File name: Pandora177s1_WestportCT_20231009_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T151037.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20231009_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20231009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231009T124110.0Z 8682.528588 249 1 49.79 2 72.32 115.52 22.57 160.60 0.00 1 0.00 1 0 17 2.003e-01 1.463e-02 2.102e-01 8.561e-03 4.316760e-01 4.613536e-03 5.689894e-03 -6.000000e+00 1.190343e-01 226.60 -2.00 3.51 -2.00 320.29 0.00e+00 2.360556e-05 1.644280e-03 3.792197e-03 -6.000000e+00 5.339266e-03 284.90 -2.00 20.00 -2.00 319.64 0.00e+00 3.246 0.001 302.00 328.00 3 4.7756e+00 1.3909e-02 4.3426e-02 -6.0000e+00 2.9460e-01 -3.8500e-02 1.7133e-02 3.3813e-02 -6.0000e+00 3.1865e-01 1.9254e-02 1.4549e-02 1.3295e-02 -6.0000e+00 1.9024e-01 -1.2487e-02 7.3961e-03 3.7593e-03 -6.0000e+00 8.2330e-02 1.0668e-04 8.8173e-05 2.7572e-04 5.0619e-05 -6.0000e+00 5.9181e-03 2.9083e-03 0.0000e+00 12 8 8 10 0 0 99.95 22.91 0.21 0.00291 0.00357 23 5 1 5 0 2164.600 26.32 20.00 22.91 13.86 21.8 940.41 900000 -71152 57303 -31204 31628 -82410 -98305 -57974 -62960 60156 -15435 95022 -24441 12424 24511 13979 -2660 -4387 -8711 -26296 3718 -9319 18617 -3653 13564 27650 -19858 -4967 -13193 3724 -21679 9517 16944 177 9916 -8431 -20620 -2941 12369 -7981 -1336 2970 10474 1015 -8386 6686 248 -588 7118 -5385 7331 7122 2005 -2564 2086 -356 1806 -2422 4770 -955 740 444 4700 2716 -689 -451 -2247 1885 3582 5857 2827 3676 -213 -1254 -3277 -4125 1701 -3560 307 -3655 -1122 131 -2306 -1757 -822 -232 137 2633 3100 2383 1790 -187 -3896 -2210 -1109 -432 815 -248 -244 -821 -1751 -2693 -559 -1586 -2351 -2374 -2068 536 1317 2763 1607 1474 413 -408 40 -1953 -374 200 416 538 888 1330 1197 258 -152 -895 -192 352 -784 -108 -1187 -1380 -168 481 -18 -297 760 910 538 430 -479 -1521 900000 -1607 478 -460 264 -1902 -2944 -1338 -1700 533 -288 793 -660 281 578 412 -101 -181 -398 -1498 171 -496 787 -210 708 1298 -1481 -308 -874 218 -1832 670 1211 15 755 -787 -2452 -354 1542 -1407 -243 547 1847 200 -1829 1263 50 -120 1381 -1247 1625 1731 553 -785 638 -115 583 -810 1461 -311 249 164 1834 1152 -303 -188 -924 769 1597 2866 1537 2036 -120 -679 -1662 -2040 745 -1666 153 -2174 -739 94 -1825 -1378 -682 -204 126 2398 2951 2182 1535 -151 -3132 -1802 -985 -430 900 -304 -313 -1034 -2057 -2936 -581 -1734 -2770 -2960 -2703 724 1909 4279 2663 2478 680 -636 59 -2812 -538 302 664 889 1461 2119 1845 387 -219 -1243 -260 497 -1227 -182 -2147 -2594 -326 978 -39 -671 1742 2103 1237 957 -1024 -3158 SS 20231009T124923.2Z 8682.534297 255 1 13.28 2 70.93 117.10 22.15 165.48 0.00 1 0.00 1 0 17 8.280e-02 1.164e-02 5.203e-02 4.028e-03 3.997973e-01 2.132850e-03 4.991265e-03 -6.000000e+00 4.921072e-02 226.60 -2.00 3.51 -2.00 319.51 0.00e+00 2.768343e-03 5.994836e-04 2.038833e-03 -6.000000e+00 2.192123e-03 284.90 -2.00 20.00 -2.00 318.81 0.00e+00 3.024 0.000 302.00 328.00 3 3.5159e+00 6.0274e-03 3.7268e-02 -6.0000e+00 1.2180e-01 -1.9735e-02 7.0998e-03 2.2652e-02 -6.0000e+00 1.3170e-01 1.6300e-02 5.4971e-03 1.1768e-02 -6.0000e+00 7.8623e-02 -1.3577e-02 2.8750e-03 3.6264e-03 -6.0000e+00 3.3821e-02 4.7585e-04 -2.2853e-05 1.2555e-04 5.1658e-05 -6.0000e+00 2.4350e-03 1.1631e-03 0.0000e+00 12 9 9 12 1 1 99.98 22.88 0.27 0.00116 0.00099 15 14 1 5 0 829.780 26.21 20.00 22.88 14.09 21.7 941.46 -27318 12924 -10088 -21131 -41391 -33091 -9106 -37990 5175 -35639 -12084 -23007 -6910 -12694 -8820 884 -12279 10832 -8488 12046 -3643 1402 5606 3675 2504 -4311 5239 -10656 -183 -10258 419 555 -369 -828 -2127 -10012 -6750 -3811 -2472 -119 -1553 -893 1646 -257 1314 -897 288 -325 850 317 2711 507 2262 224 500 2624 248 -1185 -666 1743 1079 3767 3879 3170 474 -1779 -1135 -1365 3572 1653 1954 1178 1235 1271 -919 -1748 -3438 -1591 -2298 -1622 -2556 -1972 -2266 -1822 -107 272 1714 1366 1820 1400 907 -201 -1404 -361 -1097 -1156 239 1362 -25 -344 -1721 -1730 -804 -842 -1999 -2400 -1059 -1077 1135 1758 1268 337 88 -226 -790 -784 -474 1112 1244 149 959 1354 1578 55 744 -670 -459 50 217 -780 -777 -979 -388 -32 54 361 683 1176 253 -153 -580 -1393 -651 228 -229 -510 -1138 -826 -194 -1226 128 -1290 -359 -845 -258 -609 -480 49 -844 681 -636 826 -277 110 437 312 229 -435 475 -1098 -17 -1085 45 67 -49 -112 -283 -1464 -1069 -702 -499 -27 -390 -236 439 -71 362 -255 81 -92 243 95 860 179 843 90 208 1099 108 -518 -286 736 483 1798 2032 1779 273 -996 -605 -749 2063 1090 1383 863 890 868 -590 -1025 -1917 -878 -1405 -1128 -2033 -1604 -1981 -1683 -104 280 1825 1485 1942 1433 868 -179 -1292 -337 -1055 -1252 286 1773 -32 -436 -2180 -2017 -903 -986 -2533 -3231 -1385 -1491 1656 2753 2104 571 144 -349 -1147 -1101 -673 1638 1945 245 1566 2146 2409 82 1056 -982 -657 74 330 -1299 -1364 -1783 -689 -59 107 738 1428 2473 533 -314 -1141 -2654 SS 20231009T131331.8Z 8682.551062 268 1 35.95 2 66.98 121.94 21.67 180.44 0.00 1 0.00 1 0 17 3.101e-02 1.065e-02 5.596e-03 7.692e-04 3.430717e-01 4.021499e-04 4.201325e-03 -6.000000e+00 1.843304e-02 226.60 -2.00 3.51 -2.00 318.77 0.00e+00 2.167849e-03 8.912629e-05 1.170893e-03 -6.000000e+00 8.209576e-04 284.90 -2.00 20.00 -2.00 318.02 0.00e+00 2.537 0.000 302.00 328.00 3 1.7583e+00 1.0993e-03 3.1065e-02 -6.0000e+00 4.5623e-02 1.2935e-02 1.2605e-03 1.8128e-02 -6.0000e+00 4.9329e-02 5.7860e-03 8.7213e-04 9.2902e-03 -6.0000e+00 2.9449e-02 -1.0938e-02 4.5775e-04 2.9007e-03 -6.0000e+00 1.2670e-02 4.6948e-03 8.2211e-05 2.3972e-05 3.3823e-05 -6.0000e+00 9.1193e-04 5.6718e-05 0.0000e+00 12 9 9 12 1 1 99.98 22.89 0.34 0.00006 0.00067 324 101 1 5 0 110.600 26.21 20.00 22.89 14.83 21.9 947.02 -3416 -5893 -4190 -9458 -9084 -14055 -6614 -7316 -8690 -10051 -11940 -8393 -6222 -2675 -2063 -734 -1083 1034 1874 1445 1427 -1195 1755 -55 486 -1318 -3021 -3132 -2805 -2110 -214 1494 73 -4223 -6875 -5943 -4330 -1717 -438 -877 -417 -396 279 182 1276 934 578 -101 -461 552 972 1375 1463 1461 784 1545 397 -386 -324 -96 1574 2588 3399 2459 517 -881 -1029 -447 1847 1498 1089 1578 916 941 -416 -1640 -2863 -3302 -1981 -2231 -2012 -2371 -2596 -1548 -165 374 1363 1388 1600 1427 401 -682 -1783 -845 -651 -339 597 1251 465 -618 -1508 -2192 -855 -591 -1584 -1764 -1058 -758 825 1368 1287 828 474 -225 -541 -341 126 182 1013 313 680 718 1320 727 685 -828 -742 498 -142 -346 -1051 -1237 -470 23 160 126 752 785 649 -28 -293 -1358 -136 -263 -185 -416 -367 -585 -276 -347 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