File name: Pandora177s1_WestportCT_20240501_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T181243.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240501_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240501T112638.6Z 8887.476835 172 1 41.95 2 73.27 84.06 63.87 182.92 0.00 1 0.00 1 0 25 2.339e-01 1.878e-02 2.690e-01 1.362e-02 4.864251e-01 7.509208e-03 5.873387e-03 -6.000000e+00 1.428288e-01 230.00 -2.00 3.51 -2.00 320.47 0.00e+00 3.739456e-03 2.751179e-03 2.547579e-03 -6.000000e+00 6.230622e-03 282.08 -2.00 20.00 -2.00 319.86 0.00e+00 3.419 0.001 302.00 328.00 3 4.9771e+00 2.2944e-02 4.3953e-02 -6.0000e+00 3.5771e-01 1.0615e-01 2.8097e-02 2.8306e-02 -6.0000e+00 3.8669e-01 -5.5626e-02 2.4547e-02 1.5675e-02 -6.0000e+00 2.2772e-01 1.2226e-02 1.2427e-02 5.5305e-03 -6.0000e+00 9.6374e-02 6.2947e-05 -1.6393e-04 4.3983e-04 8.6667e-05 -6.0000e+00 7.1280e-03 3.9503e-03 0.0000e+00 12 9 9 12 9 1 99.97 23.06 0.17 0.00395 0.00272 11 3 1 5 0 3495.460 26.41 19.99 23.06 17.28 24.2 984.89 61935 -80877 900000 -54194 -112261 -14412 900000 900000 -68728 -45735 -18281 99116 -64674 46127 -10408 48744 26281 -61846 52946 32905 -18489 -23846 -4152 -38605 16053 -17173 -23323 38715 -19214 9620 33694 32580 -2077 -14354 20010 10638 -24861 8115 -1367 7479 32451 9223 2325 14259 706 -12588 14493 5882 -4495 9924 9770 -650 -2509 -2386 -1088 -8 1164 -1781 1138 1124 10131 -4054 9826 10440 828 -152 -1392 -2237 2058 -1097 2976 -1285 -4517 2651 3570 -6413 -5522 -10271 3868 -3957 -4374 -1100 -2308 64 3984 679 2223 4853 802 3800 -1784 -1674 -2474 -3417 1872 -528 3398 -517 1783 578 -140 -2623 -3130 -923 -3369 -2428 -1033 1296 100 -1003 649 660 -563 -2500 -43 625 485 -699 364 1181 1619 782 1715 779 984 450 -445 1677 -331 10 -1429 -915 -889 162 261 -168 312 1560 1138 -760 -467 -1717 822 -1768 900000 -888 -3067 -191 900000 900000 -1609 -892 -285 1315 -2221 648 -309 913 677 -4152 1198 950 -909 -1247 -185 -2591 664 -1019 -1456 1349 -1125 451 1509 1702 -159 -1345 1294 768 -2866 808 -179 1030 3822 1453 407 2259 130 -2683 2380 1068 -932 1885 2026 -164 -695 -699 -328 -2 357 -557 340 337 2932 -1489 3480 3940 347 -62 -554 -931 913 -563 1577 -728 -2585 1330 1622 -2920 -2349 -4685 1707 -2182 -2761 -744 -1696 48 3106 582 1963 4238 717 3145 -1453 -1262 -1808 -2616 1506 -494 3453 -602 2128 682 -153 -2867 -3322 -994 -3966 -2994 -1322 1722 137 -1514 1023 1057 -888 -3792 -64 893 706 -1083 590 1957 2657 1253 2625 1159 1400 615 -604 2345 -520 17 -2640 -1750 -1776 339 577 -387 731 3644 2641 -1733 -1005 -3582 SS 20240501T113257.0Z 8887.481216 176 1 47.85 2 72.08 85.06 63.93 184.51 0.00 1 0.00 1 0 25 1.227e-01 1.140e-02 9.257e-02 4.536e-03 4.522563e-01 2.461468e-03 5.712968e-03 -6.000000e+00 7.377017e-02 230.00 -2.00 3.51 -2.00 320.22 0.00e+00 2.864457e-03 8.334811e-04 3.171574e-03 -6.000000e+00 3.209798e-03 282.08 -2.00 20.00 -2.00 319.59 0.00e+00 3.206 0.001 302.00 328.00 3 3.8936e+00 7.3266e-03 4.1958e-02 -6.0000e+00 1.8425e-01 1.5950e-02 8.8990e-03 2.8913e-02 -6.0000e+00 1.9888e-01 -3.3779e-03 7.5911e-03 1.5061e-02 -6.0000e+00 1.1819e-01 -5.1779e-03 3.8714e-03 4.4753e-03 -6.0000e+00 5.0306e-02 2.4832e-04 3.9314e-04 1.4435e-04 7.4901e-05 -6.0000e+00 3.6108e-03 5.5294e-03 0.0000e+00 12 9 9 12 1 1 99.97 23.03 0.38 0.00553 0.00848 37 9 1 5 0 1258.900 26.41 20.00 23.03 17.76 24.2 987.69 -79214 -42446 -50173 3713 -56841 -21590 -12567 -24929 -9858 -26114 -25707 -25137 -5894 23060 -6781 30572 -2254 -120 -1844 -4614 -13347 2507 -9266 -6547 526 5621 7897 -16234 -11900 -12439 -6992 3313 3739 -2508 -8161 -10327 -2429 -4082 -4741 -559 -4760 2684 270 -480 1096 2428 1306 630 103 640 2596 -468 1372 3121 4056 2896 465 -1475 -4577 241 606 4182 5135 4475 -431 -875 -1528 -639 869 1013 2031 3135 1526 914 -1047 -1275 -2733 -4211 -1539 -1878 -3480 -1616 -1130 -1074 5 377 1922 1156 1920 1246 386 -1406 -2577 -1512 -187 90 405 1249 -33 -288 -1788 -2199 -442 -276 -2038 -1711 -1555 -973 1509 1392 1366 463 444 -1052 -740 -905 -401 222 928 459 1020 1407 1809 924 467 -1333 -1277 -16 -378 -557 -938 -879 -549 285 31 275 539 872 586 -100 -317 -1301 -1728 -713 -932 38 -1006 -286 -167 -425 -159 -520 -536 -588 -138 495 -234 821 -92 -5 -86 -230 -742 120 -521 -385 31 321 437 -1113 -778 -869 -526 257 317 -230 -771 -1018 -249 -513 -719 -93 -908 504 54 -98 224 495 271 133 22 147 635 -129 400 946 1269 945 157 -505 -1592 81 213 1563 2098 1963 -199 -387 -659 -283 423 551 1176 1839 891 507 -542 -600 -1230 -1965 -837 -1097 -2348 -1181 -881 -889 5 350 1837 1130 1831 1141 332 -1137 -2027 -1220 -164 89 452 1518 -42 -361 -2098 -2380 -457 -297 -2385 -2109 -2013 -1330 2180 2184 2268 785 730 -1650 -1087 -1292 -581 337 1478 759 1671 2229 2754 1367 664 -1845 -1874 -23 -589 -948 -1696 -1649 -1072 585 67 620 1238 2014 1345 -222 -672 -2677 SS 20240501T135839.3Z 8887.582400 274 1 49.25 2 45.10 111.97 73.32 218.36 0.00 1 0.00 1 0 17 1.826e-02 1.174e-02 7.130e-03 2.690e-03 2.138061e-01 1.422056e-03 2.561044e-03 -6.000000e+00 1.098185e-02 230.01 -2.00 3.51 -2.00 317.10 0.00e+00 1.171643e-03 1.897005e-04 3.090327e-04 -6.000000e+00 4.778155e-04 282.09 -2.00 20.00 -2.00 316.38 0.00e+00 1.415 0.000 302.00 328.00 3 5.4220e+00 3.7423e-03 1.8026e-02 -6.0000e+00 2.7429e-02 5.7522e-02 4.1738e-03 1.0939e-02 -6.0000e+00 2.9607e-02 -1.1159e-03 2.4659e-03 5.3796e-03 -6.0000e+00 1.7595e-02 -9.0812e-03 1.1844e-03 1.6114e-03 -6.0000e+00 7.4892e-03 4.3241e-04 1.8435e-04 8.3678e-05 1.7772e-05 -6.0000e+00 5.3747e-04 5.2504e-03 0.0000e+00 12 9 8 11 8 0 99.85 22.98 0.58 0.00525 0.00664 16 4 1 5 0 3077.530 26.32 20.00 22.98 17.80 24.3 987.93 1405 1588 -1068 -1961 -345 -1894 734 -4010 -1430 -5903 -7304 -4039 -3796 1086 -1587 -372 603 3125 1021 2203 2268 798 -566 1662 1886 -405 -457 -756 -923 735 960 60 973 -3182 -7422 -4642 -4558 -590 -267 -48 -752 421 434 206 262 1733 61 -136 31 336 944 1090 2101 557 517 1483 308 -262 20 684 1566 1970 2863 2006 -306 -1281 -1281 -440 2046 1404 751 1315 1280 1319 -105 -2100 -2405 -2611 -2553 -2453 -3003 -2728 -3035 -2068 -230 431 1354 1204 1392 1168 434 -904 -1835 169 -701 -368 551 1512 345 -616 -1253 -2175 -735 -668 -1549 -1769 -763 -823 914 1432 1502 778 473 -124 -364 -501 -328 -187 724 719 651 877 1029 266 1095 -669 -580 573 112 -479 -847 -764 -513 603 389 -12 536 675 513 -429 -642 -1471 200 239 -163 -278 -44 -237 96 -612 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