File name: Pandora177s1_WestportCT_20230804_L2Fit_fwvt1c3d20221101p1-8.txt File generation date: 20230805T161633.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v3d20221101.txt Level 1 file used: Pandora177s1_WestportCT_20230804_L1_smca1c3d20221101p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20230804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0444 492.1655 492.2866 492.4076 492.5286 492.6497 492.7707 492.8916 493.0126 493.1336 493.2545 493.3754 493.4963 493.6172 493.7381 493.8589 493.9797 494.1005 494.2213 494.3421 494.4629 494.5836 494.7043 494.8251 494.9457 495.0664 495.1871 495.3077 495.4283 495.5489 495.6695 495.7901 495.9107 496.0312 496.1517 496.2722 496.3927 496.5132 496.6336 496.7541 496.8745 496.9949 497.1152 497.2356 497.3560 497.4763 497.5966 497.7169 497.8372 497.9574 498.0777 498.1979 498.3181 498.4383 498.5585 498.6786 498.7988 498.9189 499.0390 499.1591 499.2792 499.3992 499.5192 499.6393 499.7593 499.8792 499.9992 500.1192 500.2391 500.3590 500.4789 500.5988 500.7186 500.8385 500.9583 501.0781 501.1979 501.3177 501.4374 501.5572 501.6769 501.7966 501.9163 502.0360 502.1556 502.2752 502.3949 502.5145 502.6340 502.7536 502.8732 502.9927 503.1122 503.2317 503.3512 503.4706 503.5901 503.7095 503.8289 503.9483 504.0677 504.1870 504.3064 504.4257 504.5450 504.6643 504.7835 504.9028 505.0220 505.1412 505.2604 505.3796 505.4988 505.6179 505.7371 505.8562 505.9753 506.0943 506.2134 506.3324 506.4515 506.5705 506.6894 506.8084 506.9274 507.0463 507.1652 507.2841 507.4030 507.5219 507.6407 507.7595 507.8783 507.9971 508.1159 508.2347 508.3534 508.4721 508.5908 508.7095 508.8282 508.9468 509.0655 509.1841 509.3027 509.4213 509.5398 509.6584 509.7769 509.8954 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230804T135921.3Z 8616.582886 328 1 48.04 2 45.33 108.11 99.29 269.22 0.00 1 0.00 1 0 15 3.665e-03 3.669e-03 1.451e-03 1.445e-03 3.487592e+03 1.015088e+02 2.193972e+02 -6.000000e+00 2.325349e+02 289.90 -2.00 20.00 -2.00 505.20 0.00e+00 4.596766e-04 4.212920e-05 2.849316e-05 -6.000000e+00 1.095712e-04 289.90 -2.00 20.00 -2.00 500.29 0.00e+00 -6.059613e-02 3.029631e-02 2.774029e-02 -6.000000e+00 7.674810e-02 232.23 -2.00 3.51 -2.00 501.88 0.00e+00 1.420 0.000 489.00 513.00 1 7.5655e+00 2.3407e-03 3.1439e-03 -6.0000e+00 5.9427e-03 8.2894e-03 5.8476e-04 6.1454e-04 -6.0000e+00 1.4846e-03 8.2340e-04 -1.7549e-04 1.9531e-04 1.2466e-05 -6.0000e+00 5.1868e-04 5.1636e-02 -7.6471e-05 10 0 0 10 0 0 99.89 23.50 1.88 0.05164 0.05042 20 5 1 4 0 2401.470 26.83 20.00 23.50 27.04 21.7 1031.08 -231 -79 -146 -224 -64 -253 281 482 580 38 99 -359 -102 -391 -763 -29 -104 374 -103 40 -29 240 607 451 754 193 267 59 -501 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376 48 -12 184 170 484 286 740 455 263 437 311 856 484 449 378 191 173 264 209 -93 -215 -120 -535 -308 -242 50 -469 -151 -490 338 -363 323 -60 322 -68 -352 -176 -355 82 SQ 20230804T140353.3Z 8616.586034 331 1 48.89 2 44.52 109.13 100.10 269.95 0.00 1 0.00 1 0 15 3.104e-03 3.109e-03 1.045e-03 1.040e-03 3.131522e+03 7.368456e+01 2.051844e+02 -6.000000e+00 1.969750e+02 289.90 -2.00 20.00 -2.00 505.26 0.00e+00 3.989901e-04 3.041173e-05 2.504588e-05 -6.000000e+00 9.281758e-05 289.90 -2.00 20.00 -2.00 500.28 0.00e+00 -6.847304e-02 2.198417e-02 2.410676e-02 -6.000000e+00 6.502184e-02 232.23 -2.00 3.51 -2.00 501.89 0.00e+00 1.401 0.000 489.00 513.00 1 7.0280e+00 1.7031e-03 2.8971e-03 -6.0000e+00 5.0345e-03 9.2920e-03 4.2182e-04 5.5244e-04 -6.0000e+00 1.2580e-03 1.4166e-03 -2.0705e-04 1.4150e-04 1.0505e-05 -6.0000e+00 4.3939e-04 5.3556e-02 -1.0445e-04 10 0 0 10 0 0 99.92 23.53 1.87 0.05356 0.05212 43 10 1 4 0 1136.880 26.94 20.01 23.53 27.26 21.8 1032.82 -401 -63 -71 -193 -118 231 296 267 206 252 292 -83 -108 -301 -397 -215 -296 205 30 -47 -111 152 422 592 535 253 55 -56 -292 -549 -47 86 280 440 -77 -339 -546 -178 -18 121 183 141 308 472 495 275 215 24 29 -395 -663 -322 -581 -102 -292 -332 -365 -413 -179 -196 582 494 365 151 150 216 -29 -37 232 -17 51 -51 32 204 -242 -337 -507 -384 0 -129 -327 -314 -343 -456 -231 -332 -153 -274 74 96 372 509 485 321 85 9 -41 -134 -138 -451 -274 -460 156 -474 -452 -879 -357 -316 192 52 281 95 -38 97 530 452 344 496 354 356 445 327 636 327 196 388 15 50 236 276 36 -317 -406 -186 -329 -47 97 -352 -320 -184 -38 49 329 108 177 -76 -198 -202 -229 -13 -405 -64 -69 -194 -122 242 314 285 219 266 305 -85 -111 -305 -401 -218 -304 214 32 -51 -120 165 456 640 578 273 59 -59 -304 -564 -48 87 288 461 -82 -366 -589 -190 -19 127 192 148 327 504 530 295 229 25 30 -402 -661 -315 -567 -99 -292 -338 -378 -433 -188 -206 608 518 382 158 155 222 -29 -37 229 -17 50 -50 32 202 -241 -334 -498 -373 0 -124 -315 -305 -335 -450 -230 -314 -145 -261 70 92 357 491 470 311 82 9 -38 -122 -131 -426 -259 -418 144 -450 -436 -855 -344 -303 183 49 271 93 -38 97 528 453 345 496 352 350 432 315 607 313 188 371 14 48 225 261 33 -296 -376 -171 -303 -44 91 -338 -311 -180 -37 49 326 107 174 -74 -192 -193 -216 -12 SQ 20230804T142341.4Z 8616.599785 343 1 19.83 2 41.06 113.87 103.63 273.19 0.00 1 0.00 1 0 15 3.327e-03 3.339e-03 1.255e-03 1.252e-03 2.865949e+03 8.704475e+01 1.891919e+02 -6.000000e+00 2.111049e+02 289.90 -2.00 20.00 -2.00 505.25 0.00e+00 3.947296e-04 3.660979e-05 2.500463e-05 -6.000000e+00 9.947425e-05 289.90 -2.00 20.00 -2.00 500.34 0.00e+00 -5.171551e-02 2.620811e-02 2.187906e-02 -6.000000e+00 6.967921e-02 232.23 -2.00 3.51 -2.00 501.96 0.00e+00 1.325 0.000 489.00 513.00 1 6.8174e+00 2.0231e-03 2.6991e-03 -6.0000e+00 5.3952e-03 6.2618e-03 5.0546e-04 5.0076e-04 -6.0000e+00 1.3480e-03 1.7664e-03 -3.3765e-04 1.6973e-04 1.2598e-05 -6.0000e+00 4.7089e-04 5.3821e-02 -9.6157e-05 12 1 1 12 1 1 99.99 23.48 1.89 0.05382 0.05148 18 11 1 4 0 1033.980 26.83 20.01 23.48 28.41 21.7 1040.33 -150 -17 -134 -146 -308 202 312 361 337 13 81 -160 -190 -542 -187 -337 -54 128 -63 -120 -157 312 515 488 623 498 84 -67 -245 -440 -241 -108 370 345 168 -511 -97 -31 78 347 -24 200 80 638 228 392 242 323 -75 -385 -709 -682 -524 -282 -114 -332 -369 -510 -286 -17 440 459 391 488 197 228 3 155 -84 -224 -45 215 -113 137 -263 -412 -513 -357 -233 -235 -291 -133 -526 -8 -261 -377 -149 -403 7 162 620 232 701 154 138 47 -76 5 -479 -251 -465 -266 -259 -212 -651 -994 -448 -40 68 251 245 100 177 -107 209 392 491 350 268 504 396 450 699 529 448 90 154 134 245 234 78 -199 -117 -222 -153 -67 -6 -345 -161 -171 -109 289 224 256 73 52 -185 -716 -233 -328 -145 -17 -134 -150 -325 216 338 393 366 14 86 -168 -198 -562 -193 -350 -57 137 -65 -126 -166 328 542 515 656 523 88 -69 -261 -461 -250 -112 389 353 175 -539 -101 -32 80 355 -24 206 83 664 239 411 252 331 -76 -382 -724 -685 -523 -283 -111 -331 -373 -522 -293 -17 450 470 400 497 200 229 3 152 -81 -216 -43 206 -109 132 -256 -399 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