File name: Pandora177s1_WestportCT_20240504_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T181233.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240504_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240504T110234.9Z 8890.460126 118 1 48.85 2 77.14 79.62 59.05 130.70 0.00 1 0.00 1 0 25 3.141e-01 1.256e-02 2.438e-01 6.741e-03 5.999665e-01 3.911771e-03 8.025852e-03 -6.000000e+00 1.912237e-01 230.25 -2.00 3.51 -2.00 321.21 0.00e+00 2.607409e-03 1.888148e-03 7.416851e-03 -6.000000e+00 9.740162e-03 282.41 -2.00 20.00 -2.00 320.67 0.00e+00 4.374 0.001 302.00 328.00 3 3.2022e+00 1.3368e-02 6.4743e-02 -6.0000e+00 4.7976e-01 -1.3934e-02 1.8428e-02 5.6224e-02 -6.0000e+00 5.1910e-01 -2.6666e-02 1.8837e-02 2.5843e-02 -6.0000e+00 3.0547e-01 4.7615e-03 8.9403e-03 5.8945e-03 -6.0000e+00 1.3213e-01 1.4254e-04 5.4174e-04 2.1649e-04 1.5388e-04 -6.0000e+00 9.6183e-03 6.5018e-03 0.0000e+00 12 8 8 10 0 0 99.91 23.10 0.41 0.00650 0.01057 43 10 1 5 0 1135.990 26.41 19.99 23.10 13.21 24.0 957.33 -130857 900000 900000 900000 -160354 -93313 900000 -169851 900000 -115197 900000 900000 900000 -66859 -8603 -39372 -1677 66810 -97866 17353 -25045 6151 -14362 2036 -25320 16646 -2007 -29052 -43268 -34587 47840 -13380 35422 9801 9708 -18811 -13062 9652 -4389 2473 7103 10567 8924 -820 890 5629 8769 -2932 6088 -4645 4305 5251 6732 6794 -3249 -3908 1039 2981 -2802 -2287 2255 -688 7676 5110 -2094 -1376 1742 -645 4344 1966 4787 1932 1954 665 417 -3767 -5645 -1998 -1246 -297 -2714 -1491 -3222 -1022 898 -2267 2385 1920 2643 -165 563 -1402 -1323 -731 -684 -663 643 1299 986 -211 -2215 -1291 -1566 -344 -1160 -3005 -1278 -512 1772 1786 775 333 -64 -928 -1584 57 -87 1050 227 808 908 1463 2257 571 270 -1960 -1989 89 696 -733 -947 -1095 -510 -363 -59 189 511 1293 931 -244 -16 -1325 -859 900000 900000 900000 -1547 -612 900000 -2360 900000 -1181 900000 900000 900000 -877 -78 -565 -19 438 -3372 199 -452 83 -253 33 -592 266 -39 -727 -1278 -1036 746 -455 828 306 299 -795 -595 428 -272 166 507 780 699 -73 79 489 759 -296 592 -545 514 691 955 1034 -577 -728 188 523 -513 -447 448 -157 1813 1348 -607 -387 472 -190 1374 718 1832 779 769 248 143 -1225 -1798 -644 -455 -126 -1360 -825 -1963 -650 597 -1656 1741 1429 1918 -117 373 -889 -824 -481 -509 -568 621 1383 1108 -234 -2307 -1213 -1424 -321 -1164 -3253 -1439 -616 2296 2559 1207 536 -102 -1413 -2306 79 -124 1568 360 1304 1443 2228 3291 819 373 -2666 -2697 127 1104 -1308 -1817 -2214 -1082 -820 -142 439 1206 3047 2316 -588 -37 -2912 SS 20240504T110835.1Z 8890.464295 121 1 49.00 2 76.03 80.56 58.20 132.10 0.00 1 0.00 1 0 25 2.211e-01 1.099e-02 1.632e-01 3.193e-03 5.555807e-01 1.754683e-03 7.485571e-03 -6.000000e+00 1.330781e-01 230.25 -2.00 3.51 -2.00 320.84 0.00e+00 5.340408e-03 7.568654e-04 6.033470e-03 -6.000000e+00 5.794084e-03 282.41 -2.00 20.00 -2.00 320.28 0.00e+00 4.048 0.001 302.00 328.00 3 2.5284e+00 5.6455e-03 5.6209e-02 -6.0000e+00 3.3254e-01 2.3112e-03 7.4359e-03 4.4490e-02 -6.0000e+00 3.5890e-01 -2.5342e-02 7.2627e-03 2.4458e-02 -6.0000e+00 2.1328e-01 1.3804e-03 3.5466e-03 7.5511e-03 -6.0000e+00 9.0734e-02 3.9291e-04 2.9039e-04 9.7768e-05 1.5084e-04 -6.0000e+00 6.5102e-03 7.2398e-03 0.0000e+00 12 8 8 10 0 0 95.75 23.08 0.39 0.00724 0.00942 72 17 1 5 0 680.370 26.41 19.99 23.08 13.64 24.0 960.38 -92590 -45980 -100766 23709 -107302 -15608 -98243 -29789 -67399 -51757 -57254 -41408 -39495 -58055 -25649 -13823 4670 -31364 5874 417 -16643 -13972 -15387 -1089 -27918 -6721 -28890 -2 -6024 -7808 3465 -9152 -313 -13359 -9686 -7086 -6494 -5927 -2261 -908 -624 439 -1225 3194 1287 574 -3109 2779 83 4119 5566 1094 3755 -119 1878 1595 735 -146 338 157 563 4221 2491 4021 -106 1212 -1706 1361 1313 1758 1832 1378 2039 -458 -2151 -3016 -3279 -4520 -1104 -2207 -1442 -1186 -2434 91 -444 1334 2030 1154 2114 1481 611 -2304 -2224 -2427 -952 -480 1300 1250 461 -370 -2105 -2131 -800 -396 -1669 -2287 -978 -231 1167 1623 1409 483 398 -1080 -514 -747 -31 524 949 620 856 1163 1355 654 108 -1178 -1171 338 -276 -924 -1030 -1726 -435 -259 225 69 790 1130 598 284 -432 -1220 -734 -260 -1027 74 -1063 -62 -973 -169 -610 -425 -535 -387 -458 -1035 -407 -227 71 -755 105 9 -400 -365 -426 -28 -1008 -203 -1088 0 -184 -267 125 -442 -15 -769 -528 -386 -398 -437 -194 -88 -67 50 -148 380 160 74 -424 369 12 607 893 203 738 -26 420 370 174 -35 79 37 141 1135 764 1316 -37 403 -575 469 508 762 854 660 947 -205 -894 -1152 -1202 -1749 -468 -1107 -824 -752 -1686 65 -342 1075 1701 990 1767 1190 462 -1678 -1579 -1822 -791 -456 1380 1473 575 -454 -2419 -2235 -800 -409 -1866 -2724 -1215 -305 1670 2543 2153 762 615 -1767 -792 -1127 -47 840 1600 978 1467 1919 2152 1010 162 -1710 -1689 513 -469 -1745 -1892 -3343 -875 -553 506 161 1881 2700 1420 649 -941 -2563 SS 20240504T111856.2Z 8890.471484 124 1 48.89 2 74.10 82.18 56.77 134.56 0.00 1 0.00 1 0 25 1.661e-01 1.085e-02 4.983e-02 1.871e-03 4.984438e-01 1.026073e-03 6.374456e-03 -6.000000e+00 9.997699e-02 230.25 -2.00 3.51 -2.00 320.44 0.00e+00 4.317394e-03 3.806920e-04 3.901480e-03 -6.000000e+00 4.352747e-03 282.41 -2.00 20.00 -2.00 319.82 0.00e+00 3.586 0.001 302.00 328.00 3 2.1911e+00 3.1283e-03 4.7120e-02 -6.0000e+00 2.4982e-01 2.7972e-03 3.8871e-03 3.2920e-02 -6.0000e+00 2.6962e-01 -2.5122e-02 3.4815e-03 1.8157e-02 -6.0000e+00 1.6023e-01 2.9676e-03 1.7507e-03 5.9332e-03 -6.0000e+00 6.8168e-02 9.1063e-04 1.9915e-04 5.8534e-05 9.6948e-05 -6.0000e+00 4.8906e-03 6.9621e-03 0.0000e+00 12 8 8 10 0 0 96.03 23.08 0.36 0.00696 0.00846 137 32 1 5 0 356.750 26.41 20.00 23.08 14.76 24.2 968.65 -55510 -51210 -68755 -24720 -65807 -25687 -75735 -36769 -56371 -30822 -47394 -52964 -11320 -42613 4404 -28802 4560 -11052 -10992 -4344 -10303 4055 -13016 2797 -15193 -4302 -15667 -8966 -16761 -8668 -3784 -6654 4760 -8874 -3247 -11919 -4234 -5882 269 -137 -1900 2392 -1053 4117 887 4100 746 2570 495 1525 2643 2663 3281 648 2546 613 1121 -1594 -976 472 701 3761 2926 3787 312 459 -1443 249 2662 1882 1914 1149 1905 -124 1 -2916 -3308 -4731 -2041 -2200 -2112 -1333 -2992 -831 -187 1070 1469 1480 1731 1356 527 -1548 -1543 -1466 -484 -380 895 1407 294 -350 -2054 -1671 -792 144 -2182 -1631 -1087 -745 935 1213 1411 538 140 -770 -746 -769 166 523 914 621 798 1528 1420 962 369 -1158 -974 211 -132 -618 -991 -1494 -397 -147 328 -31 723 948 525 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