File name: Pandora177s1_WestportCT_20240813_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T194556.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240813_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240813T111649.5Z 8991.470017 77 1 10.53 2 77.11 81.98 163.44 2.18 0.00 1 0.00 1 0 17 5.866e-01 3.445e-02 4.078e-01 2.433e-02 6.077400e-01 1.384598e-02 1.153599e-02 -6.000000e+00 3.557201e-01 231.88 -2.00 3.51 -2.00 321.04 0.00e+00 1.258107e-02 6.247337e-03 1.440193e-02 -6.000000e+00 1.643828e-02 290.12 -2.00 20.00 -2.00 320.39 0.00e+00 4.360 0.001 302.00 328.00 3 4.1302e+00 4.6127e-02 8.5951e-02 -6.0000e+00 8.8953e-01 3.5362e-01 5.8737e-02 9.1701e-02 -6.0000e+00 9.5773e-01 -4.4791e-01 4.7250e-02 3.4407e-02 -6.0000e+00 5.7155e-01 1.7712e-01 2.2994e-02 4.6513e-03 -6.0000e+00 2.4684e-01 5.0059e-05 9.8955e-05 7.3965e-04 2.4744e-04 -6.0000e+00 1.7421e-02 5.8897e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.11 -0.13 0.00589 0.00663 2 3 1 5 0 3508.650 26.41 20.00 23.11 19.80 25.5 986.61 900000 92359 900000 197141 -149569 -48912 -149909 -30722 -56026 -143212 -175663 -123159 -83487 84645 1320 -33694 70114 248405 161908 -53167 -81645 900000 113599 900000 61640 95346 254669 1354 -93759 176901 -13430 54080 -3237 -17721 90035 -65139 8052 4174 62369 30127 60313 40688 23138 23117 25506 9557 4461 32162 25012 45653 5075 10213 21586 22542 27213 3799 17877 15882 -9930 19515 -671 -1154 30641 11810 6846 2631 21163 -1248 2931 17674 128 5883 -965 7049 745 -6842 -10179 -10219 -2337 -10316 8901 -5188 1087 -6164 -3090 449 1711 2022 -1361 940 -5138 -359 -2503 -1174 23 110 -2166 -1662 -502 -4567 -2580 -5176 -4499 381 655 1254 -4309 3840 -85 -772 4155 -965 -138 3992 -1969 -1236 2441 -43 1270 232 4822 1222 4009 1687 -2354 1994 -2572 -1364 -1220 470 -3007 295 526 1607 1614 -2535 -340 1126 521 447 -1204 -1328 900000 2190 900000 4674 -5713 -1160 -5529 -728 -1328 -5470 -9718 -4704 -2749 2007 31 -1243 1662 5890 3839 -3081 -6237 900000 2693 900000 1461 2261 6038 47 -8274 4194 -749 1810 -212 -1359 2260 -7293 505 320 3131 2353 3785 3291 2323 2386 2632 1186 597 3364 2930 4648 849 1780 3613 3930 4668 837 3416 3035 -2410 3565 -160 -309 6709 3393 2110 822 5401 -418 1051 6113 56 2486 -423 2654 271 -2443 -3606 -3805 -919 -5165 4233 -3162 670 -4333 -2236 332 1308 1562 -1069 688 -3734 -233 -1623 -798 18 97 -2233 -1901 -599 -5548 -2821 -5270 -4361 363 665 1340 -5156 4563 -116 -1110 6130 -1542 -214 6019 -2993 -1826 3557 -69 2082 371 7694 1947 5982 2490 -3477 2709 -3641 -2044 -2049 862 -5790 578 1083 3483 3701 -6294 -841 2762 1266 1042 -2681 -2817 SS 20240813T114003.2Z 8991.486148 87 1 25.74 2 72.76 85.68 162.71 19.35 0.00 1 0.00 1 0 25 1.023e-01 1.127e-02 1.256e-02 7.228e-04 4.642173e-01 3.913375e-04 5.880191e-03 -6.000000e+00 6.197239e-02 231.88 -2.00 3.51 -2.00 319.81 0.00e+00 2.392993e-03 1.210688e-04 2.951931e-03 -6.000000e+00 2.768506e-03 290.12 -2.00 20.00 -2.00 319.02 0.00e+00 3.323 0.001 302.00 328.00 3 5.3715e-01 1.1355e-03 4.3048e-02 -6.0000e+00 1.5506e-01 1.7583e-03 1.3664e-03 2.9308e-02 -6.0000e+00 1.6689e-01 -3.7450e-03 1.0973e-03 1.3736e-02 -6.0000e+00 9.9517e-02 -6.9202e-03 5.6968e-04 3.4506e-03 -6.0000e+00 4.2543e-02 6.3587e-03 2.2666e-04 2.2188e-05 5.3636e-05 -6.0000e+00 3.0129e-03 3.7398e-03 0.0000e+00 12 9 9 12 1 1 98.05 23.17 0.30 0.00374 0.00544 341 149 1 5 0 75.250 26.51 20.00 23.17 20.50 25.6 991.65 -19257 -33782 -14404 -38436 -36428 -45032 -34887 -34348 -33589 -24787 -37732 -14944 -25311 -8635 -9937 -8871 -4798 -5490 -1547 -4401 -1087 -6940 -1304 -4154 -3737 -5604 -7970 -7725 -9186 -4442 -4648 -322 -2982 -5071 -9411 -8677 -6078 -2828 572 -805 657 151 1593 762 1788 730 408 310 -942 1074 1233 1860 1413 1760 1258 1986 617 -523 -363 -110 2023 3215 3945 2989 701 -764 -1262 -364 2118 2138 1408 2110 1226 1019 -633 -2259 -3439 -3951 -1997 -2250 -1840 -2297 -2536 -1460 -75 773 1672 1741 1839 1598 382 -767 -2015 -916 -814 -486 635 1401 456 -780 -1655 -2326 -928 -362 -1623 -1886 -1148 -580 886 1463 1200 646 158 -489 -682 -374 317 528 1266 535 922 998 1604 713 503 -1205 -1001 558 -219 -452 -1261 -1406 -608 -89 212 73 850 924 667 -64 -375 -1288 -266 -602 -217 -704 -614 -825 -634 -709 -760 -542 -989 -352 -801 -284 -395 -396 -226 -280 -81 -248 -61 -417 -77 -273 -262 -414 -597 -562 -676 -331 -395 -30 -314 -557 -1053 -984 -758 -412 97 -159 141 34 372 183 431 180 102 78 -248 293 366 601 496 652 489 793 253 -216 -147 -45 852 1339 1802 1474 356 -376 -605 -179 1136 1287 919 1404 807 635 -367 -1210 -1756 -2071 -1141 -1488 -1379 -1914 -2276 -1377 -68 743 1671 1766 1835 1526 375 -705 -1803 -841 -826 -511 744 1793 617 -1042 -2058 -2672 -1021 -412 -2001 -2467 -1568 -774 1262 2253 1965 1079 257 -756 -993 -527 452 790 1994 877 1502 1576 2431 1050 771 -1796 -1466 846 -339 -768 -2288 -2656 -1106 -170 428 153 1820 1994 1431 -133 -746 -2482 SS 20240813T114522.6Z 8991.489845 90 1 48.78 2 71.76 86.54 162.38 23.03 0.00 1 0.00 1 0 25 8.648e-02 1.109e-02 7.663e-03 4.620e-04 4.446330e-01 2.482878e-04 5.577789e-03 -6.000000e+00 5.239487e-02 231.88 -2.00 3.51 -2.00 319.86 0.00e+00 2.513414e-03 7.831328e-05 2.908423e-03 -6.000000e+00 2.340898e-03 290.12 -2.00 20.00 -2.00 319.07 0.00e+00 3.152 0.001 302.00 328.00 3 2.1400e-01 7.2760e-04 4.1088e-02 -6.0000e+00 1.3110e-01 1.6334e-03 8.7657e-04 2.8312e-02 -6.0000e+00 1.4110e-01 -1.0781e-03 7.0304e-04 1.3360e-02 -6.0000e+00 8.4139e-02 -8.4095e-03 3.6297e-04 3.3589e-03 -6.0000e+00 3.5966e-02 1.0582e-02 1.0861e-04 1.4370e-05 4.9777e-05 -6.0000e+00 2.5476e-03 4.3759e-03 0.0000e+00 12 8 8 10 0 0 0.65 23.18 0.30 0.00438 0.00519 1113 256 1 5 0 43.820 26.51 20.00 23.18 20.97 25.7 996.67 -26584 -23065 -25915 -30200 -31323 -37331 -28264 -25021 -22640 -26707 -22624 -24280 -16167 -11449 -7108 -6289 -4310 -869 -2025 474 -3382 -2180 -3689 -2556 -2410 -4491 -5450 -7825 -5579 -5566 -1749 -1607 -1971 -6253 -9210 -7212 -6143 -1581 -475 -338 -606 258 446 562 1597 738 816 -178 -370 296 1617 1316 1628 1672 980 1759 312 -95 -708 314 1562 3146 3687 2892 702 -962 -1152 -648 2091 1855 1672 1758 1132 1056 -766 -2099 -3485 -3795 -2362 -2247 -2179 -2163 -2704 -1482 18 755 1826 1624 1930 1314 522 -1062 -2123 -1087 -878 -330 659 1434 474 -631 -1832 -2352 -947 -336 -1607 -1953 -1043 -673 976 1408 1292 699 208 -461 -734 -388 203 502 1120 583 830 1009 1485 767 533 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