File name: Pandora177s1_WestportCT_20230913_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T142307.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20230913_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20230913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230913T154025.5Z 8656.653073 245 1 7.95 2 40.47 152.92 28.48 171.02 0.00 1 0.00 1 0 17 2.334e-02 1.583e-02 1.495e-02 8.402e-03 1.816841e-01 4.467890e-03 2.234381e-03 -6.000000e+00 1.402711e-02 229.41 -2.00 3.51 -2.00 315.81 0.00e+00 1.001408e-03 4.563107e-04 2.432681e-04 -6.000000e+00 6.258917e-04 287.96 -2.00 20.00 -2.00 315.08 0.00e+00 1.313 0.000 302.00 328.00 3 5.9393e+00 1.1556e-02 1.6142e-02 -6.0000e+00 3.4913e-02 9.3789e-02 1.2809e-02 9.2882e-03 -6.0000e+00 3.7647e-02 -1.8260e-02 7.3759e-03 4.5122e-03 -6.0000e+00 2.2467e-02 2.3676e-04 3.3819e-03 1.2630e-03 -6.0000e+00 9.6438e-03 3.0334e-04 -4.9738e-04 2.5629e-04 1.7563e-05 -6.0000e+00 6.8689e-04 -3.1713e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.99 1.04 -0.00317 -0.00691 1 3 1 5 0 3971.100 26.32 20.00 22.99 29.13 22.2 1039.02 4109 2202 -3249 -2466 -12986 -4396 -2376 1298 -4011 -1726 -1378 2327 1259 -1297 4143 2561 -1112 -15 1242 3513 5033 1500 -884 1506 2802 1550 -4123 944 1550 -1422 268 3276 249 -640 -4719 -7557 -4716 -1695 -887 199 -1040 709 15 -99 1380 1914 232 -280 -948 -1515 564 591 -408 -1204 228 1418 861 -1953 -111 -615 1754 2901 2865 4929 -1305 -571 -2973 -771 1860 981 3457 544 1996 981 -437 -2972 -3446 -5116 -1966 -2526 -1772 -1782 -2224 -1823 -1358 1444 1430 790 1311 3024 1078 -937 -2396 -1705 -472 -1466 343 1613 1258 -10 -2362 -977 -1345 -1422 -1784 -1312 -787 -350 1018 2156 1406 1075 234 668 825 -997 -645 -693 1359 761 877 809 95 317 741 -76 -689 -41 -1036 -1408 -179 -1133 -680 -1002 769 316 1078 1637 1281 -932 -231 -2011 966 557 -853 -592 -3125 -989 -553 324 -1068 -486 -382 637 358 -426 1423 948 -439 -6 503 1423 2023 620 -378 653 1252 710 -1936 396 607 -559 107 1360 111 -286 -2088 -3416 -2270 -930 -567 133 -757 526 11 -76 1030 1402 168 -196 -650 -1046 397 440 -322 -987 188 1172 719 -1662 -92 -512 1481 2589 2727 4734 -1293 -515 -2527 -633 1603 945 3489 549 1968 992 -414 -2601 -2920 -4243 -1662 -2242 -1729 -1880 -2354 -2024 -1600 1765 1838 987 1698 3679 1233 -1045 -2493 -1733 -501 -1715 408 2049 1661 -14 -2922 -1109 -1596 -1671 -2253 -1742 -1083 -472 1419 3120 2107 1598 332 918 1040 -1221 -792 -895 1842 1095 1288 1171 134 427 944 -98 -857 -51 -1307 -1885 -245 -1583 -965 -1489 1121 483 1676 2568 2015 -1469 -350 -2995 SS 20230913T154924.1Z 8656.659307 251 1 20.07 2 39.75 156.21 28.31 175.53 0.00 1 0.00 1 0 17 1.581e-02 1.229e-02 1.142e-03 6.851e-04 1.683795e-01 3.643211e-04 2.063002e-03 -6.000000e+00 9.501275e-03 229.41 -2.00 3.51 -2.00 315.58 0.00e+00 7.334249e-04 3.555166e-05 1.893743e-04 -6.000000e+00 4.238158e-04 287.96 -2.00 20.00 -2.00 314.87 0.00e+00 1.299 0.000 302.00 328.00 3 2.7837e+00 9.4075e-04 1.5626e-02 -6.0000e+00 2.3649e-02 4.2737e-02 1.0423e-03 8.6250e-03 -6.0000e+00 2.5498e-02 -7.4276e-03 5.9778e-04 4.1902e-03 -6.0000e+00 1.5217e-02 -5.0950e-03 2.7067e-04 1.1673e-03 -6.0000e+00 6.5340e-03 7.5578e-03 -6.0438e-05 2.0861e-05 1.6537e-05 -6.0000e+00 4.6510e-04 -5.1699e-03 0.0000e+00 12 9 9 12 1 1 99.99 22.97 0.35 -0.00517 -0.00562 144 81 1 5 0 138.320 26.32 20.02 22.97 29.32 22.3 1040.69 2571 1131 463 -2956 -3711 -2365 -593 1067 -483 -3039 -4361 -2702 -911 293 776 189 126 1516 1691 2129 989 743 1554 2134 1925 1153 -263 -760 -627 -365 1573 1588 842 -3307 -5592 -4847 -3915 -1388 -229 -590 -535 -114 346 -48 666 362 -329 -662 -1073 -200 926 871 1059 934 362 1229 491 -252 -403 140 1208 2158 2643 2178 179 -1334 -1522 -1064 1847 1510 870 1436 1209 1303 116 -1421 -2663 -3307 -2057 -2215 -2481 -2569 -2900 -1697 -352 254 1187 1331 1692 1418 499 -674 -1604 -603 -534 -177 621 1364 633 -445 -1487 -2201 -1213 -620 -1683 -1821 -1042 -884 668 1507 1642 1231 816 126 -358 -452 -80 66 966 550 748 677 1023 667 912 -448 -866 429 94 -262 -754 -1146 -539 8 301 136 574 810 494 -114 -595 -1627 707 333 135 -820 -936 -563 -147 290 -144 -943 -1352 -843 -305 109 287 74 51 618 706 907 430 322 675 959 906 554 -124 -339 -262 -163 711 694 387 -1567 -2579 -2208 -1939 -789 -151 -403 -392 -87 265 -37 507 273 -242 -470 -811 -150 656 653 830 755 300 1027 416 -213 -337 117 1041 1969 2556 2177 177 -1224 -1287 -884 1608 1462 911 1421 1189 1331 111 -1244 -2141 -2808 -1813 -1988 -2470 -2769 -3059 -1864 -407 313 1520 1736 2174 1746 573 -765 -1688 -617 -576 -192 733 1727 835 -578 -1813 -2521 -1357 -724 -2128 -2437 -1443 -1179 918 2157 2411 1793 1129 174 -457 -551 -98 85 1320 742 1029 920 1444 905 1173 -554 -1032 511 119 -351 -1046 -1618 -773 12 437 207 892 1275 781 -177 -902 -2418 SS 20230913T161410.0Z 8656.676505 263 1 27.44 2 38.23 165.74 28.54 188.02 0.00 1 0.00 1 0 17 1.692e-02 1.269e-02 4.451e-03 2.390e-03 1.682708e-01 1.268390e-03 2.079561e-03 -6.000000e+00 1.016949e-02 229.41 -2.00 3.51 -2.00 315.93 0.00e+00 7.024730e-04 1.332640e-04 2.516368e-04 -6.000000e+00 4.536256e-04 287.96 -2.00 20.00 -2.00 315.19 0.00e+00 1.272 0.000 302.00 328.00 3 5.1552e+00 3.2906e-03 1.5410e-02 -6.0000e+00 2.5312e-02 6.9107e-02 3.6546e-03 8.6286e-03 -6.0000e+00 2.7291e-02 -7.6738e-03 2.1027e-03 4.2039e-03 -6.0000e+00 1.6287e-02 -6.5482e-03 9.6507e-04 1.1693e-03 -6.0000e+00 6.9935e-03 7.1828e-04 6.6172e-05 7.3209e-05 1.6459e-05 -6.0000e+00 4.9782e-04 -5.1237e-03 0.0000e+00 12 9 9 12 9 1 99.99 22.97 0.47 -0.00512 -0.00463 18 8 1 5 0 1443.720 26.32 20.00 22.97 29.54 22.3 1041.59 2962 -705 361 -4824 -760 -3180 374 1895 -1024 -1589 -5583 -2726 -1444 1416 695 1492 -104 1965 1281 1899 1475 660 1151 1078 2113 710 -1513 -1549 -338 496 -85 1652 717 -2433 -6437 -4880 -4356 -1559 -138 -667 50 -596 892 9 970 169 -326 -722 -1916 163 944 719 892 1532 223 2063 502 -644 -670 -109 1524 2407 3045 2032 389 -1584 -1715 -1619 1457 1871 492 2040 691 1745 -222 -1754 -2658 -3427 -2485 -2389 -2209 -2764 -2491 -1652 -107 85 1046 1061 1633 1407 336 -794 -1687 -347 -478 83 710 1210 611 -269 -1097 -2516 -1384 -697 -1718 -1676 -1168 -746 951 1726 1745 1378 879 415 -332 -985 -374 -296 538 649 880 648 1048 618 1036 -500 -1090 302 -12 -245 -861 -1220 -360 314 264 130 598 591 651 -31 -465 -1707 686 -178 89 -1148 -157 -643 77 430 -258 -409 -1472 -715 -408 437 238 535 -39 735 494 746 587 263 461 450 912 314 -663 -637 -129 182 -32 660 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