8599.478661 98 1 48.06 2 70.94 78.34 76.64 70.11 0.00 1 0.00 1 0 17 7.257e-02 1.041e-02 4.472e-02 3.355e-03 3.866425e-01 1.776779e-03 4.799844e-03 -6.000000e+00 4.400373e-02 232.84 -2.00 3.51 -2.00 319.80 0.00e+00 3.092339e-03 5.438662e-04 2.447608e-03 -6.000000e+00 1.971079e-03 289.51 -2.00 20.00 -2.00 318.97 0.00e+00 3.025 0.000 302.00 328.00 3 3.7207e+00 5.2147e-03 3.7626e-02 -6.0000e+00 1.1031e-01 2.1876e-03 6.2030e-03 2.3527e-02 -6.0000e+00 1.1924e-01 1.4347e-03 4.6121e-03 1.1682e-02 -6.0000e+00 7.1073e-02 -1.0350e-02 2.3533e-03 3.2445e-03 -6.0000e+00 2.9417e-02 3.9148e-04 9.3064e-04 1.0936e-04 5.1893e-05 -6.0000e+00 2.2065e-03 5.4421e-02 1.5500e-05 12 9 8 11 8 0 99.84 23.23 0.39 0.05442 0.06141 37 9 1 5 0 1298.580 26.62 20.00 23.23 30.64 21.8 1058.85 -16680 -37741 -1487 -29162 -1703 -24886 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-664 113 1241 1371 952 1618 905 -326 -338 -1162 -1950 -2020 -369 -1849 -1066 -2331 -1893 -1131 231 873 1232 1827 653 1713 -223 -164 -1631 -59 -230 -956 1307 707 398 -1026 -2035 -2861 -607 -186 -1856 -2685 -1614 -1027 604 2448 1618 987 390 -187 -343 -797 388 429 1281 183 1077 1200 2233 981 826 -449 -862 1199 -130 -823 -1939 -1480 -693 -121 158 -108 1263 983 1333 198 -199 -2026 -868 SS 20230718T114355.2Z 8599.488833 104 1 48.52 2 68.23 80.56 74.12 72.23 0.00 1 0.00 1 0 17 3.457e-02 9.892e-03 1.393e-02 1.606e-03 3.459483e-01 8.474433e-04 4.197671e-03 -6.000000e+00 2.095869e-02 232.84 -2.00 3.51 -2.00 319.20 0.00e+00 2.212772e-03 2.127832e-04 1.624337e-03 -6.000000e+00 9.391487e-04 289.51 -2.00 20.00 -2.00 318.32 0.00e+00 2.672 0.000 302.00 328.00 3 3.0306e+00 2.4003e-03 3.2861e-02 -6.0000e+00 5.2537e-02 -8.0659e-03 2.7882e-03 1.9494e-02 -6.0000e+00 5.6800e-02 8.2922e-03 1.9114e-03 9.5329e-03 -6.0000e+00 3.3854e-02 -1.2238e-02 9.7344e-04 2.6410e-03 -6.0000e+00 1.4008e-02 1.1647e-03 8.5564e-04 5.2268e-05 3.7919e-05 -6.0000e+00 1.0512e-03 5.5841e-02 -7.5757e-06 12 9 8 11 8 0 99.65 23.15 0.44 0.05584 0.06227 79 18 1 5 0 614.130 26.51 20.01 23.15 31.89 21.7 1066.68 -10129 -8974 -10672 -13512 -3005 -18611 -494 -3302 -5106 -12114 -11333 -9828 -6141 -3404 -3210 -2485 -172 1281 1221 2346 -225 -2424 637 -2563 -121 -427 -1779 -3395 180 -3613 478 906 -1229 -3931 -7169 -5223 -4560 -769 -852 -770 -1402 -1107 -270 172 1284 275 885 -141 243 37 505 951 1370 1739 470 1330 12 -100 -494 56 1749 2863 3108 2799 557 -705 -475 161 2601 1648 1014 1476 465 774 -701 -1402 -2517 -2662 -1461 -2184 -2190 -2655 -2754 -1315 14 590 1363 1489 1720 1418 252 -596 -1415 -282 -405 -432 299 1008 -57 -935 -1721 -2126 -638 -571 -1503 -1978 -1067 -652 739 1460 1000 479 284 -203 -328 -79 245 524 775 220 595 624 1163 561 821 -512 -491 484 -202 -500 -997 -1347 -319 126 292 233 578 826 654 -42 -356 -1083 -287 -351 -336 -411 -508 -95 -673 -16 -125 -214 -567 -543 -505 -354 -227 -247 -210 -15 119 119 235 -24 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