File name: Pandora177s1_WestportCT_20240817_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240829T194709.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240817_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240817T150907.5Z 8995.631337 292 1 17.05 2 36.61 132.05 164.84 4.63 0.00 1 0.00 1 0 17 1.590e-02 1.246e-02 2.714e-03 1.585e-03 1.741957e-01 8.506213e-04 2.104785e-03 -6.000000e+00 9.624787e-03 231.60 -2.00 3.51 -2.00 315.69 0.00e+00 8.581341e-04 8.463752e-05 2.030464e-04 -6.000000e+00 4.299459e-04 289.95 -2.00 20.00 -2.00 314.93 0.00e+00 1.245 0.000 302.00 328.00 3 4.2397e+00 2.2049e-03 1.5417e-02 -6.0000e+00 2.4067e-02 6.1549e-02 2.4432e-03 8.9438e-03 -6.0000e+00 2.5906e-02 -7.5056e-03 1.4023e-03 4.3148e-03 -6.0000e+00 1.5451e-02 -6.5632e-03 6.3052e-04 1.1995e-03 -6.0000e+00 6.6098e-03 1.8158e-03 5.0928e-05 4.8290e-05 1.6437e-05 -6.0000e+00 4.6819e-04 1.7106e-03 0.0000e+00 12 9 9 12 1 1 99.99 23.26 0.31 0.00171 0.00209 25 17 1 5 0 655.430 26.62 20.01 23.26 29.97 26.1 1054.25 2402 760 123 -3784 -2951 -1375 -1161 1241 -846 -3150 -4638 -2607 -1176 246 1124 268 693 1277 1666 2481 1039 872 1592 1589 1648 1028 -139 -432 -1073 344 1562 1379 1196 -3700 -5680 -4542 -3765 -1026 -57 -514 -634 -280 454 -10 646 296 -304 -666 -1125 196 1076 1110 725 1225 556 1428 229 -157 -395 413 1332 2341 2731 2169 131 -1318 -1371 -1039 1615 1190 1196 1697 1487 1415 -148 -1158 -2695 -3228 -2030 -2365 -2448 -2633 -2764 -1741 -316 194 1394 1318 1828 1464 299 -1000 -1884 -253 -641 -312 753 1317 416 -646 -1509 -2379 -1026 -813 -1555 -1718 -1045 -846 835 1561 1680 1132 683 225 -91 -245 -282 140 673 543 831 731 920 709 869 -566 -616 482 -30 -267 -861 -1054 -550 -8 177 134 714 817 622 -65 -716 -1845 629 212 34 -997 -697 -308 -276 321 -240 -927 -1366 -774 -378 88 437 101 267 500 667 1010 432 361 662 689 746 473 -63 -201 -473 146 681 642 581 -1860 -2772 -2190 -1806 -565 -37 -370 -490 -204 334 -8 473 234 -234 -496 -819 141 803 876 601 955 445 1151 187 -128 -319 332 1108 2061 2549 2089 125 -1160 -1214 -910 1368 1121 1207 1750 1520 1387 -136 -1055 -2265 -2637 -1731 -2246 -2358 -2744 -3046 -2002 -353 230 1716 1652 2249 1725 355 -1086 -1902 -249 -668 -354 929 1607 529 -805 -1906 -2829 -1191 -991 -1887 -2204 -1387 -1165 1185 2305 2543 1697 971 296 -119 -309 -359 188 885 755 1175 1018 1237 913 1152 -720 -756 593 -39 -370 -1141 -1418 -754 -12 265 209 1138 1319 1006 -103 -1111 -2808 SS 20240817T152530.6Z 8995.642715 302 1 13.96 2 34.43 137.80 164.24 17.54 0.00 1 0.00 1 0 17 1.662e-02 1.261e-02 4.220e-03 2.519e-03 1.709126e-01 1.353161e-03 2.081257e-03 -6.000000e+00 1.006352e-02 231.60 -2.00 3.51 -2.00 315.54 0.00e+00 7.623292e-04 1.309276e-04 1.705153e-04 -6.000000e+00 4.495076e-04 289.95 -2.00 20.00 -2.00 314.80 0.00e+00 1.212 0.000 302.00 328.00 3 4.9125e+00 3.5064e-03 1.5086e-02 -6.0000e+00 2.5164e-02 6.5785e-02 3.8735e-03 8.8405e-03 -6.0000e+00 2.7087e-02 -8.0699e-03 2.2205e-03 4.2728e-03 -6.0000e+00 1.6155e-02 -5.5920e-03 1.0044e-03 1.1815e-03 -6.0000e+00 6.9115e-03 9.6292e-04 -1.0024e-04 7.6962e-05 1.6541e-05 -6.0000e+00 4.8949e-04 1.2653e-03 0.0000e+00 12 9 9 12 1 1 99.69 23.28 0.40 0.00127 0.00051 8 7 1 5 0 1550.720 26.62 20.01 23.28 30.93 26.0 1059.75 3357 1782 503 -3702 -4694 -4279 -1616 1285 581 -2374 -4323 -3017 -1547 361 1201 82 -233 935 2008 2367 1939 -262 1604 964 2066 299 636 -176 756 -134 1306 1095 1260 -3519 -5607 -4308 -4149 -748 -496 -515 -361 -935 307 -369 591 1110 -459 -1052 -796 259 772 837 606 587 379 1001 546 -557 -109 1058 1292 1976 2490 2055 17 -1130 -1531 -698 1756 1392 923 1477 1027 1508 -199 -1291 -2600 -3171 -2347 -1970 -2330 -2304 -3338 -1677 -219 358 1475 1433 1989 1490 441 -1176 -1936 -565 -748 -103 761 1491 385 -263 -1226 -2393 -1446 -651 -1955 -2039 -741 -715 642 1673 1368 1140 909 143 -319 -673 -391 -44 895 566 688 908 629 889 913 -390 -1157 677 45 -41 -454 -819 -839 135 336 158 400 719 771 -44 -753 -1831 883 500 140 -988 -1143 -997 -389 335 164 -701 -1283 -907 -502 129 468 34 -100 405 882 1061 879 -121 733 462 1023 142 312 -82 326 -57 566 507 607 -1750 -2709 -2051 -2173 -416 -323 -376 -264 -714 235 -284 449 827 -359 -796 -584 189 583 668 476 474 313 834 460 -469 -91 872 1105 1796 2395 2037 17 -1020 -1278 -611 1520 1340 956 1564 1081 1514 -188 -1181 -2187 -2590 -2005 -1744 -2288 -2442 -3553 -1850 -254 442 1887 1763 2542 1827 503 -1307 -1994 -567 -794 -118 897 1881 506 -339 -1478 -2724 -1712 -757 -2466 -2718 -1016 -961 892 2411 2027 1669 1260 194 -401 -811 -475 -56 1211 766 950 1303 875 1180 1152 -501 -1442 840 55 -54 -616 -1130 -1184 197 487 239 621 1127 1207 -68 -1133 -2703 SS 20240817T152937.7Z 8995.645575 305 1 23.75 2 33.92 139.33 163.99 20.61 0.00 1 0.00 1 0 25 1.569e-02 1.230e-02 6.033e-04 3.816e-04 1.683502e-01 2.045076e-04 2.031253e-03 -6.000000e+00 9.500737e-03 231.60 -2.00 3.51 -2.00 315.31 0.00e+00 8.055953e-04 1.890540e-05 1.444266e-04 -6.000000e+00 4.243964e-04 289.95 -2.00 20.00 -2.00 314.59 0.00e+00 1.204 0.000 302.00 328.00 3 1.9766e+00 5.2868e-04 1.4919e-02 -6.0000e+00 2.3757e-02 4.1967e-02 5.8409e-04 8.6729e-03 -6.0000e+00 2.5572e-02 -7.6940e-03 3.3461e-04 4.1773e-03 -6.0000e+00 1.5251e-02 -5.7774e-03 1.5006e-04 1.1592e-03 -6.0000e+00 6.5247e-03 1.8526e-02 4.4842e-07 1.1560e-05 1.5953e-05 -6.0000e+00 4.6214e-04 1.6100e-03 0.0000e+00 12 9 9 12 1 1 99.93 23.28 0.39 0.00161 0.00161 274 130 1 5 0 86.320 26.62 20.01 23.28 31.05 26.2 1060.87 2554 1065 121 -3130 -3104 -2476 -209 1180 -255 -3164 -4620 -2567 -1055 263 855 235 110 1492 1542 2306 910 700 1651 1884 1839 767 -286 -684 -344 -375 1520 1771 750 -3399 -5798 -4719 -3756 -1150 -266 -879 -694 -164 146 102 816 288 -352 -642 -1079 -53 1012 951 1009 1013 543 1325 630 9 -266 145 1225 2214 2721 2234 127 -1404 -1530 -877 1688 1395 1003 1507 1179 1476 24 -1306 -2603 -3187 -1954 -2205 -2464 -2536 -2853 -1646 -326 282 1229 1238 1715 1298 562 -730 -1589 -518 -529 -156 664 1436 610 -435 -1375 -2086 -1041 -600 -1711 -1838 -1020 -811 719 1354 1549 1160 733 89 -362 -344 -125 42 948 547 712 676 1103 689 954 -520 -587 523 58 -141 -803 -1153 -465 30 364 143 666 727 481 -148 -590 -1707 719 320 36 -881 -868 -662 -58 328 -77 -1000 -1460 -816 -362 100 355 104 50 682 722 1098 443 339 802 951 970 413 -150 -339 -160 -170 700 866 386 -1796 -2986 -2403 -2089 -673 -181 -623 -526 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