File name: Pandora177s1_WestportCT_20230806_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T133135.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20230806_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20230806 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230806T111920.6Z 8618.471766 224 1 48.24 2 75.41 80.40 46.18 230.08 0.00 1 0.00 1 0 25 1.602e-01 1.127e-02 7.711e-02 2.733e-03 4.819511e-01 1.493647e-03 6.226919e-03 -6.000000e+00 9.732072e-02 232.16 -2.00 3.51 -2.00 320.48 0.00e+00 1.408446e-03 5.806543e-04 4.194780e-03 -6.000000e+00 4.332380e-03 289.94 -2.00 20.00 -2.00 319.78 0.00e+00 3.887 0.001 302.00 328.00 3 2.4560e+00 4.6734e-03 5.0620e-02 -6.0000e+00 2.4371e-01 -1.7656e-02 5.9062e-03 3.7333e-02 -6.0000e+00 2.6212e-01 -1.6592e-02 5.1256e-03 1.5108e-02 -6.0000e+00 1.5626e-01 5.2222e-04 2.5672e-03 3.7768e-03 -6.0000e+00 6.6862e-02 5.5010e-04 -1.4744e-04 8.5297e-05 6.3314e-05 -6.0000e+00 4.7182e-03 -6.7648e-03 0.0000e+00 12 8 8 10 0 0 99.79 23.70 0.43 -0.00676 -0.00787 103 24 1 5 0 468.310 27.05 19.96 23.70 23.02 21.5 1004.08 -72793 -30200 -24071 -33045 -67481 -47019 -58619 -48346 19943 -63587 -40966 -54185 -31597 -27106 -19205 -4810 -20980 -8388 -20524 4077 -15331 -7682 -2412 -4121 -3527 -13527 -6208 -22039 1345 -18816 -691 -7977 4633 -4022 -7561 -5922 -11578 3468 -3365 4200 -5545 3954 2611 1999 1359 -766 2547 -2088 400 -1419 3808 1962 2421 2931 900 3832 1355 1619 -2424 1944 933 2391 4746 3592 1340 -1001 -728 -2705 2832 1343 2471 1924 1063 740 -1243 -2394 -3896 -2620 -3593 -1929 -2810 -1268 -2675 -1622 449 633 2293 1326 2232 1065 1103 -1355 -2441 -1317 -971 -114 103 1831 -93 -279 -1879 -1912 -1350 -19 -1586 -2192 -1113 -1242 1147 1500 1553 949 308 -615 -898 -347 -154 676 951 396 609 839 1481 575 760 -1244 -748 -161 -74 -536 -1093 -1353 -797 4 81 71 488 1118 467 292 -277 -1242 -935 -285 -222 -320 -866 -490 -753 -644 150 -1171 -635 -1076 -605 -611 -479 -119 -671 -256 -756 136 -579 -301 -94 -177 -163 -717 -304 -1233 59 -1068 -37 -534 302 -295 -562 -440 -1021 318 -400 537 -866 599 416 327 227 -132 430 -375 72 -276 768 444 592 759 250 1072 397 470 -722 556 283 787 1692 1396 540 -398 -280 -1096 1209 656 1293 1045 574 380 -599 -1060 -1644 -1109 -1702 -1040 -1747 -864 -1996 -1276 370 555 2080 1239 2042 945 914 -1068 -1865 -1028 -835 -111 112 2179 -119 -352 -2231 -2082 -1410 -20 -1841 -2715 -1437 -1707 1671 2378 2388 1502 480 -1005 -1385 -515 -232 1062 1581 687 1055 1410 2388 903 1144 -1828 -1074 -241 -121 -974 -1933 -2502 -1533 8 174 159 1117 2570 1073 652 -592 -2559 SS 20230806T112833.7Z 8618.478168 227 1 13.25 2 73.70 81.84 47.48 232.59 0.00 1 0.00 1 0 25 1.238e-01 1.259e-02 8.090e-02 4.708e-03 4.310807e-01 2.556340e-03 5.742110e-03 -6.000000e+00 7.517472e-02 232.16 -2.00 3.51 -2.00 319.82 0.00e+00 3.452371e-03 7.927006e-04 3.261680e-03 -6.000000e+00 3.346983e-03 289.94 -2.00 20.00 -2.00 319.05 0.00e+00 3.503 0.001 302.00 328.00 3 3.2214e+00 7.4549e-03 4.3885e-02 -6.0000e+00 1.8825e-01 -1.6358e-02 8.9257e-03 2.8811e-02 -6.0000e+00 2.0248e-01 5.4472e-03 7.1046e-03 1.3635e-02 -6.0000e+00 1.2071e-01 -9.9437e-03 3.6870e-03 3.4090e-03 -6.0000e+00 5.1642e-02 3.8650e-04 -1.8400e-04 1.4646e-04 5.8675e-05 -6.0000e+00 3.6451e-03 -5.9287e-03 0.0000e+00 12 9 9 12 1 1 97.05 23.58 0.41 -0.00593 -0.00731 11 10 1 5 0 1089.320 26.94 20.01 23.58 23.45 21.5 1006.98 -68871 -9207 -14445 -44664 2360 -68474 -4641 -61340 -9477 -36794 -2531 13014 -34144 -154 -21592 26091 -13417 -701 -4696 1744 5021 2022 -4441 -3445 2465 -13334 1112 -7737 -2168 -4788 -323 1165 769 40 -15168 -3387 -7512 4628 -7773 -6941 4286 1546 4142 -2259 2813 143 -1023 234 2929 -1518 2158 890 351 1592 276 1440 926 148 -50 2963 1516 1497 3254 2035 2229 144 519 -835 2485 1767 2462 2080 87 744 -383 -722 -2899 -3924 -2175 -2849 -2242 -1822 -2645 -1200 429 -122 2345 1597 2351 1844 -19 -712 -4160 -346 -1080 -287 251 808 557 -471 -1504 -3664 -1469 -816 -1947 -1648 -993 -668 1169 1614 1272 1285 265 -305 -874 -84 41 185 1545 708 62 776 1438 1005 804 -711 -871 157 81 -661 -698 -1016 -799 269 -298 -82 375 1216 1027 36 -596 -1426 -1739 -144 -245 -984 30 -1760 -68 -1802 -183 -980 -50 245 -1238 -5 -1011 862 -721 -36 -265 97 277 116 -281 -231 166 -1090 78 -579 -152 -363 -26 108 78 4 -1810 -364 -938 614 -1402 -1431 870 343 930 -553 665 35 -256 58 727 -414 615 281 120 570 104 556 365 58 -20 1133 619 671 1584 1073 1183 75 257 -431 1373 1005 1504 1316 55 446 -236 -404 -1552 -2140 -1284 -1948 -1577 -1413 -2224 -1057 397 -121 2391 1675 2418 1828 -18 -623 -3590 -295 -1017 -303 297 1050 700 -587 -1916 -4379 -1662 -953 -2459 -2201 -1271 -903 1676 2500 2096 2153 436 -475 -1284 -118 59 278 2432 1169 103 1252 2229 1508 1159 -994 -1302 222 126 -1126 -1261 -1913 -1564 508 -601 -173 804 2617 2203 76 -1202 -2782 SS 20230806T113412.4Z 8618.482087 231 1 17.11 2 72.65 82.73 48.29 234.08 0.00 1 0.00 1 0 25 6.625e-02 1.040e-02 2.169e-02 1.622e-03 4.153903e-01 8.704308e-04 5.089976e-03 -6.000000e+00 4.023281e-02 232.16 -2.00 3.51 -2.00 319.54 0.00e+00 1.682736e-03 2.467688e-04 1.984269e-03 -6.000000e+00 1.791399e-03 289.94 -2.00 20.00 -2.00 318.75 0.00e+00 3.303 0.001 302.00 328.00 3 1.7929e+00 2.4847e-03 4.0463e-02 -6.0000e+00 1.0075e-01 -1.8827e-02 2.9360e-03 2.4377e-02 -6.0000e+00 1.0837e-01 -8.4355e-04 2.2521e-03 1.1555e-02 -6.0000e+00 6.4602e-02 -5.5538e-03 1.1797e-03 3.0189e-03 -6.0000e+00 2.7637e-02 2.0036e-03 -9.1303e-05 5.0509e-05 4.0033e-05 -6.0000e+00 1.9510e-03 -5.4952e-03 0.0000e+00 12 9 9 12 1 1 99.87 23.55 0.42 -0.00550 -0.00618 79 51 1 5 0 211.700 26.94 20.01 23.55 23.74 21.6 1009.77 -23135 -11685 -19060 -10733 -25861 -24186 -23383 -25167 -23366 -25976 -7018 -20626 -7554 -9595 -5949 -2047 -5353 -731 535 -423 -1346 316 -1822 2280 -2593 -2672 -4370 -5360 -3522 -6780 -1763 326 -1003 -5740 -6570 -5518 -3496 -2228 -210 -612 -1164 446 486 604 1450 743 229 11 -808 -102 1454 943 1760 1362 1048 1590 162 -429 -304 394 1353 2762 3385 3265 981 -883 -1525 -871 1478 1462 1529 1727 1128 1095 -265 -1998 -3036 -3170 -2051 -1978 -2194 -2138 -2227 -1550 -194 455 1799 1491 1755 1548 616 -327 -1565 -825 -673 -545 436 1217 441 -336 -1639 -2284 -866 -252 -1338 -1902 -1308 -939 883 1565 1256 630 245 -367 -556 -564 179 212 1133 471 834 848 1263 701 644 -1026 -657 175 62 -403 -1032 -1153 -571 -6 333 91 672 873 503 -85 -284 -1310 -494 -248 -446 -221 -577 -524 -547 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